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The kinetics of the methanation of carbon dioxide was investigated using an alumina supported Ni-La2O2 catalyst in a differential and integral reactor. In the differential reactor the molar ratio of H2 to CO2 was varied from 0.6 to 30. In the integral reactor the rates were measured with up to 90% conversion. Both reactor tests were carried out at temperatures between 513 and 593 K. The experimental results were described by a Langmuir-Hinshelwood type equation. The kinetics can be explained by assuming equilibrium of dissociative carbon dioxide and hydrogen adsorption, and assuming hydrogenation of surface carbon as the rate determining step. 相似文献
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This investigation focuses on slow, isothermal, two-phase flow of gas bubble suspensions in Separan solutions, prepared with the help of a sodium borohydride blowing agent at room temperature. The total residence time in these experiments is much smaller than characteristic times for growth or rise of bubbles. The variation of bubble volume fraction across a narrow gap between two planes, is recorded at two locations along the flow direction. This is done with a Cesium gamma-radiation source focused on a region of area.012 cm2 in the flow plane, and a Sodium iodide detector across the channel yielding a resolution of.01 over the range of void fractions investigated from.02 to.08. This measurement allows us to identify conditions under which the two-phase flow may be described by a two fluid model with a uniform bubbly core and a bubble free wall layer. With this two phase flow structure, a relative viscosity equation for the suspension is used to compute an apparent viscosity. Such calculations indicate that the observed reduction in apparent viscosity for the two phase flow may be attributed to a bubbly core which is more shear thinning than the medium. The additional shear thinning factor for the suspension is related to the elasticity of the medium. 相似文献
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Kai Xing Fengjuan Zhang Yi Liang Dechang Chen 《Personal and Ubiquitous Computing》2014,18(8):1917-1928
Along with the increasing popularity of electric vehicles caused by economic and environmental incentives, the penetration of plug-in hybrid electric vehicles (PHEVs) poses a great threat to the power grid, especially to the aggregated load in the power system. Motivated by this observation, in this paper, we analyze the impact of large-scale usage of PHEVs and address the load distribution problem by solving a decentralized optimization problem and smoothening the peak load with pricing strategies in the power grid. We also investigate the influence of charging time and charging mode on load distribution, as the charging price varies with the changes of these two factors. Our simulation study on PJM’s data warehouse shows that the proposed strategies can well smooth the peak load by pricing on the charging time and mode. The results also indicate that our strategies always distribute the load in a smoother manner at a smaller load fluctuation compared with other schemes (e.g., First Come First Service and PMCS) and thus improving the stability and reliability of the power grid. 相似文献
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A novel and simple growth mark method was developed to make marks during the growth process of carbon nanotube arrays. These marks can be read out under scanning electron microscope or optical microscope. Based on this method, the growth rates at different temperatures and under different acetylene partial pressures were measured, from which the activation energy and the order of reaction were determined. Based on our experimental results, the growth of carbon nanotube arrays in our experimental condition could not be diffusion-limited. The measured activation energy could possibly be attributed to the heterogeneous decomposition of acetylene over the catalyst particle. Furthermore the marked array with special segmental structure may be found some applications in the future. 相似文献
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吕锴 《重庆科技学院学报(社会科学版)》2010,(4):125-126,135
电影《电话亭》(Phone Booth)充分体现了西方戏剧的一些重要的特征。《电话亭》舍弃了电影擅长的时空及人物的多样性,选择恪守传统戏剧的“三一律”,只利用非常有限的场景、时间和人物,制造出一波三折的戏剧性冲突,体现了西方戏剧是激变型的艺术这一特征。此外影片还体现了基督教的“性恶论”与西方悲剧的关联,具有警世的意味。 相似文献
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采用对比的试验方法,研究并讨论了钢纤维、聚丙烯纤维及其混杂对混凝土长期性能及耐久性的影响.研究结果表明,用不同尺度、不同性质的钢纤维与聚丙烯纤维按二元混杂以总体积率0.9%掺入高性能混凝土中,明显改善了水泥混凝土的长期性能,90d干缩值减少36.6%,200d徐变度降低45.4%,并可显著提高混凝土的耐久性能,相对渗透系数降低79.03%,氯离子渗透系数降低30.5%. 相似文献