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| 苦味酸铋的合成、分解反应动力学及热安全性(英文) | |
| 引用本文： | 任莹辉,仪建华,赵凤起,陈智群,胡荣祖,宋纪蓉.苦味酸铋的合成、分解反应动力学及热安全性(英文)[J].火炸药学报,2010,33(5). |
| 作者姓名： | 任莹辉 仪建华 赵凤起 陈智群 胡荣祖 宋纪蓉 |
| 作者单位： | 1. 西北大学化工学院/陕西省物理无机化学重点实验室,陕西,西安,710069;燃烧与爆炸国家级重点实验室/西安近代化学研究所,陕西,西安,710065 2. 燃烧与爆炸国家级重点实验室/西安近代化学研究所,陕西,西安,710065 3. 西北大学化工学院/陕西省物理无机化学重点实验室,陕西,西安,710069;故宫博物院文保科技部,北京,100009 |
| 基金项目： | The National Natural Science Foundation of China(No.20803058),2008 Equipment |
| 摘 要： | 合成了苦味酸铋配合物(Bi-PA),对其结构进行了表征,并用TG-DTG及DSC技术研究了化合物的热行为和分解反应动力学。结果表明,在TG曲线上出现一个最大的失重阶段,对应于DSC曲线上的最大放热峰。放热分解反应过程可以认为是化学反应,其机理方程的微分式为f(α)=3(1-α)-ln(1-α)]2/3,动力学方程为dα/dt=1013.51(1-α)-ln(1-α)]2/3e-1.96×104/T。反应阶段的活化熵(ΔS≠),活化焓(ΔH≠)及活化自由能(ΔG≠)分别为2.25J.mol-1.K-1,159.82kJ.mol-1及158.60kJ.mol-1。 |
| 关 键 词： | 物理化学 苦味酸铋 热行为 分解反应动力学 热安全性 |
Synthesis,Decomposition Reaction Kinetics and Thermal Safety of Bismuth Complex of Picric Acid |
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| REN Ying-hui,YI Jian-hua,ZHAO Feng-qi,CHEN Zhi-qun,HU Rong-zu,SONG Ji-rong.Synthesis,Decomposition Reaction Kinetics and Thermal Safety of Bismuth Complex of Picric Acid[J].Chinese Journal of Explosives & Propellants,2010,33(5). | |
| Authors: | REN Ying-hui YI Jian-hua ZHAO Feng-qi CHEN Zhi-qun HU Rong-zu SONG Ji-rong |
| Abstract: | The bismuth complex of picric acid(Bi-PA) was prepared and characterized,and its thermal behaviors,non-isothermal decomposition reaction kinetics were investigated by thermogravimetry and derivative thermogravimetry(TG-DTG),and differential scanning calorimetry(DSC).The results show that there is one mass loss stage in the TG curve,which is corresponding to one exothermic peak on a DSC curve.The reaction mechanisms of the exothermal decomposition processes is classified as chemical reaction,the mechanism fu... |
| Keywords: | physical chemistry bismuth complex of picric acid thermal behaviors decomposition reaction kinetics thermal safety |
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