Hetero-assembly of colloidal particles in concentrated non-aqueous suspensions by polymer dispersant design

Although many colloidal assembling systems have been reported, most systems suffer from severe aggregation under high solid concentrations, which can often be observed in typical hetero-aggregation system. In this study, we created a hetero-assembly system using concentrated (~50 vol%) suspensions by mixing large SiO₂ particles modified with polyacrylic acid partially complexed with oleylamine (PAA-OAm) and small SiO₂ particles modified with polyethyleneimine partially complexed with oleic acid (PEI-OA) in a non-aqueous solvent. We demonstrated that hetero-assembly is driven by the interactions between the uncomplexed carboxyl/amine groups of the PAA/PEI present on the particles, while severe aggregation is simultaneously prevented by the steric repulsions of the aliphatic oleyl chains. Comparison of the cross sections of the in-situ solidified hetero-assembled suspensions with those of ideally assembled structures which were reproduced by a simulation considering the statistical distribution of particles strongly supported successful particle assembling via the proposed approach. The results revealed that the OA content in the PEI-OA complex was the dominant factor that controlled the dispersion and assembling state of the binary particles. The significance of this study is that our findings will provide a class of colloidal dispersion state which binary particles were assembled in a high solid content suspension without forming strong aggregates.     

Relationship between the adhesion properties of UV-curable alumina suspensions and the functionalities and structures of UV-curable acrylate monomers for DLP-based ceramic stereolithography

Digital light processing (DLP)-based ceramic stereolithography has attracted significant attentions due to the high printing speed and high dimensional accuracy of DLP printers. However, undesired dropping of unfinished ceramic parts during printing, owing to inadequate adhesion between the first cured layer and the substrate of the building platform, still remains a challenge. In this study, the relationship between the adhesion properties of ultraviolet (UV)-curable alumina (α-Al₂O₃) suspensions and the functionalities and structures of UV-curable acrylate monomers was investigated. With an increase in the proportions of monofunctional monomers, the adhesion abilities of UV-curable alumina suspensions enhanced because of reduced volume shrinkage, however, inferior curing performances were observed due to a decrease in the double bond densities. Furthermore, the large-volume branched chain structures in monofunctional monomers and ethyoxyl groups in polyfunctional monomers effectively decreased the volume contraction, improving the adhesion performances of UV-curable alumina suspensions and facilitating the conversion of double bonds to provide excellent curing properties, further guaranteeing strong adhesion of these suspensions to the substrate.     

忠武输气管道悬索跨越设计创新及探讨

忠武输气管道有4次悬索跨越,分别是蚂蝗溪悬索跨越、木龙河悬索跨越、马水河悬索跨越、野三河悬索跨越。文章介绍了这几座悬索跨越管桥设计中采用的多项新技术,如采用热聚乙烯半平行钢丝索代替以往的钢丝绳;采用钢管塔架代替以往的角钢塔架;根据地形地貌特点变换风索型式或取消塔架等。这些新技术、新设计在工程中均取得了良好的效果。另外,文章还针对悬索跨越桥面结构型式、预拱度设置、不对称荷载的影响、风索基础的设置等问题进行了探讨。     

重介选煤厂自动化控制系统

介绍了重介选煤厂实现全自动控制的系统原理及所能实现的各项功能。     

从烟草悬浮细胞中分离液泡前体的方法研究

通过跟踪含有液泡前体特异标记物的组分, 利用细胞壁酶水解胞壁制造原生质体, 并用真针头挤压的方法裂解细胞, 用蔗糖密度梯度离心的方法分离液泡前体. 通过相差显微镜观察, 发现所分离的液泡前体保持完整的结构. 利用不同细胞器的标记物抗体进行免疫标记检测, 证明所纯化的液泡前体不含其他细胞器, 具有较高的纯度.     

丙烯酸2-乙基己酯与醋酸乙烯酯共聚合成高吸油性树脂的研究

以丙烯酸2－乙基己酯与醋酸乙烯酯为单体，采用悬浮聚合法，以单体自交联制得高吸油性树脂。对影响其吸油性能的多种因素，如单体配比、引发剂、油水相比的用量等，进行了系统的研究，得到的高吸油性树脂吸苯最高达16．1g/g，吸甲苯为14．8g/g，吸环己烷为13．3g/g，吸煤油为12．5g/g，可用于河面、海洋浮油的回收及工厂废水处理等领域.     

树脂悬浮光度法测定微量银

在ｐＨ６．９的缓冲溶液中，银与硫代米Ｃｈｉ酮（ＴＭＫ）形成的螯合物在树脂甘油相中悬浮富集，用光度法测定银在波长４６１ｎｍ处有最大吸收，银在０～６μｇ／１０ｍＬ范围内遵守比尔定律，可用于样品中微量银的测定。     

Kinetic analysis for effect of initial substrate concentration on growth and secondary metabolite production in cultures of Nicotiana tabacum

Suspension cultures of tobacco cells were studied using airlift and rotary-drum bioreactors. The effect of initial concentrations of a major substrate, sucrose, on the growth and production of a secondary metabolite, phenolic compounds, was investigated. The dry weights and total concentrations of the phenolic compounds increased with the initial sucrose concentration in both bioreactors. Both bioreactors were found to have the same tendency for the effect of initial sucrose concentration. The structured model, presented previously was modified by considering that sucrose was hydrolyzed to glucose and fructose by an enzymatic reaction. The previous and the new models were applied to the above two sets of experimental data obtained with two bioreactors, independently. The hydrolysis of sucrose was elucidated to contribute slightly to the overall kinetics of growth and secondary metabolite production in these cultures. Furthermore, the levels of shear damage in each bioreactor were quantitatively compared based on the death rate constant, k_i, which is one of the model constants.     

消光剂TiO_2悬浮液配制工艺优化

讨论了在配制过程中减少凝聚粒子形成的有效措施。分散系统由分散器和弱搅拌组成 ,悬浮液初始浓度为 5 0 % ,分散时间应在 0 .5h以上。莫诺泵最佳转速在 85r min左右 ,球磨后TiO2 大粒子通过离心机分离出去 ,使产品中的大于 10 μm的凝聚粒子数小于 0 .4个 mg。