Preparation,microstructure, mechanical,and thermal properties of in situ polymerized polyimide/organically modified sericite mica composites

In this work, sericite mica was initially modified with a multi‐step procedure and the novel composites of polyimide (PI) with the organophilic sericite mica were subsequently synthesized via in situ polymerization technique. XRD patterns revealed d₀₀₂‐spacing of clay was expanded from 0.99 to 2.77 nm. TEM photographs indicated majority of the organoclay exhibited an exfoliated morphology structure in composites with 5 wt% filler loading. Several critical properties of composites such as thermal stability, mechanical property, and storage modulus were tremendously enhanced with the increasing organoclay loading. Especially, the glass transition temperature of composites with 7 wt% organoclay addition revealed a 72°C increment compared with pristine PI, indicating greater improvement than the reported literature values. POLYM. COMPOS., 37:2243–2251, 2016. © 2015 Society of Plastics Engineers     

Preparation and Fluorescence Properties of Polymethyl Methacrylate Resin Incorporated with Sodium Tris （Pyridine Dicarboxylato）Europate

Based on the strong fluorescence and the highly thermal stability of sodium tris (pyridine dicarboxylato)eruopate(Na3Eu(DPA)3),polymethyl methacrylate(PMMA)composite material incorporated with the complex,PMMA:Na3Eu(DPA)3,was prepared at 250℃，The fluorescence behavior of PMMA:Na3Eu(DPA)3material was examined,The results show that the composite material keeps the luminescent characteristics of the Eu^3 chelate after PMMA is incorporated with Na3Eu(PDA)3,and strong orange-red emission of the composite wsa observed.The fluorescence intensity of the composite material increases with the increase of the weight ratio of Na3Eu(PDA)3to PMMA,but the relationship is not linear.     

聚酰亚胺／磺化聚芳醚砜共混中空纤维膜用于醇／醚气相分离的研究

甲醇／ 甲基叔丁基醚的分离是目前具有实用意义的重要研究课题之一．文中采用气流吹扫式操作,研究了不同共混比的磺化聚芳醚砜／ 聚酰亚胺中空纤维膜对甲醇／ 甲基叔丁基醚气相混合体系的分离性能,以及不同操作条件对分离性能的影响．结果表明,共混改性聚酰亚胺膜具有非常高的醇／ 醚分离系数,有很好的应用前景．     

表面修饰纳米SiO2增强增韧聚氯乙烯

用过量的2 , 4-甲苯二异氰酸酯(TDI)对纳米SiO₂表面进行修饰合成含—NCO 的功能化SiO_2,再用丙烯酸羟丙酯(HPA)对其表面进行修饰合成出HPA修饰纳米SiO₂(SiO₂-HPA)。用共混法制备了SiO₂-HPA/PVC纳米复合材料,研究了不同 SiO₂含量及不同界面特性时复合材料的力学性能。结果表明: SiO₂-HPA/PVC复合材料的力学性能和加工性能等方面均优于未修饰的样品。在纳米SiO₂质量分数为0%～5%时,SiO₂-HPA/PVC的拉伸强度和冲击强度随着填充量的增加呈先上升后下降的趋势并在3%～4%达到最大值。表面修饰纳米SiO₂与PVC基体之间具有很强的界面结合作用,其相容性得到大大改善,填充表面修饰纳米SiO₂达到了增强增韧双重效果。此外,对纳米粒子增强增韧机制进行了深入的探讨。     

Compatibilizing effect of maleated polypropylene on the mechanical properties of injection molded polypropylene/polyamide 6/functionalized-TiO2 nanocomposites

TiO₂ nanoparticles were pretreated with excessive toluene-2,4-diisocyanate to synthesize TDI-functionalized TiO₂ (TiO₂-NCO), and then the polypropylene/polyamide 6/(PP/PA6, 70/30 wt%) blends containing 3 phr of the TDI-functionalized TiO₂ were prepared using twin-screw extruder followed by injection molding. Maleated polypropylene (PP-g-MAH) was used to compatibilize the blends. The mechanical properties of PP/PA6 blends based nanocomposites were studied through tensile and flexural tests. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to assess the fracture surface morphology and the dispersion of the TDI-functionalized TiO₂, respectively. The dynamic mechanical properties of PP/PA6 based nanocomposites were analyzed by using dynamic mechanical thermal analyzer (DMTA). The strength and stiffness of the PP/PA6 compounds were improved significantly in the presence of PP-g-MAH. This has been attributed to the synergistic effect of TDI-functionalized TiO₂ and PP-g-MAH. The PP-g-MAH compatibilized PP/PA6 compounds showed a homogeneous morphology supporting the compatibility improvement between PP, PA6 and TDI-functionalized TiO₂. TEM results revealed that the TDI-functionalized TiO₂ nanoparticles were exfoliated and uniformly dispersed in blends matrix. Possible chemical interactions between PP, PA6, TDI-functionalized TiO₂ and PP-g-MAH were proposed based on the experimental work.     

