Void fraction in vertical gas-liquid slug flow: Influence of liquid slug content

In this study we develop a model for computing the mean void fraction and the liquid slug void fraction in vertical upward gas-liquid intermittent flow. A new model for the rate of gas entrained from the Taylor bubble to the liquid slug is formulated. It uses the work done by the pressure force at the rear of the Taylor bubble. Then an iterative approach is employed for equating the gas entrainment flux and the gas flux obtained via conservation equations. Model predictions are compared with experimental data. The developed iterative method is found to provide reasonable quantitative predictions of the entrainment flux and of the void fraction at low and moderate liquid slug void fraction conditions. However, with an increased liquid slug void fraction experimental data indicate that the flow in the liquid slug transits to churn-heterogeneous bubbly flow thus gas entrainment flux tends to zero. Considering this effect in the iterative model significantly improved the predictions for large liquid slug void fraction conditions.     

Slug characteristics of polymer particles in a gas-solid fluidized bed

The slug characteristics (frequency, rising velocity and length) have been determined by analyzing pressure fluctuations in a fluidized bed (0.38 m-I.D.x4.4m-high) of linear-low-density-polyethylene (LLDPE) and polypropylene (PP) particles. The slug characteristics of LLDPE and PP particles have been determined as a function of gas velocity (0.6-1.2 m/s) and the axial height (0.65–1.15 m) from the distributor. The rising velocity and vertical length of slug increase with increasing superficial gas velocity and the axial height of the bed. The slug shape of LLDPE particles is found to be the square-nose whereas that of PP particles is the round-nose. The slug frequency and its length have been correlated in terms of the excess fluidizing velocity, column diameter and bed height based on the data from the present and previous studies.     

Slug flow in curved microreactors: Hydrodynamic study

The need for eco-friendly and energy saving processes which are substantially compact and give higher efficiency has led to the concept of process intensification (PI). Curved microchannel is such innovative device, which has potential for the intensification of processes currently carried out in conventional straight or T-type microchannels. Curved microchannels utilize the benefits of centrifugal force to its advantage. The present study deals with the numerical simulation of the Taylor flow in curved microchannels, particularly on gas and liquid slugs with varying curvature ratios (i.e., coil to tube diameter=5, 10, 20 and 30). The three-dimensional, unsteady slug flow development in the curved microchannel was carried out using control volume finite difference method (CVFDM). The gas and liquid slug lengths at various operating and fluid conditions were obtained. The slug flow development for different inlet conditions and geometries (premixed feed, T-type and Y-type inlets) was also studied in the curved microchannels. It was found that for low curvature ratio (D/d=3), the phenomenon of flow reversal and slug freezing takes place due to centrifugal and buoyancy forces. For the similar process conditions, with an increase in curvature ratio to 5 and 10, the phenomenon of flow reversal and slug freezing observed was very minor. The non-uniformity in the slug formation was observed for low curvature ratio as compared to the higher curvature ratios. Further the influence of surface tension, viscosity and wall adhesion was studied on slug flow development in the curved microchannels. From the results it was observed that the surface tension, viscosity and wall adhesion have significant influence on slug flow development in curved microchannels.     

Formation of liquid–liquid slug flow in a microfluidic T‐junction: Effects of fluid properties and leakage flow

Characteristics of liquid–liquid slug flow are investigated in a microchannel with focus on the leakage flow that bypasses droplets through channel gutters. The results show that the leakage flow rate varies in a range of 10.7–53.5% and 8.3–30.9% of the feed flow rate, during the droplet formation (i.e., at T‐junction) and downstream flow (i.e., in the main channel), respectively, which highly depends on Ca number and wetting condition. Empirical correlations are proposed to predict them for perfectly and partially wetting conditions. Leakage flow contribution is further used to improve the Garstecki model for size scaling in order to extend its suitability for both squeezing and shearing regimes. The instantaneous flow rates of the immiscible phases are found to fluctuate periodically with the formation cycles, but in opposite behavior. The effect of the presence of leakage flow on such fluctuation are investigated and compared with gas–liquid systems. © 2017 American Institute of Chemical Engineers AIChE J, 63: 346–357, 2018     

地形起伏管路气液两相段塞流模型研究

段塞流是气液两相流动中的一种常见流型,由于地形原因,管路多处于起伏状态,而目前国内外对起伏诱发的气液两相管路段塞流研究尚不成熟。针对实际气液两相管路中频繁出现的地形起伏段塞流,首先利用历史数据对现有段塞流模型的适用性进行了比较,建立了地形起伏状态下段塞流的液塞追踪修正模型,最后利用FLUENT软件进行了模拟,研究了管路起伏诱发状况对段塞流段塞分布、拐角处持液率、液塞长度和压降的影响,并将模拟压降与计算压降进行对比,结果表明建立的模型具有一定的精度,对于实际的地形起伏诱发段塞流管道的安全高效运行有一定的指导意义。     

