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排序方式: 共有2347条查询结果,搜索用时 31 毫秒
1.
Gerasimov Sergey I. Ilyushin Mikhail A. Putis Sergey M. Dushenok Sergey A. Shugalei Irina V. Sudarikov Andrey M. 《含能材料》2022,30(4):370-378
In the present work it is found that the pyrotechnic composition VS-2 can be initiated with flash lamps IFC-500 and EVIS. VS-2 pyrotechnic composition contains 90% of mercury(Ⅱ) 5-hydrazinotetrazolate perchlorate and 10% of optically transparent copolymer of 2-methyl-5-vinyltetrazole and methacrylic acid (PVMT). We have found that the flash lamps make it possible to initiate combustion of VS-2 composition with its transition to detonation both in cylindrical charges placed in brass caps of 5 mm diameter and 2 mm high, and film charges with 10 mm×80 mm in size and surface weights of 60 mg·cm-2 and 90 mg·cm-2, showing ignition delay times 10 μs and 3 μs, respectively. We also measured detonation velocities for VS-2 composition film charges, which were 4375-4505 m·s-1 (of the charge being surface mass 60 mg·cm-2) and 4221-4281 m·s-1 (of the charge being surface mass 90 mg·cm-2) and their blasting action on the aluminum plate. The depths of the normal shock wave imprints at the charge-barrier interface were 0.6-0.7 mm (for surface mass of the film charges 60 mg·cm-2) and 1.2-1.3 mm (for surface mass of the film charges 90 mg·cm-2). 相似文献
2.
Tomasz Pdzinski Katarzyna Grzyb Konrad Skotnicki Piotr Filipiak Krzysztof Bobrowski Chryssostomos Chatgilialoglu Bronislaw Marciniak 《International journal of molecular sciences》2021,22(9)
Within the reactive oxygen species (ROS) generated by cellular metabolisms, hydroxyl radicals (HO•) play an important role, being the most aggressive towards biomolecules. The reactions of HO• with methionine residues (Met) in peptides and proteins have been intensively studied, but some fundamental aspects remain unsolved. In the present study we examined the biomimetic model made of Ac-Met-OMe, as the simplest model peptide backbone, and of HO• generated by ionizing radiation in aqueous solutions under anoxic conditions. We performed the identification and quantification of transient species by pulse radiolysis and of final products by LC-MS and high-resolution MS/MS after γ-radiolysis. By parallel photochemical experiments, using 3-carboxybenzophenone (CB) triplet with the model peptide, we compared the outcomes in terms of short-lived intermediates and stable product identification. The result is a detailed mechanistic scheme of Met oxidation by HO•, and by CB triplets allowed for assigning transient species to the pathways of products formation. 相似文献
3.
Fanbo Meng Mingchang Zhang Jin Huang Wen Feng Lu Jun Min Xue Hao Wang 《Advanced functional materials》2021,31(9):2008280
The development of the Internet of things has prompted an exponential increase in the demand for flexible, wearable devices, thereby posing new challenges to their integration and conformalization. Additive manufacturing facilitates the fabrication of complex parts via a single integrated process. Herein, the development of a multinozzle, multimaterial printing device is reported. This device accommodates the various characteristics of printing materials, ensures high-capacity printing, and can accommodate a wide range of material viscosities from 0 to 1000 Cp. Complete capacitors, inclusive of the current collector, electrode, and electrolyte, can be printed without repeated clamping to complete the preheating, printing, and sintering processes. This method addresses the poor stability issue associated with printed electrode materials. Furthermore, after the intercalation of LiFePO4 with Na ions, X-ray photoelectron spectroscopy and X-ray diffraction results reveal that the Na ions permeate the interlayer structure of LiFePO4, enhancing the ion migration channels by increasing the ion transmission rate. A current rate of 2.5 mAh ensures >2000 charge/discharge cycles, while retaining a charge/discharge efficiency of 96% and a discharge capacity of 91.3 mAh g−1. This manufacturing process can provide conformal power modules for a diverse range of portable devices with various shapes, improving space utilization. 相似文献
4.
近年来,我市因雷击而导致搅拌站系统瘫痪停产、影响工程进度的事件时有发生,在针对混凝土搅拌站配料秤的实际检定工作中,也常发现配料秤的称重传感器因雷击损坏而影响计量准确性。因此,对混凝土搅拌站防雷的研究具有重要意义。本文阐述了雷电对混凝土搅拌站的主要危害,分析了混凝土搅拌站常见的雷击原因及其防护措施,旨在引起生产方、安装方以及使用方对混凝土搅拌站防雷的共同重视。 相似文献
5.
