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壳聚糖季铵盐处理对真丝纤维结构与性能的影响
引用本文:张伟,林红,路艳华,陈宇岳,葛迪新.壳聚糖季铵盐处理对真丝纤维结构与性能的影响[J].印染,2007,33(1):8-10.
作者姓名:张伟  林红  路艳华  陈宇岳  葛迪新
作者单位:苏州大学材料工程学院,江苏,苏州,215021
摘    要:采用两种不同分子量的壳聚糖合成了水溶性壳聚糖季铵盐(HTCC),并对经HTCC溶液处理后桑蚕丝的聚集态结构和力学性能进行研究。结果表明,壳聚糖合成HTCC的取代反应主要发生在壳聚糖的氨基上;经HTCC溶液处理后,普通桑蚕丝的断裂强度和伸长率增大,结晶度提高,热稳定性增强。

关 键 词:功能性整理  壳聚糖  季铵盐  蚕丝
文章编号:1000-4017(2007)01-0008-03
修稿时间:2006-10-19

Effects of chitosan quaternary ammonium on structure and properties of silk fiber
ZHANG Wei,LIN Hong,LU Yan-hu,CHEN Yu-yue,GE Di-xin.Effects of chitosan quaternary ammonium on structure and properties of silk fiber[J].Dyeing and Finishing,2007,33(1):8-10.
Authors:ZHANG Wei  LIN Hong  LU Yan-hu  CHEN Yu-yue  GE Di-xin
Affiliation:College of Material Engineering, Soochow University, Suzhou 215021, China
Abstract:Two chitosans with different molecular weight are used to prepare water-based chitosan quaternary ammonium salt(HTCC),application process of HTCC sulution to mulberry silk fiber is undergone.The structure of aggregated state and mechanical properties of treated silk fiber are investigated.Results show that the substitution reaction occurred mainly on the amine groups of chitosan.The treated silk fabric features higher breaking strength,elongation percentage,crystallinity,and the thermodynamic stability as well.
Keywords:functional finishing  chitosan  ammonium salt  real silk
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