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硫酸工业含砷污泥中的重金属测定
引用本文:黄永文,李成国,毕亚凡.硫酸工业含砷污泥中的重金属测定[J].化学与生物工程,2011,28(7):92-94.
作者姓名:黄永文  李成国  毕亚凡
作者单位:1. 宜昌市环境科学研究所,湖北宜昌,443000
2. 湖北洋丰肥业股份有限公司,湖北荆门,448000
3. 武汉工程大学环境与城市建设学院,湖北武汉,430073
摘    要:以某硫酸企业含砷污泥为研究对象,采用现行的浸取方法处理该含砷污泥,并用原子荧光光谱法和火焰原子吸收分光光度法测定其浸出液中的砷和铅、镉、铜、锌等5种重金属含量.结果表明,含砷污泥中砷、铅、镉、铜4种重金属含量均存在超标现象,相对标准偏差在81.1%~103.5%之间,加标回收率在0.05%~0.64%之间.此分析方法简...

关 键 词:硫酸工业  含砷污泥  重金属含量  测定

Determination of Heavy Metal Content of Arsenic Sludge of Sulfuric Acid Industry
HUANG Yong-wen,LI Cheng-guo,BI Ya-fan.Determination of Heavy Metal Content of Arsenic Sludge of Sulfuric Acid Industry[J].Chemistry & Bioengineering,2011,28(7):92-94.
Authors:HUANG Yong-wen  LI Cheng-guo  BI Ya-fan
Affiliation:1.Yichang Institute of Environmental Sciences,Yichang 443000,China;2.Hubei Newyangfeng Fertilizer Stock Co.Ltd.,Jingmen 448000,China;3.School of Environment and Civil Engineering,Wuhan Institute of Technology,Wuhan 430073,China)
Abstract:The arsenic sludge taken from a sulfuric acid enterprise was treated with the current method,then contents of five kinds of heavy metal arsenic,lead,codmium,copper,zinc,which were contained in its leaching solution,were determined by atomic fluorescence spectrometry and flame atomic absorption spectrophotometry.The results showed that,contents of four heavy metals including arsenil,lead,codmium,copper were over the limit.The relative standard deviations were 0.05%~0.64%,and the recoveries were 81.1%~103.5%.This analysis method is simple,sensitive,accurate and suitable for determination of heavy metal content of arsenic sludge and other solid industrial wastes of sulfuric acid industry.
Keywords:sulfuric acid industry  arsenic sludge  heavy metal content  determination
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