V_2O_5对H13钢在盐浴硫氮碳共渗中的影响

研究了在加入 V2 O5后的低温无毒硫氮碳共渗对 H1 3钢的影响。结果表明 ,这种处理能有效地催渗并且减缓由表至里的硬度梯度 ,V2 O5可提高 H1 3钢共渗层的耐磨性、硬度及表面与其基体结合强度 ,能取得较好的经济效益     

高速钢P6AM5硫氮碳共渗过程的特点

<正> 碳钢与铸铁在尿素与硫磺高温分解产物中进行气体硫氮碳三元共渗的过程在有关文献中已有阐述。其中特别指出:这种扩渗气氛能保证渗氮层的浓度稍低于人HBT-12型高氰盐浴中的硫氮碳共渗.因此在研究高速钢硫氮碳共渗的特点时,采用尿素(NH_2)_2CO和硫脲(NH_2)_2CS分解而得的高温分解气氛,其氮势     

盐浴氮碳共渗对金属耐蚀性的影响

研究了普碳钢（A3,45#）及1Cr18Ni9不锈钢经不同盐浴氮碳共渗处理后在5%NaCl 0.1%H2O2溶液的腐蚀行为,盐浴氮碳共渗能改善碳钢的耐蚀性,其后的氧化、抛光能进一步提高碳钢的耐蚀性。     

气体硫氮碳共渗工艺介绍

硫氮碳共渗是向钢铁零件表面同时渗入硫、氮、碳三种元素的化学热处理工艺。一般采用的温度是570～580℃。 硫氮碳共渗是一种既古老又年轻的工艺。早期应用的硫氮碳共渗盐浴含有大量的氰根(CN~-),对环境污染严重。为了解决这一问题,近年来发展了所谓“无污染硫氰共渗工艺”,将盐浴含氰量降至0.5%～0.8%,且它的废     

低温钛催渗对Cr12钢盐浴氮碳共渗的影响

试验研究了钛催渗对Cr12钢低温盐浴氮碳共渗的影响。结果表明：钛催渗具有明显的催渗效果,可使氮、碳原子的渗入速度显著加快,提高渗层厚度和渗层硬度,同时钛催渗盐浴氮碳共渗工艺简单方便,共渗温度低,共渗时间短,具有明显的节能特点。     

Cr12MoV钢硫氮碳共渗层摩擦磨损特性研究

探讨了Ｃｒ１２ＭｏＶ钢硫氮碳共渗层中硫的渗入深度及渗层表面状态对摩擦系数和耐磨性的影响。     

碳氮共渗及离子氮化H13钢的抗热疲劳性能

分别制备了调质、离子氮化和碳氮共渗处理的H13钢试样,借助X射线衍射仪、扫描电子显微镜和能谱仪对其渗层进行了分析,检测了不同处理后H13钢的抗热疲劳性能.结果表明:经过1000次18℃→700℃热疲劳试验后,碳氮共渗H13钢表面萌生了少量的热裂纹;而离子氮化H13钢表面的热裂纹已经形成网状,并且穿透渗氮层扩展到基体内约300 μm;经调质处理的H13钢表面的热裂纹有轻微的发展,扩展到基体内约100μm;三种试样中碳氮共渗处理H13钢的抗热疲劳性能最好.     

稀土对H13钢在盐浴氮化中的影响

研究了稀土对Ｈ１３钢在盐浴氮化中的影响。对Ｈ１３钢进行低温无毒硫氮碳共渗,在这基础上加入稀土元素,实验结果表明,稀土元素的加入可加速盐浴氮化的过程,具有催渗效果,并能改善其性能,满足模具盐浴氮化的技术要求,具有较好的经济效益和社会效益     

High load AFM friction and wear experiments on V2O5 thin films

High load friction and wear experiments by means of atomic force microscopy were carried out at the surface of highly (0 0 1) oriented vanadium oxide V₂O₅ thin films deposited on silicon by reactive magnetron sputtering. Microscopic friction coefficient was estimated for wide range of loads. The nature of surface wear due to multiple, high load scanning is presented and discussed.     

钨镍共掺杂V2O5薄膜的光电特性研究

利用溶胶–凝胶旋涂法和后退火工艺在FTO导电玻璃上制备了钨镍共掺杂V₂O₅薄膜,研究了薄膜在不同温度和不同偏压下的光电特性和相变特性。利用X射线衍射仪（XRD）、扫描电子显微镜（SEM） 和X射线光电子能谱仪（XPS） 测试了钨镍共掺杂V₂O₅薄膜的晶体结构、表面形貌和组分,分析了不同钨镍共掺杂浓度对V₂O₅薄膜相变光电特性的影响。结果表明,当钨和镍的掺杂质量分数分别为3 %和1.5 %时,钨镍共掺杂的V₂O₅薄膜的相变温度为218.5 ℃,在可见光范围内有较高的透过率,在近红外1310 nm波长处的光学透过率达48.83%,与未掺杂V₂O₅薄膜的光学透过率相比提高了10.29%,薄膜电阻降低了30.53%,热致回线宽度收窄为15 ℃,说明钨镍共掺杂的V₂O₅薄膜具有良好的可逆相变光电特性,有望在新型光电器件领域得到较好的应用。     

