Inactivation efficacy of plasma-activated water: influence of plasma treatment time,exposure time and bacterial species

This study aimed to evaluate the influence of plasma treatment time, bacterial exposure time to PAW and bacterial species on the inactivation efficacy of plasma-activated water (PAW), with additional investigation of the inactivation mechanisms of PAW. Six bacterial species, including Listeria innocua, Staphyloccus aureus, Escherichia coli, Pseudomonas fluorescens, Shewanella putrefaciens and Aeromonas hydrophila were selected as the representative bacteria. The initial bacterial concentration was around 7 log CFU ml⁻¹ after mixing with PAW, and the inactivation efficacy was measured after different exposure times during the 4 °C storage. Scanning electron microscopy (SEM) images of the bacteria after PAW treatment were carried out to inspect the cell structure damage, and physicochemical properties of PAW, including pH, conductivity and long-living reactive species of H₂O₂, , and , were examined. The results showed that the inactivation efficacy of PAW was positively correlated with plasma treatment time and bacterial exposure time, and for the species examined in this study, the Gram-negative species were more sensitive to PAW than the Gram-positive species. Cell structure damage, including shrinkage, distortion, or holes, was observed after PAW treatment. The pH of PAW was acidified to 2.5–2.9, and conductivity was significantly increased to 518.0 μs cm⁻¹. and H₂O₂ were reduced during the 48 h storage, while an increased concentration was observed for . This study demonstrated that the processing parameters of plasma treatment time, exposure time and characteristics of bacteria can significantly affect the inactivation efficacy of PAW.     

Carbon nitride materials: impact of synthetic method on photocatalysis and immobilization for photocatalytic pollutant degradation

Different synthesis routes for carbon nitride materials (CN) and the resulting products were compared to study the photocatalytic activity (pollutant degradation) in dependence on structure and properties. The CN materials were synthesized by thermal decomposition of dicyandiamide in air and under argon as well as in sealed ampoules with or without the use of a salt melt. The as-prepared materials were characterized by IR spectroscopy, nitrogen adsorption measurement, solid-state NMR spectroscopy, diffuse reflectance UV–Vis spectroscopy, elemental analysis and powder X-ray diffraction (PXRD). The surface polarity of the CN materials was estimated by adsorption of the dicyano-bis(1,10-phenanthroline)-iron(II) complex, which allows an evaluation of the degree of condensation. The CN materials were tested with regard to the photocatalytic degradation of rhodamine B (RhB). It is shown that the photocatalytic activity increases with higher surface polarity. Promising CN materials with high RhB degradation of 85% within 25 min and high surface polarity of 0.89 were selected for an immobilization approach to obtain coatings on a silicone substrate using a high-volume low-pressure (HVLP) spray coating technique. To study the photocatalytic activity of the catalyst coatings, the degradation rates of an aqueous RhB solution and solutions of organic pollutants such as triclosan and ethinyl estradiol were examined. Pollutants are decomposed with up to 63% of the initial concentration. Xenon lamps and different LEDs were used as light sources for comparison. Particularly high degradation efficiencies were obtained using LEDs, and the degradation rates are increased by adjusting the emission spectrum of the lamp to the pollutant and absorption edge of the catalyst, which results in a 40 times higher degradation efficiencies of LEDs compared to a Xe lamp.

Graphical abstract

     

A Compact Semi-circular Slot MIMO Antenna with Enhanced Isolation for Sub-6 GHz 5G WLAN Applications

