UHMWPE基复合材料在干摩擦和油田污水条件下的摩擦磨损性能

采用模压烧结法制备了超高分子量聚乙烯(UnMWPE)/聚苯酯(Ekonol)复合材料;采用45#钢为摩擦对偶件的往复滑动式摩擦磨损试验机,在室温下测试了Ekonol含量对UHMWPE在干摩擦和油田污水条件下的摩擦磨损性能影响,实验条件为:接触压力7.5 kN、滑动速度1.8 m/min、时间3 h;采用扫描电子显微镜观察复合材料磨损表面形貌并分析了磨损机制.结果表明:填充加%Ekonol可以显著改善UHMWPE的摩擦磨损性能.与干摩擦条件相比,在油田污水条件下,UHMWPE基复合材料摩擦因数提高不明显,但磨损率明显增大;在干摩擦条件下,纯UHMWPE的磨损机制主要为粘着和犁沟效应,UHMWPE/Ekonol复合材料的磨损机制为粘着和疲劳,而在油田污水条件下UHMWPE/Ekonol复合材料的磨损机制主要为磨粒磨损和疲劳.     

水润滑条件下高岭土填充UHMWPE基复合材料的摩擦学特性

分别用釜内聚合和机械混合两种方法制备高岭土填充UHMWPE基复合材料,对其在水润滑条件下的滑动摩擦磨损特性进行了试验研究,并通过对磨损表面形貌的观察分析,对材料的磨损机理进行了探讨.结果发现,水润滑对UHMWPE/Kaolin?5钢摩擦副的减磨(摩)作用显著;填充适量高岭土可以明显提高UHMWPE在水润滑条件下的摩擦磨损性能;釜内聚合方法制备的UHMWPE/Kaolin的磨损率相对较低,具有广阔的应用前景.     

纳米锌填充超高分子量聚乙烯复合材料微动摩擦磨损性能

利用热压烧结法制备不同含量纳米锌填充超高分子量聚乙烯(UHMWPE)复合材料,采用微动摩擦磨损试验机研究干摩擦条件下纳米锌含量对复合材料微动摩擦磨损性能的影响。利用场发射扫描电子显微对复合材料断面进行分析,采用扫描电子显微镜对材料磨损表面及钢球进行表征,探讨复合材料的磨损机制。研究结果表明:随着纳米Zn含量的增加,复合材料的摩擦因数和磨损率均表现为先降低后升高;当纳米Zn质量分数为1%时复合材料具有最低的摩擦因数和磨损率,且对偶钢球表面形成连续的转移膜;复合材料的磨损机制主要为黏着磨损和磨粒磨损。添加锌纳米颗粒,可以提高UHMWPE复合材料的微动摩擦磨损性能,当纳米锌质量分数为1%时,复合材料具有最低的摩擦因数和最优的耐磨损性能。     

聚丙烯、炭黑和碳纤维共混填充超高分子量聚乙烯复合材料的力学和摩擦磨损性能

采用模压成型的方式制备超高分子量聚乙烯(UHMWPE)复合材料,通过AG-1型电子万能实验机和MM-200型摩擦磨损试验机分别研究填料对复合材料力学性能和摩擦磨损性能的影响,采用光学显微镜分析复合材料磨损表面的形貌。结果表明:聚丙烯(PP)和无机填料炭黑(CB)或CB与碳纤维(CF)混杂填料的加入使UHMWPE复合材料的拉伸强度降低,弯曲模量和硬度增加,其中UHMWPE/PP/CB/CF复合材料的弯曲模量和硬度增幅大于UHM-WPE/PP/CB复合材料。填料的加入可改善UHMWPE复合材料的摩擦磨损性能,当填料的质量分数为5%时,UHMWPE复合材料的摩擦磨损性能最好,且UHMWPE/PP/CB/CF复合材料的耐磨性能优于UHMWPE/PP/CB复合材料。与UHM-WPE相比,UHMWPE/PP/CB/CF复合材料的摩擦因数和磨痕宽度分别下降了10%和44%,UHMWPE/PP/CB复合材料则分别下降了12%和42%。光学显微镜观察表明填料的加入大大改善了UHMWPE的磨粒磨损,复合材料表面以较浅的犁沟磨损为主要特征。     