对我国常用的闭口闪点测定方法宾斯基-马丁闭口杯法、阿贝尔闭口杯法和泰格闭口杯法的测定原理进行对比分析,并采用这3种方法分别对2种有证标准样品、4种有机试剂样品和7种喷气燃料样品的闭口闪点进行测定。结果表明:这3种方法在适用范围、仪器结构、升温速率和点火操作要求等方面都有一定差异,导致采用这3种方法测定同一样品的闭口闪点结果略有差异,闪点测定结果之间的最大差值与样品闪点的高低呈正相关;与阿贝尔闭口杯法相比,宾斯基-马丁闭口杯法测得的闪点结果较高,对于3号喷气燃料,二者之差为0~1.0 ℃,阿贝尔闭口杯法更适合3号喷气燃料闭口闪点的测定;对于纯有机试剂样品,阿贝尔闭口杯法和宾斯基-马丁闭口杯法测得的闪点结果呈现较好的线性关系。 相似文献
6.
7.
Xianjing Jia Yunfeng Yan A. Basak Kayitmazer Yongsheng Li Yisheng Xu 《Advanced functional materials》2021,31(32):2100452
Photothermal-chemotherapeutic nanoparticles (NPs) are attracting increasing attention and becoming more widely used for cancer therapy in the clinic due to their noninvasiveness, notable tissue penetration abilities, and low systemic adverse effects. However, functional ligands are conventionally modified onto photothermal NPs to well stabilize the inorganic particles suffering from complex chemical modifications, low productivity, and batch-to-batch inconsistencies, and thus significantly restricting their clinical applications. Herein, flash nanoprecipitation (FNP) is taken advantage of to afford rapid and uniform mixing for generating local supersaturated CuS clusters for small and highly stable CuS NPs effectively stabilized by polyacrylic acid through a continuous strategy. It greatly reduces the complexity for CuS NPs synthesis and functionalization in a facile intensified mixing process. These as-synthesized particles are high-drug loading, scalable, and most importantly, it is easy to control their sizes and charges through external conditions. Toxicity and tumor inhibition experiments confirm the high cell toxicity and good suppression of tumor growth under near-infrared irradiation indicating a promising prospect of FNP in the large-scale and continuous yielding of highly stable and high-performing photothermal-chemotherapeutic NPs for cancer therapy. 相似文献
8.
《Ceramics International》2020,46(8):11622-11630
In the last decades, the production of ultra-high temperature composites with improved thermo-mechanical properties has attracted much attention. This study focuses on the effect of graphite nano-flakes addition on the microstructure, densification, and thermal characteristics of TiB2–25 vol% SiC composite. The samples were manufactured through spark plasma sintering process under the sintering conditions of 1800 °C/7 min/40 MPa. Scanning electron microscopy images demonstrated a homogenous dispersion of graphite flakes within the TiB2–SiC composite causing a betterment in the densification process. The thermal diffusivity of the specimens was gained via the laser flash technique. The addition of graphite nano-flakes as a dopant in TiB2–SiC did not change the thermal diffusivity. Consequently, the remarkable thermal conductivity of TiB2–SiC remained intact. It seems that the finer grains and more interfaces obstruct the heat flow in TiB2–SiC–graphite composites. Adding a small amount of graphite nano-flakes enhances the densification of the mentioned composite by preventing the grain growth. 相似文献
9.
Harry Charalambous Shikhar Krishn Jha Kent Harrison Christian Ryan Thomas Lay Thomas Tsakalakos 《Journal of the European Ceramic Society》2018,38(10):3689-3693
In conventional flash sintering, the current rises nonlinearly to a set current limit, accompanied by a spike in the power density. This sudden power spike may cause hot spot formation, in which current preferentially channels through a small area, causing localized melting while other areas remain unsintered. By using a controlled current ramp early on the sudden power spike can be avoided. In addition, by changing the ramp rate material properties such as porosity, grain size and conductivity can be tuned. 相似文献
10.
以高速摄影技术作为主要研究手段,研究钢轨交流闪光焊接过程过梁爆破特征,并结合热成像系统采集焊接过程温度场,以此为数据基础定量分析了钢轨交流闪光焊接过梁爆破特征. 结果表明,钢轨交流脉动闪光焊接工艺模式下,加速闪光阶段具有几个阶段中最高的闪光频次46.93次/s,脉动闪光阶段具有最低的闪光频次11.07次/s;连续闪光阶段闪光烈度为0.009 2 mm/次,是几个阶段中最强的,脉动阶段的闪光烈度最弱,为0.003 8 mm/次;从闪光加热因子来看,脉动阶段最高,符合了该阶段积累热量的主要目的;加速闪光阶段最低,是由于该阶段为了制造保护气氛产生的气化过梁带走了较多的热量;从闪光均匀度看,闪光最不均匀的阶段是闪平阶段,最均匀的阶段是脉动阶段,这恰恰说明了两待焊端面的微观平行情况在闪平阶段最差、脉动阶段最佳. 相似文献