Janus‐Structured Co‐Ti3C2 MXene Quantum Dots as a Schottky Catalyst for High‐Performance Photoelectrochemical Water Oxidation

MXene materials have attracted increasing attention in electrochemical energy‐storage applications while MXene also becomes photo‐active at the quantum dot scale, making it an alternative for solar‐energy‐conversion devices. A Janus‐structured cobalt‐nanoparticle‐coupled Ti₃C₂ MXene quantum dot (Co‐MQD) Schottky catalyst with tunable cobalt‐loading content serving as a photoelectrochemical water oxidation photoanode is demonstrated. The introduction of cobalt triggers concomitant surface‐plasmon effects and acts as a water oxidation center, enabling visible‐light harvesting capability and improving surface reaction kinetics. Most importantly, due to the rectifying effects of Co‐MQD Schottky junctions, photogenerated carrier separation/injection efficiency can be fundamentally facilitated. Specifically, Co‐MQD‐48 exhibits both superior photoelectrocatalysis (2.99 mA cm^?2 at 1.23 V vs RHE) and charge migration performance (87.56%), which corresponds to 194% and 236% improvement compared with MQD. Furthermore, excellent photostability can be achieved with less than 6.6% loss for 10 h cycling reaction. This fills in gaps in MXene material research in photoelectrocatalysis and allows for the extension of MXene into optical‐related fields.     

A Multifunctional Blue‐Emitting Material Designed via Tuning Distribution of Hybridized Excited‐State for High‐Performance Blue and Host‐Sensitized OLEDs

Actualizing full singlet exciton yield via a reverse intersystem crossing from the high‐lying triplet state to singlet state, namely, “hot exciton” mechanism, holds great potential for high‐performance fluorescent organic light‐emitting diodes (OLEDs). However, incorporating comprehensive insights into the mechanism and effective molecular design strategies still remains challenging. Herein, three blue emitters (CNNPI, 2TriPE‐CNNPI, and 2CzPh‐CNNPI) with a distinct local excited (LE) state and charge‐transfer (CT) state distributions in excited states are designed and synthesized. They show prominent hybridized local and charge‐transfer (HLCT) states and aggregation‐induced emission enhancement properties. The “hot exciton” mechanism based on these emitters reveals that a balanced LE/CT distribution can simultaneously boost photoluminescence efficiency and exciton utilization. In particular, a nearly 100% exciton utilization is achieved in the electroluminescence (EL) process of 2CzPh‐CNNPI. Moreover, employing 2CzPh‐CNNPI as the emitter, emissive dopant, and sensitizing host, respectively, the EL performances of the corresponding nondoped pure‐blue, doped deep‐blue, and HLCT‐sensitized fluorescent OLEDs are among the most efficient OLEDs with a “hot exciton” mechanism to date. These results could shed light on the design principles for “hot exciton” materials and inspire the development of next‐generation high‐performance OLEDs.     

一种用于高速A/D转换器的高精度参考电压电阻网络

提高分压电阻网络输出参考电压的精度对设计高速A/D转换器有重要意义.本文基于对参考电压非线性误差的分析提出一种并联式高精度参考电压电阻网络,给出其输出参考电压在最坏情况下的非线性误差分布形式.详细的讨论以及模拟结果表明勿需补偿电路,并联式电阻网络通过减少支路电阻串上的电阻数目能有效地抑制由于负载效应造成的参考电压非线性误差,使得输出参考电压的精度明显提高,同时稳定速度加快,驱动负载能力强,对温度的灵敏度低,适合于多种结构的高速A/D转换器,如:全并行、分步式、折叠式等.     

红外激光划痕涂层的应力应变理论分析

为研究涂层的热应力和应变与涂层结合强度之间的关系,对红外激光划痕后的涂层的热应力应变进行了理论分析,建立了涂层的热应力理论模型和应变公式.红外激光划痕涂层的试验结果表明,激光划痕后涂层在沿其厚度方向上的应变量有明显的突变过程,突变点的位置即是涂层从基体脱离下来的临界位置;激光划痕时涂层的剥离应力随涂层的温度增大而增大,并会呈现出两个阶段过程变化,进而说明了两个阶段之间的转折点反映了涂层结合强度的大小.     

