Rückgewinnung von Vinylchloridmonomer

The production of the polymer polyvinylchloride (PVC) emits a high amount of waste gas. The recovery of the evaporated base product vinylchoridemonomer (VC) is an important aspect for the economics of the whole process. Membrane and vacuum technology improve the efficiency and the economics of the recovery process considerably.     

激光光束质量因子的研究进展

本文详细分析了各种光场下光束质量M2因子。在不同的场中,A.E.Siegman当初所定义的M2因子,已经有了很大的变化,因而M2因子的特性也与当初不同,不仅M2因子可以大于等于1,而且可以小于1,甚至小于0。其反映的物理意义,也从经典场中的衍射极限倍数,变化为非经典场中的准直性量度以及对空间相干性的某些反映。此外还列举并分析了几种特殊的光束质量因子,最后讨论了M2因子应用的问题并指出了其局限性。     

适用于LED显示屏或照明工程的异步控制卡DS2000-M1

DS2000-M1是高性能、开放式的LED控制系统,本文从软硬件两方面简述其设计原理。     

稻壳基碳量子点对废水中Pb(Ⅱ)的检测

为了进一步实现生物质废弃资源的综合利用,以及对废水中污染物的检测,以稻壳粉为原料,在600℃和N2氛围下煅烧完成后使用一步水热法制备了钝化剂修饰的碳量子点,得到荧光为蓝绿光的二酸铵(ACA-CQDs)改性稻壳基碳量子点.采用SEM/EDS、HRTEM、FTIR等现代分析技术对碳量子点进行了理化特性表征,发现二酸铵(ACA-CQDs)量子点可以成功检测水中的Pb(Ⅱ).建立了一种有效的检测水体中Pb(Ⅱ)简便快速高效的方法.     

硫化树脂对EPDM性能的影响

文中通过对三元乙丙橡胶化学结构的分析，探讨了多种硫化树脂与EPDM分子中的双键、巯基进行的交联反应，旨在提高EPDM制品的物理机械性能，减少其他配合剂的用量，防止硫化产品喷霜。实验证明，树脂硫化EPDM体系效果良好，在性价比方面国产WS硫化树脂具有较大的市场发展空间。     

Kinetics of the methanation of carbon dioxide over a supported Ni-La2O3 catalyst

The kinetics of the methanation of carbon dioxide was investigated using an alumina supported Ni-La₂O₂ catalyst in a differential and integral reactor. In the differential reactor the molar ratio of H₂ to CO₂ was varied from 0.6 to 30. In the integral reactor the rates were measured with up to 90% conversion. Both reactor tests were carried out at temperatures between 513 and 593 K. The experimental results were described by a Langmuir-Hinshelwood type equation. The kinetics can be explained by assuming equilibrium of dissociative carbon dioxide and hydrogen adsorption, and assuming hydrogenation of surface carbon as the rate determining step.     

抗氧剂3114合成反应热力学和动力学的研究

研究了常温溶剂法合成抗氧剂3114反应热力学和动力学过程。控制温度在117±2℃,研究结果表明,反应是零级反应,反应速率常数k=1.91×10-3/min,反应的平衡常数K=138.4(mol/L)-6,反应活化能Ea=1366.2J/mol。     

A growth mark method for studying growth mechanism of carbon nanotube arrays

A novel and simple growth mark method was developed to make marks during the growth process of carbon nanotube arrays. These marks can be read out under scanning electron microscope or optical microscope. Based on this method, the growth rates at different temperatures and under different acetylene partial pressures were measured, from which the activation energy and the order of reaction were determined. Based on our experimental results, the growth of carbon nanotube arrays in our experimental condition could not be diffusion-limited. The measured activation energy could possibly be attributed to the heterogeneous decomposition of acetylene over the catalyst particle. Furthermore the marked array with special segmental structure may be found some applications in the future.