基于UHMWPE/纳米ZnO复合材料的滑动摩擦磨损机制

用热压成型法制备了超高分子量聚乙烯(UHMWPE)纳/米ZnO复合材料,采用销盘式摩擦磨损试验机考察了载荷和相对滑动线速度对复合材料摩擦学性能的影响;采用扫描电子显微镜观察了复合材料磨损表面形貌。结果表明:在低载荷试验条件下磨损机制为粘着磨损,在高载荷试验条件下磨损机制为粘着磨损和疲劳磨损。而在一定载荷试验条件下,无论相对滑动线速度高或低,复合材料的磨损机制主要表现为粘着磨损,只是在高速情况下粘着磨损程度加大,局部还出现了表面撕裂的痕迹。     

纳米SiO_2、玻璃微珠共混改性UHMWPE复合材料空蚀性能研究

通过模压成型工艺制备纳米SiO2、玻璃微珠颗粒共混改性UHMWPE复合材料,采用MRH-5A型环块磨损试验机研究载荷以及玻璃微珠含量对UHMWPE复合材料摩擦磨损性能的影响,利用转盘式空蚀磨损试验装置对复合材料进行空蚀磨损试验。结果表明,适量的纳米SiO2和玻璃微珠颗粒填充可以提高UHMWPE硬度,有效地改善UHMWPE的摩擦磨损性能和抗空蚀性能,质量分数10%纳米SiO2和2%玻璃微珠改性UHMWPE复合材料抗空蚀性能是纯UHM-WPE的3倍。     

SiCp增强铝基复合材料与Kevlar增强摩擦材料摩擦副摩擦磨损机理研究

采用盘销式摩擦磨损试验机，对SiCp含量为20vol％的铝基复合材料和Kevlar增强摩擦材料组成的摩擦副在于摩擦条件下的摩擦磨损机理进行了实验研究。结果表明：摩擦副在跑合过程中，铝基复合材料中的SiCp颗粒对较软的有机复合材料产生犁削和微观切削效应，磨损机理为铝基复合材料的硬质颗粒对较软的有机复合材料的磨粒磨损；在跑合后的磨损试验中，摩擦材料磨损表面呈现出粘着磨损和塑性变形特征，随着转动速度的增加，塑性流动加剧；摩擦副接触表面发生材料的相互转移，并在铝基复合材料表面形成转移膜，且在较高速度下转移膜更易形成；在高速条件下，摩擦材料表面可见从铝基复合材料的铝合金基体中脱离的SiCp颗粒和熔融迹象；摩擦材料的磨损机理主要为磨粒磨损、粘着磨损和塑性变形。     

填充纳米SiO2对超高分子量聚乙烯复合材料摩擦磨损性能的影响

用热压成型法制备了纳米SiO2填充超高分子量聚乙烯(UHMWPE)复合材料,采用销-盘式摩擦磨损试验机考察了纳米粒子对复合材料摩擦磨损性能的影响,采用扫描电子显微镜观察了复合材料磨损表面形貌,并借助X射线能谱仪对试样磨损表面进行了微区分析。结果表明:纯UHMWPE磨损表面局部存在着大量的粘着变形和疲劳裂纹的特征,填充15%(质量分数)的纳米SiO2能较好地改善UHMWPE/nano-SiO2复合材料的摩擦磨损性能,其磨损表面只存在粘着撕裂现象,看不到疲劳裂纹特征。当填充纳米SiO2质量分数达到20%时,其磨损表面存在贫Si区和富Si区,同时磨损表面呈现出热裂纹迹象,复合材料的耐磨性能改善程度明显下降,并且摩擦因数出现了增大趋势。     

石墨填充聚四氟乙烯基复合材料的摩擦学性能

为了研制PTFE基粘弹-摩擦型阻尼材料,采用机械共混-冷压成型-烧结的工艺制备了石墨、聚苯硫醚、聚醚醚酮混合填充PTFE基复合材料,利用环-块式磨损试验机,在干摩擦条件下考察了复合材料的摩擦学性能,并用扫描电镜观察了磨损表面形貌,研究了复合材料的磨损机制。结果表明:PTFE含量不同的复合材料,随石墨填充量的增大,摩擦因数和磨损率的变化趋势不同,磨损主要由犁削、粘着和疲劳剥落中的一种或几种引起;适当配比的PTFE基复合材料具有较好的摩擦阻尼性能,能够满足粘弹-摩擦阻尼材料的要求。     

