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51.
Biaxial forming behavior is investigated for three aluminum sheet alloys (Al 5182 containing 1% Mn (5182+Mn), Al 5754, and
6111-T4) using a heated die and punch in the warm forming temperature range of 200–350 °C. It is found that, while all three
alloys exhibit significant improvement in their formability compared with that at room temperature, the non-heat-treatable
alloys 5182 + Mn and 5754 give higher part depths than that of heat-treatable 6111-T4. The formability generally increases
with decreasing BHP (BHP), but increasing the forming temperature and/or BHP minimizes the wrinkling tendency and improves
the forming performance. The stretchability of the sheet alloys increase with increasing temperature and increasing BHP. For
the alloys and forming conditions involved in the current study, the formability, measured in terms of part depth, comes mainly
from the drawing of metal into the die cavity, although stretching effects do influence the overall forming behavior. The
optimum formability is achieved by setting the die temperature 50 °C higher than the punch temperature to enhance the drawing
component. Setting the die temperature higher than the punch temperature also improves the strain distribution in a part in
such a manner that postpones necking and fracture by altering the location of greatest thinning. 相似文献
52.
Anindita Bhattacharyya 《Chemical engineering science》2004,59(21):4481-4492
An arbitrary flow of a viscous, incompressible fluid past a porous sphere of radius `a' with an impermeable core of radius `b', using Brinkman's equation in the porous region is discussed. At the interface of the clear fluid and porous region, stress jump boundary condition for the tangential stresses along with the continuity of normal stresses and the velocity components are used. On the surface of the impermeable core no slip condition is used. The corresponding Faxen's laws are derived to compute the drag and torque acting on the surface r=a. It is found that the drag and torque not only change with the change of the permeability, but also a significant effect of the stress jump co-efficient is observed. The variation of drag and torque with permeability for different thickness (a-b) of the porous region as well as for different values of stress jump coefficient is discussed when the basic flow is due to uniform flow, two dimensional irrotational flow, doublet in a uniform flow, stokeslet, rotlet. In case of uniform flow the flow field has been plotted. In all the cases, a significant effect of the stress jump coefficient has been realized. 相似文献
53.
B. N. Rai A. K. Sinha U. K. Ghosh S. N. Gupta S. N. Upadhyay 《Chemical Engineering Communications》1988,68(1):15-30
Mass transfer in annuli has been critically examined for various flow situations. The overall mass transfer rate depends on the hydrodynamic regions prevailing in the annular channel as well as on its dimensions. Theoretically consistent correlations are proposed and recommended for both developed and developing boundary layers under laminar and turbulent flow conditions. 相似文献
54.
Short term regulation of hepatic cholesterol ester hydrolase by reversible phosphorylation is described. Two different kinase
systems seem to be involved in this regulation. The addition of ATP, cyclic AMP and Mg2+ to rat liver 104,000× g supernatant (S104) produced a 100–140% increase in cholesterol ester hydrolase activity. This stimulation
was abolished when protein kinase inhibitor was added prior to the addition of ATP, cyclic AMP and Mg2+. Cholesterol ester hydrolase activity was also stimulated when calcium ions, phosphatidylserine, and diolein were added to
S104 along with ATP and Mg2+. Diolein in this reaction could be substituted by phorbol 12-myristate 13-acetate. Preincubation of S104 with alkaline phosphatase
resulted in a deactivation of cholesterol ester hydrolase. The addition of increasing concentrations of Mg2+ to S104 produced increasing inhibition of cholesterol ester hydrolase activity, and this effect was blocked by NaF.
It is suggested that rat liver cholesterol ester hydrolase is activated by cyclic AMP dependent protein kinase and protein
kinase C. Deactivation is accomplished by dephosphorylation catalyzed by a phosphoprotein phosphatase, dependent on Mg2+.
This work was presented at the Twenty-Third Southeastern Regional Lipid Conference, held October 26–28, in Cashiers, North
Carolina. 相似文献
55.
Filled covulcanizates of elastomer blend comprising natural rubber (NR) and ethylene‐propylene‐diene rubber (EPDM) of commercial importance were successfully prepared by using a multifunctional rubber additive; namely, bis(diisopropyl)thiophosphoryl disulfide (DIPDIS). A Two‐stage vulcanization technique further improved the physicochemical properties of the blend vulcanizates by restricting, through the formation of polar rubber bound intermediates, the migration of curative and filler from lower to highly unsaturated rubber. Scanning electron microscopy studies indicate homogeneity and coherency in the morphology of the two‐stage vulcanizates. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1001–1010, 2002; DOI 10.1002/app.10361 相似文献
56.
