新型耐磨耐高温氧化NiCrAlSiC复合涂层的制备及性能研究

采用"电泳+电沉积"两步法在金属基体上先预沉积CrAlSiC电泳层,再电沉积Ni,制备了NiCrAlSiC复合涂层,并制备不含SiC的NiCrAl涂层为对比样品。采用XRD、SEM、EPMA和TEM对复合涂层进行形貌、结构和成分表征,并研究其高温氧化性能和摩擦磨损性能。结果表明:复合涂层致密并与基体结合良好,涂层内颗粒分散均匀。与不含SiC的NiCrAl复合涂层相比,NiCrAlSiC复合涂层的氧化膜由NiO、NiAl2O4和Al2O3三层结构转变为NiAl2O4和Al2O3两层结构,且氧化膜更薄;同时,涂层硬度提高26%,磨损速率下降52%,磨损机制由磨粒磨损转变为黏着磨损。SiC颗粒的加入同时提高了NiCrAl涂层的抗高温氧化性能和耐磨性能。

Preparation and Performance of a Novel Wear-Resistant and High Temperature Oxidation-Resistant NiCrAlSiC Composite Coating

ZHAO Mingyu;ZHEN Huijuan;DONG Zhihong;YANG Xiuying;PENG Xiao(Shenyang Institute of Technology,Fushun 113122,China;Laboratory for Corrosion and Protection,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;School of Materials Science and Engineering,University of Science and Technology of China,Shenyang 110016,China;School of Materials Science and Engineering,Nanchang Hangkong University,Nanchang 330063,China)