碳纤维增强杂萘联苯聚醚砜酮复合材料的摩擦学性能研究

利用MRH-03型环-块摩擦磨损试验机研究不同碳纤维含量的聚醚砜酮(PPESK)基复合材料的摩擦磨损性能,讨论载荷、速度及润滑介质对质量分数10%碳纤维增强复合材料摩擦磨损性能的影响,并用SEM观察材料的断面形貌和磨损表面形貌。结果表明：适量碳纤维的加入可以明显提高材料的摩擦磨损性能,并使得复合材料干摩擦条件下的磨损机制由严重的磨粒磨损和黏着磨损转变为黏着磨损和轻微的磨粒磨损。以质量分数10%碳纤维增强的复合材料为例,随着载荷的增加复合材料在干摩擦条件下的摩擦因数降低,而磨损率先降低后增加,在高滑动速度下复合材料的摩擦因数降低而磨损率增加;而海水润滑介质的加入大大降低了材料的摩擦因数和磨损率,并使得复合材料的磨损机制由干摩擦条件下的黏着磨损和轻微的磨粒磨损转变为轻微的磨粒磨损。     

基于SOM神经网络的摩擦状态识别研究

为提取摩擦振动的特征和实现摩擦副摩擦状态的识别,在往复摩擦磨损试验机进行摩擦副混合摩擦和干摩擦状态的摩擦磨损试验。应用谱减法对试验采集的摩擦振动信号进行降噪,计算降噪后的摩擦振动15个特征参数。应用自组织映射(Self-organizing map, SOM)神经网络对摩擦副不同摩擦状态的摩擦振动特征参数进行分析,得到摩擦振动的SOM神经网络神经元分类。研究结果表明,谱减法能消除摩擦磨损试验机的背景噪声,SOM神经网络算法能够有效分析摩擦振动信号的特征,实现摩擦副摩擦状态的识别。     

炭黑及丙烯腈含量对丁腈橡胶磨损机理的影响

丁腈橡胶是一种重要的螺杆泵定子材料.以不同炭黑及丙烯腈含量的丁腈橡胶与45#钢组成的摩擦副为研究对象,采用MPV-600型环-块摩擦磨损试验机,在干摩擦和原油润滑条件下进行摩擦磨损试验,对丁腈橡胶磨损量及摩擦系数进行分析,初步探讨了其磨损机理.从试验结果可以看出,干摩擦条件下丁腈橡胶的磨损量随着载荷的增大而增大,炭黑和丙烯腈含量的增加使丁腈橡胶的耐磨性增强.原油介质下的磨损规律与干摩擦基本相同,丁腈橡胶磨损表面平整,磨损量很小,且原油介质的润滑和冷却作用使橡胶的摩擦系数降低.     

Assessment of friction and wear characteristics of domestic friction composite materials in loaded aircraft brakes

Results of study of the friction and wear characteristics of carbon frictional composite materials used in aircraft brakes are reported. The effect of the reinforcement type and the heat treatment conditions of the materials on their friction coefficient, wear rate, and the stability indicator of the friction coefficient are studied. Also, the effect of water and detergents on the friction and wear of carbon frictional composite materials is discussed, and it is demonstrated that higher density is an effective way of elimination of the negative effect of detergents and considerable reduction of the water effect.     

MgO/SiO2复合纳米添加剂的自修复性能试验研究

以纳米MgO/SiO2作为添加剂,在HQ-1摩擦磨损实验机上进行自修复实验。试验考察载荷、转速、修复时间对纳米MgO/SiO2复合添加剂自修复性能的影响。实验结果表明,纳米MgO/SiO2在适宜的条件下对钢-钢摩擦副磨损金属表面有修复效果,其修复性能受载荷、转速及修复时间等条件影响;纳米MgO/SiO2添加剂对磨痕具有一定的填平作用,在一定程度上能够改善磨痕的粗糙度。     

波动载荷对C/C复合材料/铬青铜摩擦副载流摩擦磨损性能的影响

借助于HST-100高速载流摩擦磨损试验机,研究载荷的波动大小对C/C复合材料/铬青铜摩擦副载流摩擦磨损性能的影响,利用扫描电镜对磨损表面进行观察分析。结果表明:随着载荷波动的加剧,平均电流逐渐减小,载流效率降低,离线率和电弧能量逐渐增大;C/C复合材料的摩擦因数和磨损率均呈现先减小然后增大的趋势;摩擦过程中的磨损机制逐渐由磨粒磨损转变为磨粒磨损、电气磨损共同作用。     

Polyester composite based on betelnut fibre for tribological applications

A polyester composite based on betelnut fibres was fabricated and its adhesive wear and frictional performance studied using a block on disk machine at different applied loads and sliding distances at 2.8 m/s sliding velocity under dry/wet contact conditions. SEM was used to study worn surface morphology. The results revealed that betelnut fibre reinforced polyester (BFRP) composite had better wear and frictional performance under wet contact condition compared to dry. The wear mechanism of the BFRP composite was predominated by micro and macro-cracks in the polyester regions and debonding of fibres.     