Poly(o‐toluidine) (POT) is an electroactive polymer with poor mechanical and thermal characteristics. We examined the scope for improving such properties by making blends of POT with ethylene–propylene–diene rubber (EPDM). We prepared POT–EPDM blends containing different weight fractions of POT by intimately mixing known volumes of separate solutions of the two polymers (POT in THF and EPDM in toluene). Films of EPDM and POT–EPDM blends in solution were obtained by spreading, solvent evaporation, and film casting techniques. POT, EPDM, and their blends were characterized in solution by ultraviolet‐visible spectroscopy, and the respective dried samples were analyzed by Fourier transform infrared spectroscopy and thermogravimetry. The polymer samples were further analyzed morphologically by scanning electron microscopy, and their tensile strengths were also evaluated. Spectroscopic and thermal studies of the blends indicated some sort of interaction between the two constituent polymers. The direct current electrical conductivity of the blends in increasing order of POT loading (12.5–100%) was in the range 9.9 × 10?5 to 11.6 × 10?2 S cm?1. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2550–2555, 2003 相似文献
57.
Recognizing a subject given a set of biometrics is a fundamental pattern recognition problem. This paper builds novel statistical models for multibiometric systems using geometric and multinomial distributions. These models are generic as they are only based on the similarity scores produced by a recognition system. They predict the bounds on the range of indices within which a test subject is likely to be present in a sorted set of similarity scores. These bounds are then used in the multibiometric recognition system to predict a smaller subset of subjects from the database as probable candidates for a given test subject. Experimental results show that the proposed models enhance the recognition rate beyond the underlying matching algorithms for multiple face views, fingerprints, palm prints, irises and their combinations. 相似文献
58.
Mechanical properties and morphological studies of compatibilised blends of PA6/EVA-g-MA and PA6/EVA/EVA-g-MA were studied as functions of maleic anhydride content (MA) and dispersed phase (EVA-g-MA) concentrations, respectively at blending composition of 20 wt% dispersed phase (EVA-g-MA or combination of EVA and EVA-g-MA). The maleic anhydride (MA) was varied from 1 to 6 wt% in the PA6/EVA-g-MA blend, whereas MA concentration was fixed at 2 wt% in the ternary compositions with varying level of EVA-g-MA. ATR-IR spectroscopy revealed the formation of in situ copolymer during reactive compatibilisation of PA6 and EVA-g-MA. It was found that notched Izod impact strength of PA6/EVA-g-MA blends increased significantly with MA content in EVA-g-MA. The brittle to tough transition temperature of reactively compatibilised blends was found to be at 23 °C. The impact fractured surface topology reveals extensive deformation in presence of EVA-g-MA whereas; uncompatibilised PA6/EVA blend shows dislodging of EVA domains from the matrix. Tensile strength of the PA6/EVA-g-MA blends increased significantly as compared to PA6/EVA blends. Analysis of the tensile data using predictive theories showed an enhanced interaction of the dispersed phase and the matrix. It is observed from the phase morphological analysis that the average domain size of the PA6/EVA-g-MA blends is found to decrease gradually with increase in MA content of EVA-g-MA. A similar decrease is also found to observe in PA6/EVA/EVA-g-MA blends with increase in EVA-g-MA content, which suggest the coalescence process is slower in presence of EVA-g-MA. An attempt has been made to correlate between impact strength and morphological parameters with regard to the compatibilised system over the uncompatibilised system. 相似文献
59.
The rheological behavior of an aqueous solution of poly(vinyl alcohol) (PVA) and polypyrrole (PPY) dispersions prepared by ferric chloride (FeCl3)‐catalyzed polymerization of pyrrole was investigated at 12°C using a coaxial rotational viscometer. The results show that the addition of a low dose of FeCl3 to the PVA solution greatly influences its rheology. The prominent shear‐thickening (dilatant) nature of PVA turns significantly pseudoplastic (shear thinning) in the presence of FeCl3. Polypyrrole‐loaded PVA was obtained in a stable, optically clear dispersion by in situ polymerization of pyrrole in an aqueous PVA solution (5%) using FeCl3 as the oxidative catalyst at 12°C. The PPY dispersions in aqueous PVA systems having a low loading of PPY and low Fe+3 content retain the dilatant character of an aqueous PVA solution; however, for an aqueous PVA system having a relatively high PPY loading and also a high Fe+3 content, prominent pseudoplastic (shear thinning) behavior is exhibited. The odd novel rheological patterns exhibited by a PVA solution in the absence and presence of FeCl3 and the PVA–PPY dispersions containing FeCl3 under different sets of conditions are explained on the basis of the complexation of PVA by Fe+3 and related ions and also as a consequence of some degree of H‐bonding and chemical grafting between the support polymer PVA and the PPY formed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3737–3741, 2004 相似文献
60.
H. S. Tripathi B. Mukherjee S. Das M. K. Haldar S. K. Das A. Ghosh 《Ceramics International》2003,29(8):915-918
Stoichiometric magnesium aluminate spinel was synthesized by reaction sintering of alumina with caustic and sintered magnesia. The volume expansion of 5–7% during MgAl2O4 formation was utilized to identify the starting temperature of spinel formation and densification by high temperature dilatometry. The magnesia reactivity was determined by measurement of crystallite size and specific surface area. Caustic magnesia and sintered magnesia behave differently vis-à-vis phase formation and densification of spinel. Densification of stoichiometric Mag-Al spinel was carried out between 1650 and 1750 °C. Attempts were made to correlate the MgO reactivity with microstructure and densification of spinel. 相似文献