Hydrodynamic studies of liquid–liquid slug flows in circular microchannels

The aim of the work presented was to clarify the existence of a wall film and its influence on the hydrodynamics of liquid–liquid slug flow capillary microreactor.The methodology of the laser induced fluorescence (LIF) was adopted for visualisation purposes. The measurement of the light intensity profiles revealed a fully developed wall film for a variety of aqueous–organic two-phase systems in glass and PTFE capillaries of 1 mm internal diameter. In addition an acid as a quenching agent enabled the observation of the internal circulation patterns within the liquid slugs, as the fluorescent dye was deactivated by the acid diffusing in from the dye-free phase. A well-defined internal circulation pattern was always present in the wetting phase, i.e. that forming the wall film, leading to uniform mixing in the slugs of this phase. Stagnant zones and local circulation vortices, indicated by variations in the concentrations of the quenched dye, were observed in the non-wetting dispersed phase. These more complex flow structures varied little with the slug velocity, but were strongly dependent on the physical properties of the liquid–liquid system. To predict slug shape and hydrodynamics within the liquid slugs, CFD simulations were carried out using the volume-of-fluid method (VOF) based on the incompressible Navier–Stokes equation with appropriate boundary conditions between the two phases. The slug generation process was studied in a T-junction with 1 mm internal diameter inlets. The implementation of the wetting contact angle, measured in the visualisation experiments for the various systems, led to realistic slug lengths and shapes. The velocity vector plot indicated a fully developed internal circulation pattern within the simulated slugs. Calculations for a single slug with a non-wetting condition gave rise to a wall film in the simulated system.The results obtained demonstrate the significance of the wall film in the hydrodynamics and mass transfer liquid–liquid slug flow and reveal the presence of hitherto unsuspected complex patterns in place of simple single Taylor vortex flow assumed in the past.     

The effect of liquid viscosity and modeling of mass transfer in gas–liquid slug flow in a rectangular microchannel

Both chemical (by adding 0.05 M NaOH) and physical absorption of CO₂ into aqueous glycerol solutions with viscosity up to 45.6 mPa·s in a microchannel are investigated. The concentration distribution pattern, absorption time, and mass transfer coefficient are analyzed and discussed. A new concentration distribution pattern is observed with the lowest concentration locating at the channel center. It is shown for the first time that presents a positive relationship with liquid viscosity, which is explained by the essential role of the mass exchange between the liquid film and bulk liquid slug. This mass exchange may lead to a rise in k _L when increasing the liquid viscosity under some cases in chemical absorption. A mass transfer model is successfully applied to predict the bubble size evolution in physical absorption. The model also shows about 10–46% of the mass transfer contribution from liquid films before saturation.     

Void fraction measurement and calculation model of vertical upward co-current air–water slug flow

The focus of this paper is on the measurement and calculation model of void fraction for the vertical upward co-current air–water slug flow in a circular tube of 15 mm inner diameter. High-speed photography and optical probes were utilized, with water superficial velocity ranging from 0.089 to 0.65 m·s^-1 and gas superficial velocity ranging from 0.049 to 0.65 m·s^-1. A new void fraction model based on the local parameters was proposed, disposing the slug flow as a combination of Taylor bubbles and liquid slugs. In the Taylor bubble region, correction factors of liquid film thickness C_δ and nose shape C_Z^* were proposed to calculate α_TB. In the liquid slug region, the radial void fraction distribution profiles were obtained to calculate α_LS, by employing the image processing technique based on supervised machine learning. Results showed that the void fraction proportion in Taylor bubbles occupied crucial contribution to the overall void fraction. Multiple types of void fraction predictive correlations were assessed using the present data. The performance of the Schmidt model was optimal, while some models for slug flow performed not outstanding. Additionally, a predictive correlation was correlated between the central local void fraction and the cross-sectional averaged void fraction, as a straightforward form of the void fraction calculation model. The predictive correlation showed a good agreement with the present experimental data, as well as the data of Olerni et al., indicating that the new model was effective and applicable under the slug flow conditions.     

PRESSURE LOSSES IN TWO-PHASE GAS-NON-NEWTONIAN LIQUID FLOW IN A VERTICAL TUBE

Experimental data on pressure drop for two-phase gas-non-Newtonian ps:udoplastic liquid vertical slug flow have been analysed. Correlation have been proposed for predicting the two-phase friction factor as a function of the physical and dynamic variables of the system.     