基于WIFI物联网的家电智能控制系统信息控制端的研究

随着WiFi无线通信技术的发展和普及,WiFi已成为当今无线网络接入的主流标准。本文以智能家居广阔的市场需求为基础,选取家庭智能控制系统为研究对象,基于ARMS3C2440处理器和Linux嵌入式操作系统基础上,利用WiFi模块组建了家庭无线网络,采用Java技术为平台,实现一个可以在WiFi热点区域接入互联网的无线通信终端,并可以对家电设备远程控制。经测试,信息控制端可以在WiFi信号覆盖区域接入因特网,系统启动和运行正常,证明这种网络控制的方案是可行的。     

Supporting cooperative caching in ad hoc networks

Most researches in ad hoc networks focus on routing and not much work has been done on data access. A common technique used to improve the performance of data access is caching. Cooperative caching, which allows the sharing and coordination of cached data among multiple nodes, can further explore the potential of the caching techniques. Due to mobility and resource constraints of ad hoc networks, cooperative caching techniques designed for wired networks may not be applicable to ad hoc networks. In this paper, we design and evaluate cooperative caching techniques to efficiently support data access in ad hoc networks. We first propose two schemes: CacheData, which caches the data, and CachePath, which caches the data path. After analyzing the performance of those two schemes, we propose a hybrid approach (HybridCache), which can further improve the performance by taking advantage of CacheData and CachePath while avoiding their weaknesses. Cache replacement policies are also studied to further improve the performance. Simulation results show that the proposed schemes can significantly reduce the query delay and message complexity when compared to other caching schemes.     

A direct digital frequency synthesizer with fourth-order phase domain /spl Delta//spl Sigma/ noise shaper and 12-bit current-steering DAC

This paper presents a direct digital frequency synthesizer (DDFS) with a 16-bit accumulator, a fourth-order phase domain single-stage /spl Delta//spl Sigma/ interpolator, and a 300-MS/s 12-bit current-steering DAC based on the Q/sup 2/ Random Walk switching scheme. The /spl Delta//spl Sigma/ interpolator is used to reduce the phase truncation error and the ROM size. The implemented fourth-order single-stage /spl Delta//spl Sigma/ noise shaper reduces the effective phase bits by four and reduces the ROM size by 16 times. The DDFS prototype is fabricated in a 0.35-/spl mu/m CMOS technology with active area of 1.11mm/sup 2/ including a 12-bit DAC. The measured DDFS spurious-free dynamic range (SFDR) is greater than 78 dB using a reduced ROM with 8-bit phase, 12-bit amplitude resolution and a size of 0.09 mm/sup 2/. The total power consumption of the DDFS is 200mW with a 3.3-V power supply.     

Multiuser carrier frequency offsets estimation for OFDMA uplink with generalized carrier assignment scheme

The frequency synchronization issue of multiuser in the uplink of an orthogonal frequency-division multiple-access (OFDMA) system is investigated in this letter. We develop a subspace based blind carrier frequency offsets (CFOs) estimation algorithm for the base station (BS) equipped with uniform linear array (ULA). Due to the adoption of ULA at the BS and the narrowband signal assumption, CFOs of different users can be separated by their spatial information. Thus, unlike existing blind alternatives, which are subject to some specific carrier assignment schemes (CAS) or rely on null subcarriers, our proposed method can support generalized carrier assignment scheme (GCAS) and fully loaded systems, i.e., all subcarriers are available to users. Consequently, the dynamic channel assignment is available and the bandwidth efficiency is higher. Moreover, the closed-form directions of arrival (DOAs) of all active users are also obtained, which can be used in downlink beamforming in frequency division duplex (FDD) systems. Performance of the proposed scheme is evaluated by computer Monte Carlo simulations.     

A multicast dynamic wavelength assignment algorithm based on matching degree

The wavelength assignment with multiple multicast requests in fixed routing WDM network is studied. A new multicast dynamic wavelength assignment algorithm is presented based on matching degree. First, the wavelength matching degree between available wavelengths and multicast routing trees is introduced into the algorithm. Then, the wave.length assignment is translated into the maximum weight matching in bipartite graph, and this matching problem is solved by using an extended Kuhn-Munkres algorithm. The simulation results prove that the overall optimal wavelength assignment scheme is obtained in polynomial time. At the same time, the proposed algorithm can reduce the connecting blocking probability and＂ improve the system resource utilization.     

DF/HF化学激光器喷管总压损失的数值模拟

DF/HF化学激光器需要体积庞大的压力恢复系统才能够工作。为了综合考虑激光器和压力恢复系统一体化设计,对DF/HF化学激光器的两种喷管的内流场采用了CFD技术进行了模拟,比较了它们的总压损失的差别和内流场的不同,并讨论了这种不同对整个激光器性能的影响。计算结果表明,细喉道的喷管不但有利于减小激光器增益发生器的尺寸,而且它的总压损失近似于标准喷管,从而不会增加激光器后部压力恢复系统的体积。