Effects of Zinc Borate and Fly Ash on the Mechanical and Tribological Characteristics of Brake Friction Materials

Friction materials based on several combinations of zinc borate (ZB) and fly ash (FA) were fabricated and characterized for their mechanical and tribological performance. The triboperformance of the friction materials was evaluated on a Chase friction testing machine according to the brake lining quality test procedure as per SAE J661. The composites were manufactured based on a nonasbestos organic-based friction material for an automotive brake system and contained typical ingredients for commercial brake friction materials. The composites had a fixed composition of 15 wt% resin, 15 wt% fibers, and 5 wt% friction additives. ZB and FA as fillers were added to the the raw materials mixture at a total fraction of 65 wt%. The results showed that ZB and FA contents have a significant influence on the mechanical and tribological properties of the friction composites. In particular, the composites containing 0–5 wt% ZB and 65–60 wt% FA showed better friction stability and improved fade resistance compared to those containing 10–35 wt% ZB and 55–30 wt% FA, whereas the composite with 5 wt% ZB and 60 wt% FA showed a maximum friction coefficient. On the other hand, the specific wear rate of the composites decreased with increasing ZB and decreasing FA contents. The morphologies of the worn surfaces as well as wear debris were analyzed by means of scanning electron microscopy.     

配副材料对碳纤维增强环氧树脂复合材料摩擦学性能的影响

采用铺层/热压烧结的方法制备交叉铺层的碳纤维增强环氧树脂复合材料,探究配副材料及载荷对铺层材料摩擦学性能的影响,并探讨复合材料的磨损机制。结果表明:随着载荷的增加,复合材料的摩擦因数逐渐降低,磨损率则逐渐增加;在研究的载荷下,复合材料与轴承钢配副时摩擦因数较低,而与Si₃N₄和Al₂O₃陶瓷球配副时润滑性能较差;在低载荷下复合材料与轴承钢配副时磨损率较高,高载荷下则相反。磨损表面形貌分析显示:当施加的载荷较低时,磨损表面形貌主要为犁沟及少量裂纹,磨损机制主要为磨粒磨损;当载荷较高时,高的接触应力使磨损表面产生了大量裂纹并伴随树脂基体脱落,磨损机制由磨粒磨损转变为疲劳磨损。     

磨损间隙调整式环块摩擦试验机的研制

为了优选橡胶材料和掌握其摩擦磨损机制,以提高橡胶衬套材料的耐磨性和液体介质输送设备的使用寿命,研制一台磨损间隙调整式环块摩擦试验机。该试验机可通过加载机构可实现对橡胶试块的垂直加载或橡胶试块与摩擦环之间的间隙调整,并可实现干摩擦和含固体颗粒黏稠液体介质润滑下金属摩擦环与橡胶之间的摩擦磨损试验。利用该试验机对丁腈橡胶在不同磨损间隙下的摩擦磨损性能进行测试。试验结果表明,该试验机在过盈配合及不同磨损间隙下均具有较高的试验精度。     

Effect of rubber component on the performance of brake friction materials

Various composite friction materials containing 40 vol.% organic binder (phenolic resin plus styrene–butadiene–rubber (SBR)) with varying phenolic-resin/SBR ratio were prepared. The content of phenolic resin in each composite was indicated by the resin value (RV) index ranging between 0 and 100%. The composites with RVs greater than 50% form resin-based friction materials in which the primary binder is the phenolic resin. For RVs less than 50%, the composites become the rubber-based materials where the primary binder is the SBR. The analysis of mechanical properties exhibited that the conformability of the composites increases upon incorporation of SBR. The frictional analysis revealed that type of polymeric binder, i.e. resin or rubber, dominates greatly the frictional behavior of the composites. The increment of friction force and higher improvement in the frictional fade and recovery with sliding velocities are the general features of rubber-based friction materials. It was attributed to the inherent properties of rubber on the viscoelastic response at higher sliding velocities and entropic contribution on the mechanical properties at higher temperatures. The wear rate of resin-based materials and its drum temperature is lower than those of rubber-based materials. It was attributed to the strongly adhered multilayer secondary plateaus formed on the surface of resin-based materials.