| 5-氯-2，3-二氢-2-羟基-1-氧代-1H-茚-2-羧酸甲酯合成研究进展 |
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| 引用本文： | 朱玉青,余生,胡新根,陈帆.5-氯-2，3-二氢-2-羟基-1-氧代-1H-茚-2-羧酸甲酯合成研究进展[J].辽宁化工,2009,38(3):180-184. |
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| 作者姓名： | 朱玉青 余生 胡新根 陈帆 |
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| 作者单位： | 温州大学化学与材料工程学院,浙江,温州,325035 |
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| 摘 要： | 综述了5-氯-2，3-二氢-2-羟基-1-氧代-1H-茚-2-羧酸甲酯的各种合成方法。认为研究开发基于手性配体的金属催化剂是提高产品ee值和产率的重要发展途径。
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| 关 键 词： | 5-氯-2 3-二氢-2-羟基-1-氧代-1H-茚-2-羧酸甲酯 茚虫威 杀虫剂 |
Progress in Synthesis of 5-Chloro-1-Oxo-2,3-Dihydroindene-2-Carboxylate |
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| ZHU Yu-qing,YU Sheng,HU Xin-gen,CHEN Fan.Progress in Synthesis of 5-Chloro-1-Oxo-2,3-Dihydroindene-2-Carboxylate[J].Liaoning Chemical Industry,2009,38(3):180-184. |
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| Authors: | ZHU Yu-qing YU Sheng HU Xin-gen CHEN Fan |
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| Affiliation: | School of Chemistry and Material Engineering;Wenzhou University;Wenzhou 325035;China |
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| Abstract: | The synthesis of the intermediate:(+) 5-chloro-1-oxo-2,3-dihydroindene-2-carboxylate is the key step in the whole synthesis process of the new pesticide indoxacarb.This reaction step produces chiral molecule structure.The enantiomeric excess and insecticidal activity depend upon the asymmetry of the reaction.In this paper,the current progress of the synthesis of(+) 5-chloro-1-oxo-2,3-dihydroindene-2-carboxylate have been reviewed.It is considered that the development of metallic catalysts based on polydenta... |
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| Keywords: | 5-chloro-1-oxo-2 3-dihydroindene-2-carboxylate Indoxacarb Insecticide Preparation |
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