| PC/HBPS共混物的流变性能 |
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| 引用本文： | 李爱英,常杰云,王凯全,陆路德,杨绪杰,汪信.PC/HBPS共混物的流变性能[J].高分子材料科学与工程,2006,22(3):149-151. |
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| 作者姓名： | 李爱英 常杰云 王凯全 陆路德 杨绪杰 汪信 |
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| 作者单位： | 1. 南京理工大学化工学院,江苏,南京,210094
2. 江苏工业学院,江苏,常州,213016 |
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| 摘 要： | 通过熔融共混法制备了PC/HBPS共混物,研究了其流变特性。结果表明,此共混物属于假塑性流体,随着HBPS含量的增加,非牛顿指数增加;随着剪切速率的增加,表观黏度下降,但下降趋势较缓慢;随着温度的增加,表观黏度下降,但下降趋势很快;共混物的粘流活化能都比纯PC的粘流活化能高;随着HBPS含量的增加,表观黏度下降。
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| 关 键 词： | 高支化聚苯乙烯 聚碳酸酯 共混物 流变性能 |
| 文章编号： | 1000-7555（2006）03-0149-03 |
| 收稿时间： | 2005-12-05 |
| 修稿时间： | 2006-01-18 |
RHEOLOGICAL BEHAVIORS OF POLYCARBONATE AND HIGHLY BRANCHED POLYSTYRENE BLENDS |
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| LI Ai-ying,CHANG Jie-yun,WANG Kai-quan,LU Lu-de,YANG Xu-jie,WANG Xing.RHEOLOGICAL BEHAVIORS OF POLYCARBONATE AND HIGHLY BRANCHED POLYSTYRENE BLENDS[J].Polymer Materials Science & Engineering,2006,22(3):149-151. |
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| Authors: | LI Ai-ying CHANG Jie-yun WANG Kai-quan LU Lu-de YANG Xu-jie WANG Xing |
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| Affiliation: | 1. College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; 2. Jiangsu Polytechnic University, Changzhou 213016, China |
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| Abstract: | Rheological characteristics of polycarbonate and highly branched polystyrene(PC/HBPS-1) blends prepared by melt blending were studied.Results show that the PC/HBPS-1 blends belong to the pseudo-plastic liquids.The non-Newtonian index of the PC/HBPS-1 blends is increased with the increase of HBPS-1 content.The apparent viscosity of the PC/HBPS-1 blends is decreased with the increase of shear rate and temperature,at the same time,the decreased trend of shear rate is slow and that of temperature is soon.The viscous activation energy of the PC/HBPS-1 blends is higher than that of pure PC.The apparent viscosity of the PC/HBPS-1 blends is decreased with the increase of HBPS-1 content. |
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| Keywords: | highly branched polystyrene polycarbonate blends rheological properties |
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