In this paper, a novel compact semi-circular slot (SCS) 2 × 2 MIMO antenna is presented for 5G NR sub-6 GHz applications with high isolation. The proposed antenna consists of a semi-circular slot in ground plane, U-shaped stub, and 50-ohm microstrip feed line. The novelty of this paper are the Semi-Circular Slot acts a radiator, the port isolation  is enhanced using a simple conductor strip as a neutralization line, very compact in size, low ECC, and good impedance matching. The overall size of the proposed SCS MIMO antenna is 16 mm x 21 mm, and FR4 substrate is used with thickness of 1.6 mm. The two SCS antenna elements are separated by edge-to-edge distance of 1mm (\(=0.019\lambda _{0}\)). The proposed compact MIMO antenna design is simulated using Ansys HFSS. To validate SCS MIMO antenna, a prototype was fabricated and tested. The measured results are attained at 5.5 GHz with isolation greater than 25dB, impedance bandwidth (S11\(<-10\) dB) covers from 5.10 GHz to 5.80 GHz with return loss of ? 39.5 dB. The MIMO antenna parameters, ECC, CCL, TARC, and MEG are studied, and the values are obtained within acceptable limits. The measured and simulated antenna results are almost similar. This compact MIMO antenna is suitable for 5G communications in sub-6 GHz wifi-5 band applications.

     

Universitärer Forschungscluster „Sustainable Technologies in Metal Production and Processing” (STMP)

Foundation of a university research cluster — Co-operation along the value creation chain from raw materials to components — Evidence of joint performance offers — Utilization of synergies — Integration of Christian Doppler Laboratories — Flexible arrangement of co-operations and networks     

Main trends in the theory of coal mining processes at large depths

Journal of Mining Science -     

Interaction of Bacillus polymyxa with some oxide minerals with reference to mineral beneficiation and environmental control

Interaction of Bacillus polymyxa with calcite, hematite, corundum and quartz resulted in significant surface chemical changes not only of the cells but also in the minerals. Both the cell surfaces as well as quartz particles were rendered more hydrophobic after mutual interaction, whilst the rest of the minerals exhibited enhanced hydrophilicity after interaction with the bacteria. The bacteria were also observed to be capable of dissolving calcite, hematite and corundum and biosorbing the dissolved metal ions to varying extents. An excess of polysaccharides could be observed on biotreated calcite, hematite and corundum while the predominance of a protein-based metabolic product was evident on quartz surfaces. The utility of bioprocessing in the beneficiation of the above minerals through bioflotation and bioflocculation is demonstrated.     

'EUROPART'. Airborne particles in the indoor environment. A European interdisciplinary review of scientific evidence on associations between exposure to particles in buildings and health effects

The relevance of particle mass, surface area or number concentration as risk indicators for health effects in non-industrial buildings has been assessed by a European interdisciplinary group of researchers (called EUROPART) by reviewing papers identified in Medline, Toxline, and OSH. Studies dealing with dermal effects or cancer or specifically addressing environmental tobacco smoke, house dust-mite, cockroach or animal allergens, microorganisms and pesticides were excluded. A total of 70 papers were reviewed, and eight were identified for the final review: Five experimental studies involving mainly healthy subjects, two cross-sectional office studies and one longitudinal study among elderly on cardiovascular effects. From most studies, no definite conclusions could be drawn. Overall, the group concluded that there is inadequate scientific evidence that airborne, indoor particulate mass or number concentrations can be used as generally applicable risk indicators of health effects in non-industrial buildings and consequently that there is inadequate scientific evidence for establishing limit values or guidelines for particulate mass or number concentrations.     

Two-step seismic limit state design procedure based on non-linear LRFD and dynamic response analyses

Recently, the limit state design (LSD) or performance-based design have got popularity in the field of building design in Japan as well as in other countries. In the two design methods the structural reliability theory plays an essential role in setting design criteria as well as demonstrating the target reliability level to society. However, the conventional load and resistance factor design (LRFD) has been basically formulated supposing that safety checking is done on the basis of linear assumption of member forces and displacement. Therefore, when applying the LRFD for seismic design, for more accurate treatment of the non-linearity, a new procedure has to be explored especially for the ultimate limit state. Although several procedures for the structural reliability evaluation, treating non-linear displacement responses, have been proposed, they require complex procedures that may not be used in the practical design process. Accordingly, for applying it to a seismic LSD format based on the probabilistic concept, it is essential to manage two important requirements at the same time, accuracy and simplicity of procedure. In the present study, a new design format using the following two-step procedure is proposed to maintain both accuracy and simplicity; (1) a non-linear LRFD formulation, and (2) a formulation based on non-linear dynamic response analysis. Also, two design examples are presented.