Crosslinking of PVC and NBR blends

The purpose of our work is to control the interfacial bonds between PVC and NBR using the ammonium salts of triazine thiols and dithiodimorpholine (DTDM) and thereby reveal the relation between the interfacial bonds and the final mechanical properties of products. In the experimental work a two-stage process was used. At first, an NBR/PVC blend was mixed with a mono-tetra-n-butylammonium salt of triazine trithiol at a temperature of 100°C on a two-roll mill to give the branching structure of triazine thiols into PVC. In the second stage branched NBR/PVC reacted with DTDM to afford the branched PVC containing trithiomorphonyl groups. In the presence of ZnO at 160°C trithiomorphonyl groups react with NBR to form a crosslinking structure between NBR and PVC. The mechanical properties of cured NBR/PVC blends were markedly improved by the treatment process and after addition of tetramethylthiuram monosulphide also. The mechanical properties were not improved by increasing the concentration of TT-TBA (tetrabutylammonium salt of 1,3,5-triazine-2,4,6-trithiol) over 4.2 phr.     

Research and development related to PFM for aged nuclear components

At the Japan Atomic Energy Research Institute (JAERI), research activities related to probabilistic fracture mechanics (PFM) have been conducted as a part of the research program on aging and structural integrity of LWR components. This paper describes the outline of two activities related to PFM, i.e. the development of a PFM code and a contract research on ‘Application of PFM Methodology to Reliability Assessment of Nuclear Components’ implemented by the Japan Welding Engineering Society (JWES). In the former research, a new PFM code PASCAL (PFM Analysis of Structural Components in Aging LWR) was developed. This code has some new functions in models of semi-elliptical crack extension, elastic–plastic fracture analysis based on R6 method and options for the evaluation of overlay cladding and warm pre-stress (WPS) effect. Besides, the code has the function to evaluate the effect of irradiation embrittlement recovery by thermal annealing of a reactor pressure vessel and re-irradiation embrittlement. Based on the analyses on benchmark problem conducted by USNRC/EPRI, performance and functions introduced in the code were examined. Some case studies were also carried out to investigate the influence of various parameters. On the other hand, JAERI has been sponsoring the PFM related activities in relation to the structural integrity of LWR components. These activities have been conducted at JSME and JWES. The objective of this activity has been to provide for the future need of PFM methodology.     

PFC emission‐reduction strategy for the LCD industry

Abstract— The perfluorocarbons (PFCs) used as etching‐process and chamber‐cleaning gases in the manufacture of LCD devices have a high global‐warming potential and a long atmospheric lifetime. Thus, to voluntarily reduce these environmentally harmful PFCs, in 2001 the Japanese LCD association established the World LCD Industry Cooperation Committee (WLICC), together with its counterpart associations in the Republic of Korea and Taiwan. Since that time involving many discussions, the WLICC reached a consensus on reducing the aggregate absolute PFC emissions to the equivalent of less than 0.82 million metric tons of carbon by 2010. Each association has been taking whatever emission reduction steps it considers best to achieve this goal. Thanks to these measures, the PFC emissions from the Japanese LCD industry have remained at the same level, or less, than those of the year 2000, in spite of the fact that PFC purchases have continually increased. In the interim, the Japanese LCD association has been obtaining experimental data for the 2006 IPCC Inventory Guidelines, which will give the emission factors needed to estimate the PFC emissions. As a result, some data are quite different from emission factors given in the current 2000 Inventory Guidelines. All the data obtained have been submitted to the IPCC to be adopted in the new 2006 Guidelines.     

Electrical characteristics of B-implanted p-channelMNOS transistors

Boron ions (¹¹B⁺ of 3·7 to 7·4 × 10¹¹/cm² were implanted at 60–120 keV into the channel region of p-channel MNOS double layer insulated gate field effect transistors through 920–940 Å of SiO₂ and various thicknesses (300–1800 Å) of Si₃N₄ deposited on SiO₂. Subsequent annealing was performed in a nitrogen atmosphere at 1000°C for 30 min. Acceleration energy, implant dose and Si₃N₄ thickness dependences of the shift of the threshold voltage showed good agreement with the calculated results based on Ishiwara and Furukawa's theory for distribution of implanted atoms in the double layered substrate, using the projected ranges and standard deviations larger than LSS predictions by the factor of 1·2 for SiO₂ and 1·3 for Si₃N₄, respectively. The results on the gain terms and the breakdown voltages were qualitatively the same as those of ¹¹B⁺-implanted p-channel MOS transistors.     

Discharge behaviour of electrodeposited PbO2 and Pb electrodes

The discharge behaviour of electrodeposited lead dioxide and lead electrodes was investigated under various conditions; the surfaces of the discharged electrodes were observed with a scanning electron microscope. Both the positive and negative electrodes were passivated by a covering of deposited lead sulphate crystals. The amount of lead sulphate required for passivation depended on the size of the crystals.     

Interactions between sodium tetradecyl sulfate and a series of homogeneous polyoxyethyleneglycol- n- dodecyl ethers

The surface tensions of a mixed system of sodium tetradecyl sulfate (STS) and a series of polyoxyethyleneglycol-n-dodecyl ethers (nED) were measured at temperatures of 30 and 40 C, respectively. When the STS concentration was fixed, the surface tension curves of the mixed system showed a flat portion in the range of which the mixed micelles would be formed. With a decrease of the added STS concentration, the length of the flat portion in these curves decreased gradually, and finally disappeared in the presence of 0.05 mM STS. Furthermore, when the concentration of STS was fixed at 1.0 mM, which is below the critical micelle concentration (CMC), the flat portion length in the surface tension curves de-creased with decreasing ethylene oxide chain length in nED and with increasing temperature. The influence of increment of temper-ature was comparable to that for reducing the length of ethylene oxide chain in nED.     

A relational database machine with large semiconductor disk and hardware relational algebra processor

This paper describes the basic concepts, design and implementation decisions, standpoints and significance of the database machine Delta in the scope of Japan’s Fifth Generation Computer Project. Delta is planned to be operational in 1985 for researchers’ use as a backend database machine for logic programming software development. Delta is basically a relational database machine system. It combines hardware facilities for efficient relational database operations, which are typically represented by relational algebra, and software which deals with hardware control and actual database management requirements. Notable features include attribute-based internal schema in accordance with the characteristics found in the relation access from logic programming environment. This is also useful for the hardware relational algebra manipulation algorithm based on merge-sorting of attributes by hardware and a large capacity Semiconductor Disk for fast access to databases. Various implementation decisions of database management requirements are made in this novel system configuration, which will be meaningful to give an example for constructing a hardware and software combination of a relational database machine. Delta is in the stage between detailed design and implementation.