H13模具钢的热处理实践

H13模具钢经过热处理可以获得优良的性能,诸如高强度、红硬性及高的冲击韧性值。从解析H13的化学成分入手,对选用高温球化退火、淬火及二次回火做了说明,提供了工艺数据,并在结论中给出了生产实践中获得的五条经验。     

Study of the heating rate effect on the glass transition properties of (60 − x)V2O5–xSb2O3–40TeO2 oxide glasses using differential scanning calorimetry (DSC)

The glass-transition temperature (T_g) and crystallization temperature (T_Cr) have been determined for the system (60 − x)V₂O₅–xSb₂O₃–40TeO₂ with 0 < x < 10 (in mol%) using differential scanning calorimetry (DSC) at heating rates φ = 3, 6, 9 and 13 K/min. The effect of the heating rate and the Sb₂O₃ content on T_g is discussed. It was observed that the transition region shifts to higher temperatures when the measuring time is reduced (or, conversely, when the applied temperature rate is increased). Using differential scanning calorimetry, the compositional dependence of T_g has been determined and so, an empirical equation has been deduced which relates the glass-transition temperature with the Sb₂O₃ content.     

单价银离子在 CaO-P2O5 系统玻璃中的发光特性

在弱还原气氛下制备了单价银离子(Ag⁺)掺杂的CaO-P₂O₅系统玻璃,测试了其在室温下的吸收光谱、激发光谱和发射光谱。Ag⁺-CaO-P₂O₅玻璃的吸收光谱表明两个吸收峰。高能峰位于220nm波长,由4d¹⁰→4d⁹5P¹跃迁引起,低能峰中心位于240nm波长,归因于4d¹⁰→4d⁹5s¹跃迁,该吸收与其发射特性有关。紫外波段的宽带吸收产生了可见波段强烈的荧光发射,发光峰位于440nm波长,半宽度为130nm.研究了掺质浓度与发光特性的关系,随着掺质浓度的增加(0.05～0.25mol%),发光峰向较长波段移动。在Ag₂O含量为0.5mol%时,出现了浓度猝灭现象。为了比较起见,同时还研制了Cu⁺-CaO-P₂O₅及Cu⁺-Ag⁺-CaO-P₂O₅玻璃。     

Tribological performance of MoS2---B2O3 compacts

A recent investigation suggests that selected oxides perform well as additives in molybdenum disulphide (MoS₂) because of their ability to soften at asperity contacts with the result that the solid lubricant can attain and retain a preferred tribological orientation.This research determined the effectiveness of boric oxide (B₂O₃), when used as an additive in MoS₂, for substrate temperatures ranging from 21°C to 316°C. This range was used to allow the asperity contact temperature to vary below and above the softening point of B₂O₃. It was found that a moderate friction coefficient and high wear, which is attributed to the additive acting abrasively, occurred when the asperity contact temperature was well below the softening point of the oxide. When the asperity contact temperature neared the softening point of the oxide, the friction coefficient increased dramatically and wear volume was reduced. It is postulated that B₂O₃ acted adhesively at the interface resulting in a higher coefficient of friction, and wear decreased due to an attainment of a preferred orientation by the MoS₂. For asperity contact temperatures significantly above the softening point of B₂O₃, the friction coefficient returned to about the same value as for temperatures below the softening point. It is speculated that wear continued to increase moderately because of localized melting of the B₂O₃, permitting the MoS₂ to be removed from the interface. These observations support a hypothesis that an additive, such as boric oxide, can soften as the asperity contact temperature approaches the softening point temperature of the additive so that the overall tribological conditions may be improved resulting in reduced interfacial wear. Significant changes in temperature, load or sliding velocity would, of course, dramatically alter the wear characteristics observed at the interface.     

H13热作模具钢稀土硼碳氮多元共渗

对H13热作模具钢稀土硼碳氮共渗工艺进行了研究，并对其共渗层的组织、硬度及耐磨性和抗氧化性进行了测试与分析，结果表明与碳氮硼共渗工艺相比，稀土硼碳氮共渗层的硬度、耐磨性和抗氧化性明显提高。稀土元素的渗入不仅提高了渗层的硬度、耐磨性和抗氧化性，并且使过渡层的硬度变化减缓，增强了基体与共渗层的结合，为共渗层提供强有力的支撑作用。     

Al2O3-TiB2-ZrO2三元复合陶瓷刀具的性能研究

对Al