合成己二腈反应技术研究——(Ⅴ)己二腈工业反应过程模拟与反应器改造

对己二腈工业反应器提出了两釜串联带回流的模型,通过模拟计算得出模型的级间返混系数 f=6的结论。该模型能较好地预测工业反应器中物料组分浓度变化和气、液两相的流动特性;指出了现工业反应器的鼓泡中和段体积偏小是造成己二酸浓度偏高的关键;提出了可以通过增加串连一个鼓泡预反应段的改造方案,能有效地降低己二酸的浓度,从7%降至4%左右,从而能较好地减缓腐蚀和结焦。     

A concise process technology for 3-D suspended radio frequency micro-inductors on silicon substrate

In this letter, a concise process technology is proposed for the first time to enable the fabrication of good quality three-dimensional (3-D) suspended radio frequency (RF) micro-inductors on bulk silicon, without utilizing the lithography process on sidewall and trench-bottom patterning. Samples were fabricated to demonstrate the applicability of the proposed process technology.     

Simulation study of peak junction temperature and power limitationof AlGaAs/GaAs HBTs under pulsed and CW operation

The authors have used a 3-D transmission-line matrix (TLM) modeling method to study the junction temperature distribution and power limitation of device geometries with multiple embedded heat sources. Peak values of the junction temperature against the dissipated power density under both pulsed and CW operation are presented for a typical power AlGaAs/GaAs HBT structure. These data should facilitate the rapid determination of junction temperature for a given output power, which is of paramount importance in power device design     

Eigenvalue-based algorithms for testing positive realness of SISO systems

A computational test for scalar positive real and strictly positive real functions is proposed in this paper. The input for this algorithm is state space representation, not necessarily minimal. It is derived for the discrete time problem, based on numerical stable eigenvalue computations. The test can be used in the continuous counterpart, which is in fact an improvement of an algorithm posed by Bai and Freund. Differences between the discrete and continuous time problems are also pointed out.     

压力容器材料质量控制的几个重要环节

针对压力容器材料方面存在的问题,从设计、采购、检验、制造等环节进行了分析,根据实际情况确定材料的质量控制要点。材料使用前要通过各种检测手段,判断材料的真实性,确保所用材料合格;并应从设计、选材、采购、计划、填报内容和选择可靠的供应方等方面加以控制,确保材料的正确使用,为压力容器产品的材料控制提供借鉴。     

美国的灭火与救援机器人研发综述

设想某一个城镇生产木材调色板的流水线车间里 ,由于电器原因引发了一场火灾 ,致使建筑物坍塌。没有人能够确切地说出有多少工人被埋压在里面 ,更糟的是 ,当毗邻墙体坍塌时 ,隔壁的旧轮胎储藏室也被埋压在下面。于是市消防局派遣一批机器人去现场救援。第一个到达的机器人进入现场调查情况 ,该机器人能忍耐80 0℃的高温炙烤 ,身上安装了摄像机 ,可以给 90 m外的控制室发送图片 ,控制室的指挥人员就可以根据图片决定是否派消防队员冒险进入现场。第二个机器人是无人驾驶卡车 ,进入后便从 75 m远的地方以2 6 gal/ s的速度往火场喷水 ,并用它所…     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

Preparation and Photoluminescence of Partially Filled ZnO Microtubes Using Block Copolymers

Partially filled ZnO microtubes were synthesized in large scale using block copolymers. The growth mechanism of this unique construction is proposed on the basis of adsorption of block copolymers on {0002} plane of wurtzite ZnO. The photoluminescence property of these unique ZnO microtubes is also studied using a Xe lamp as the excitation source at room temperature. Blue emission band at 425 nm is a much stronger ultraviolet emission band, which is due to laminar structure of ZnO microtubes.