| 无底单室电解溶样法测不锈钢的主要组分含量 |
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| 引用本文： | 杨桂珍,杨建男,陈伟珍.无底单室电解溶样法测不锈钢的主要组分含量[J].广州化工,2010,38(6):152-154. |
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| 作者姓名： | 杨桂珍 杨建男 陈伟珍 |
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| 作者单位： | 广东高校新材料工程技术开发中心,湛江师范学院化学科学与技术学院,广东,湛江,524048 |
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| 基金项目： | 湛江师范学院自然科学科研项目 |
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| 摘 要： | 以无底单室电解池作采集器,根据电解原理和Faraday定律,由待分析的不锈钢样品元素含量确定其近似的电化学摩尔质量(k),选择合适的电解条件使其电解效率为100%,用Faraday定律直接计算被采集的样品质量,结合ICP—AES法快速测定不锈钢样品中的Fe、Cr、Ni、Mn等主要组分的含量。而电解法溶样后用ICP—AES法测定的含量与已知的样品含量较为一致;可见该方法是可行的。
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| 关 键 词： | 无底单室电解池 不锈钢 ICP—AES |
Determination of the Main Components of Stainless Steel with Bottomless Single Compartment Electrolytic Dissolution |
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| YANG Gui-zhen,YANG Jian-nan,CHEN Wei-zhen.Determination of the Main Components of Stainless Steel with Bottomless Single Compartment Electrolytic Dissolution[J].GuangZhou Chemical Industry and Technology,2010,38(6):152-154. |
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| Authors: | YANG Gui-zhen YANG Jian-nan CHEN Wei-zhen |
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| Affiliation: | (Development Center for New Materials Engineering ＆ Technology in Universities of Guangdong,School of ChemistryScience and Technology,Zhanjiang Normal University,Guangdong Zhanjiang 524048,China) |
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| Abstract: | A novel electrolytic method for the dissolution of stainless steel sample was suggested in which the stainless steel sample was acted as anode and the electrolysis was carried out in bottomless single compartment electrolytic cell.The amount of sample was calculated by the Faraday＇s law（m=kIt）,and results in consistency with the certified values were obtained.Discussion and optimization of analytical conditions and parameters were also proposed. |
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| Keywords: | ICP-AES |
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