Axial dispersion of particles in a slugging column—the role of the laminar wake of the bubbles

Axial solid dispersion promoted by Taylor bubbles in a batch liquid column was studied. A mechanistic model was developed to predict the axial solid dispersion. The model is based on the upward transport of particles inside closed wakes of non-interacting Taylor bubbles. The model predictions are compared with experimental data. The experimental data were obtained in a test tube of internal diameter. The particle volumetric distribution was measured by several differential pressure transducers placed along the column. Two classes of glass beads, mean diameter 180 and , were suspended in aqueous glycerol solutions, with glycerol percentage ranging from 40% (v/v) to 100% (v/v). The amount of particles in the column was such that the volumetric particle fractions were 0.1, 0.2 and 0.3, supposing homogeneous liquid-solid suspension. The air flow rate ranged from 90×10⁻⁶ to at PTN conditions. The obtained experimental data are in good agreement with the model predictions for laminar wakes, i.e., closed wakes with internal recirculation and without vortex shedding. The experimental data show a higher upward particle transport for wakes in the transition laminar-turbulent regime; closed wakes with internal recirculation and vortex shedding. The upward particle transport is higher for increasing air flow rate, decreasing particle diameter and increasing amount of particles in the column.     

Effective interfacial area for mass transfer in the liquid–liquid slug flow capillary microreactors

Liquid–liquid biphasic reactions play an important role in the chemical and pharmaceutical industries. The liquid–liquid slug flow capillary microreactor offers considerable potential benefits over the conventional liquid–liquid contactors. Though the hydrodynamics and mass transfer have been investigated for this reactor concept, so far the effective interfacial area available for mass transfer has not been experimentally quantified. Despite the well-defined flow patterns arising in the capillary microreactor, the wetting behaviour of the liquids at the capillary wall is inadequately integrated into the models and thus, the true interfacial area being used for mass transfer is uncertain.     

PREDICTION OF FLOW REGIME TRANSITIONS IN VERTICAL UPWARD THREE PHASE GAS-LIQUID-SOLID FLOW

The effect of solids concentration on the bubble to bubble-slug, bubble-slug to slug, and slug to churn flow transitions in gas-liquid-solid vertical flow has been studied using air, water, and glass beads in a 5 cm ID plexiglass column. Several simple models to predict the transitions were developed utilizing criteria proposed for gas-liquid vertical flow. These criteria are shown to apply equally well in the absence or presence of the solid phase

With solids present in the flow, the bubble to bubble-slug and bubble-slug to slug flow transitions both occurred at lower superficial gas velocities because of increased bubble coalescence. However, the slug to churn flow transition was unaffected by solids in the range of flow conditions studied.     

Experimental study of drag reduction by a polymeric additive in slug two-phase flow of crude oil and air in horizontal pipes

In this study the effect of the presence of a drag reducing agent (DRA) on the pressure drop in cocurrent horizontal pipes carrying slug two-phase flow of air and crude oil is investigated. An experimental set-up is erected. The test section of the experimental set-up is consisted of: a smooth pipe of polycarbonate with 10.3 m long and 2.54 cm ID, a rough pipe of galvanized iron with 8.8 m long and 2.54 cm ID and a rough pipe of galvanized iron with 8.8 m long and 1.27 cm ID. The employing DRA is a Polyalpha-olefin (Polyisobutylene). The percent drag reduction (%DR) is calculated using the obtained experimental data, in presence of the DRA. The results show that addition of DRA could be effective up to some doses of DRA after which the pressure drop is kept constant. A %DR of about 40 is obtained for some experimental conditions.     

Extraction in microreactors: Intensification by adding an inert gas phase

The influence of an inert gas phase on liquid extraction using a microstructured device is analyzed. The gas phase establishes a modified flow pattern. The performance of the gas-liquid-liquid flow is compared to that of a segmented two phase flow, as regards mass transport as well as separation. The extraction of vanillin dissolved in water with toluene was chosen as an example and experiments at different residence times were conducted by varying the total volumetric flow rate. μ-PIV measurements were performed to reveal the influence of the inert gas phase on recirculation within the liquid slugs. Addition of the gas leads to an increase in mass transfer at flow velocities above 0.08 m/s. However, no difference can be noted at lower flow velocities and longer residence times, respectively. The two liquid phases were separated within the microstructured device by using a capillary separator. Purity was always higher than 96%. For two phase segmented flow, the toluene phase was pure, whereas the water phase was free of toluene rests when applying the inert gas phase. Thus, the inert gas phase can be used to enhance mass transfer under certain circumstances and to tune the separation behavior of a capillary separator.