准噶尔盆地东部阜东斜坡区侏罗系岩性圈闭识别

依据地震沉积学的理论与方法,针对准噶尔盆地东部阜东斜坡区侏罗系头屯河组河道砂体,综合运用地震属性分析、相干体分析、频谱分解、三维可视化及全三维数据体解释等技术进行了岩性圈闭识别和新技术的探索.用单一地震属性对岩性目标的刻画具有较强的多解性.为了减少多解性,提高地震属性的预测精度,采用了多种地震属性进行联合分析、相互验证,以提高预测精度,降低勘探风险.通过应用多种地震解释新技术对研究区河道砂体进行识别,从多方面清晰地展示了河道砂体的空间展布特征,识别出了多个岩性目标.经多年的勘探,在该区发现了阜东2井、阜东5井及阜东16井等头屯河组岩性油藏,为准噶尔盆地岩性油气藏的勘探提供了新的思路和新的勘探目标类型.     

Slightly off-axis interferometry for microscopy with second wavelength assistance

Slightly off-axis interferometry for microscopy has been performed, where the dc term of the interferogram is suppressed by the object wave in another wavelength. One wavelength of the laser beam (red light) is used to generate the slightly off-axis interferogram, while the second wavelength (blue light) is employed to measure the transmittance of the specimen. Both the red light and blue light are recorded simultaneously by a color CCD camera and can be separated without cross talk via the red-green-blue components. The dc term of the slightly off-axis interferogram of red light is suppressed with the object wave of blue light. As a consequence, the requirement on the off-axis angle between the object and reference waves is relaxed as well as the requirement on the resolving power of CCD camera.     

新型预硫化型重整预加氢催化剂的工业应用

根据重整预加氢工业装置及所需催化剂的特点,通过自主研发的器外预硫化工艺及硫化剂配方开发出了新型预硫化型重整预加氢催化剂DZF-1。在国内某炼油厂500 kt/a重整预加氢装置进行工业应用,表明该催化剂具有简化开工程序、可省去干燥脱水过程、节省器内硫化所需的注硫设施、缩短开工时间、减少环境污染及催化剂硫化完全等优点。与氧化型催化剂硫化相比至少节省24 h开工时间,活化开工时催化剂能够逐级释放H_2S,使循环氢中H_2S含量在理想范围内,整个活化开工过程反应器床层最高温升小于15℃。工业运转表明在其他工艺参数相当条件下,与上周期国内某同类型催化剂相比平均反应温度降低10~15℃。     

非均匀介质特征参数地震随机反演方法

地下介质普遍存在非均质特性,即表征含油气储层特征的弹性、物性及流体性质在空间上是不均匀的。常规的地震随机反演主要以测井数据为核心,求取变差函数表征地下地层的空间结构特征,难以有效描述地下复杂非均质储层的空间变化特性。为此,通过描述不同非均匀介质特征参数对介质的空间扰动特性,并在贝叶斯理论框架下充分利用已知测井和地震数据中蕴含的地下地层信息,提出了基于非均匀介质特征参数的随机反演方法。该方法融合已知测井和地震数据,依据随机介质理论估算的非均匀介质特征参数能更好地描述地下储层空间结构特征,进而构建后续反演所需的先验信息模型,最后利用非常快速量子退火算法优化求解目标函数,得到波阻抗的随机反演结果。模型试算表明,非均质特征参数先验模型可以描述储层的非均质特性,为后续反演提供了可靠的地质统计先验信息。实际资料的应用进一步证明,所提方法可以较好地实现对地下复杂储层的高分辨率反演,获得更可靠的反演数据体。