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991.
The design of a liquid/liquid contact apparatus necessitates the knowledge of fluid dynamics and mass transfer in the dispersion. Prediction of process parameters is challenging due to swarm and interfacial effects. Single drop investigations are suitable to enable a sophisticated dimensioning based on few simple experiments combined with published theories and correlations. In the first part of this article, the fundamentals of fluid dynamics and mass transfer in absence of interfacial effects were explained. Here, an overview of relevant interfacial phenomena and the influence of different substances typically occurring in technical applications as impurities or accompanying components is given. 相似文献
992.
Local droplet sizes and volumes of entrained liquid are captured with an image-based measurement technique for comparison with a conventional, integral method for entrainment analysis. Experiments in a forced circulation flash evaporation were performed for different operating conditions and with two different chemical systems. Droplet size and frequency rise with an increase in thermal energy input. The local readings confirm the trends found by the integral measurement method. The modification of the image-based probe enables the detection of small (≈ 10 µm) and at the same time fast droplets under challenging operating conditions, such as vacuum and superheated feed similar to industrial process conditions. 相似文献
993.
Marion Börnhorst Jens Friedland Bjarne Kreitz Emanuele Moioli Gregor Wehinger 《化学,工程师,技术》2021,93(8):1210-1213
In this article, the results of the NaWuReT (Early Career Reaction Engineers) workshop on the topic “Are we doing relevant science?” are presented. The topics “(In)surmountable hurdles for Citizen Scientists in reaction engineering?” and “Circular Economy in reaction engineering with/for society?” were discussed. Therefrom, a variety of ideas and suggestions were extracted. 相似文献
994.
Renaud Merlet Louis Winnubst Arian Nijmeijer Mohammad Amirilargani Ernst J. R. Sudhölter Louis C. P. M. de Smet Sara Salvador Cob Pieter Vandezande Matthieu Dorbec Soraya Sluijter Henk van Veen Yvonne VanDelft Ingrid Wienk Petrus Cuperus Subhalaxmi Behera Yusak Hartanto Ivo F. J. Vankelecom Patrick de Wit 《化学,工程师,技术》2021,93(9):1389-1395
Organic solvent nanofiltration (OSN) is gradually expanding from academic research to industrial implementation. The need for membranes with low and sharp molecular weight cutoffs that are able to operate under aggressive OSN conditions is increasing. However, the lack of comparable and uniform performance data frustrates the screening and membrane selection for processes. Here, a collaboration is presented between several academic and industrial partners analyzing the separation performance of 10 different membranes using three model process mixtures. Membrane materials range from classic polymeric and thin film composites (TFCs) to hybrid ceramic types. The model solutions were chosen to mimic cases relevant to today's industrial use: relatively low molar mass solutes (330–550 Da) in n-heptane, toluene, and anisole. 相似文献
995.
The increased use of carbon fiber reinforced thermosets generates more waste and end-of-life products. However, an efficient recycling method for the expensive carbon fibers has not yet been developed. The selective decomposition of amine-cured epoxy resin under mild conditions is presented. A two-step method was investigated to decompose the epoxy resin. The optimum parameters were initially determined using a model compound. By analysis of the reaction products, a cleavage of the C–N bond according to the Cope elimination could be proven. Therefore, the Cope elimination is suggested as the main step of the decomposition of amine-cured epoxy resins in presence of hydrogen peroxide. By dissolving the resin, it is possible to recover resin-free fibers with unimpaired mechanical properties. 相似文献
996.
Reliable prediction of flooding conditions is needed for sizing and operating packed extraction columns. Due to the complex interplay of physicochemical properties, operational parameters and the packing-specific properties, it is challenging to develop accurate semi-empirical or rigorous models with a high validity range. State of the art models may therefore fail to predict flooding accurately. To overcome this problem, a data-driven model based on Gaussian processes is developed to predict flooding for packed liquid-liquid and high-pressure extraction columns. The optimized Gaussian process for the liquid-liquid extraction column results in an average absolute relative error (AARE) of 15.23 %, whereas the algorithm for the high-pressure extraction column results in an AARE of 13.68 %. Both algorithms can predict flooding curves for different packing geometries and chemical systems precisely. 相似文献
997.
998.
Dr. Markella Konstantinidou Asmaa Oun Pragya Pathak Bidong Zhang Zefeng Wang Frans ter Brake Dr. Amalia M. Dolga Dr. Arjan Kortholt Dr. Alexander Dömling 《ChemMedChem》2021,16(6):959-965
Here we present the rational design and synthetic methodologies towards proteolysis-targeting chimeras (PROTACs) for the recently-emerged target leucine-rich repeat kinase 2 (LRRK2). Two highly potent, selective, brain-penetrating kinase inhibitors were selected, and their structure was appropriately modified to assemble a cereblon-targeting PROTAC. Biological data show strong kinase inhibition and the ability of the synthesized compounds to enter the cells. However, data regarding the degradation of the target protein are inconclusive. The reasons for the inefficient degradation of the target are further discussed. 相似文献
999.
Prof. Andrea Baier Dr. Anne Kokel Dr. William Horton Ewa Gizińska Dr. Garima Pandey Prof. Ryszard Szyszka Prof. Béla Török Prof. Marianna Török 《ChemMedChem》2021,16(12):1927-1932
A set of novel hydrazone derivatives were synthesized and analyzed for their biological activities. The compounds were tested for their inhibitory effect on the phosphorylating activity of the protein kinase CK2, and their antioxidant activity was also determined in three commonly used assays. The hydrazones were evaluated for their radical scavenging against the DPPH, ABTS and peroxyl radicals. Several compounds have been identified as good antioxidants as well as potent protein kinase CK2 inhibitors. Most hydrazones containing a 4-N(CH3)2 residue or perfluorinated phenyl rings showed high activity in the radical-scavenging assays and possess nanomolar IC50 values in the kinase assays. 相似文献
1000.
In this study, the underlying mechanism for improved spinnability when mixing lignin and cellulose in solution was investigated. Co-processing of lignin and cellulose has previously been identified as a potential route for production of inexpensive and bio-based carbon fibers. The molecular order of cellulose contributes to the strength of the fibers and the high carbon content of lignin improves the yield during conversion to carbon fibers. The current work presents an additional benefit of combining lignin and cellulose; solutions that contain both lignin and cellulose could be air-gap spun at substantially higher draw ratios than pure cellulose solutions, that is, lignin improved the spinnability. Fibers were spun from solutions containing different ratios of lignin, from 0 to 70 wt%, and the critical draw ratio was determined at various temperatures of solution. The observations were followed by characterization of the solutions with shear and elongational viscosity and surface tension, but none of these methods could explain the beneficial effect of lignin on the spinnability. However, by measuring the take-up force it was found that lignin seems to stabilize against diameter fluctuations during spinning, and plausible explanations are discussed. 相似文献