Neue Entwicklungen beim Hohlkatoden‐Gasflusssputtern. New Developments in Hollow Cathode Gas Flow Sputtering

The gas flow sputter technique was invented a few years ago particularly for the inexpensive fabrication of sophisticated ceramic layers. Meanwhile, it has matured and become increasingly powerful. Today it is on the verge of being applied in industrial fabrication processes. The present article gives an overview over the method, its characteristics and the numerous applications.     

俄气南供与天然气利用规划

介绍了俄气南供的供气方案，讨论了天然气的市场调查和价格的确定等问题。     

Rückgewinnung von Vinylchloridmonomer

The production of the polymer polyvinylchloride (PVC) emits a high amount of waste gas. The recovery of the evaporated base product vinylchoridemonomer (VC) is an important aspect for the economics of the whole process. Membrane and vacuum technology improve the efficiency and the economics of the recovery process considerably.     

激光光束质量因子的研究进展

本文详细分析了各种光场下光束质量M2因子。在不同的场中,A.E.Siegman当初所定义的M2因子,已经有了很大的变化,因而M2因子的特性也与当初不同,不仅M2因子可以大于等于1,而且可以小于1,甚至小于0。其反映的物理意义,也从经典场中的衍射极限倍数,变化为非经典场中的准直性量度以及对空间相干性的某些反映。此外还列举并分析了几种特殊的光束质量因子,最后讨论了M2因子应用的问题并指出了其局限性。     

Estimation procedure for the Weibull parameters used in the local approach

The local approach was recently proposed by Beremin and Mudry for evaluating the statistical behaviour of toughness results of materials. This approach introduces a stress parameter _w , termed the Weibull stress, as a measure of the fracture resistance of materials instead of the conventional toughness parameters such as K _c, _c and J _cl (critical stress intensity factor, CTOD and J-integral, respectively). The Weibull stress _w obeys the Weibull distribution with the two parameters m and _u (the shape and the scale parameter, respectively). The first parameter m is normally estimated to be 22 irrespective of the kind of material. In this paper a procedure for the determination of the Weibull parameters m and _u is developed. This procedure consists of the determination of the plastic zone ahead of the crack tip, from which cleavage fracture originates, and of the maximum likelihood estimation of the parameters m and _u based on the stress distribution in the plastic zone. Calculations using this procedure confirm that the distribution of the Weibull stress _w is a material property independent of specimen thickness, and in particular that the shape parameter m depends on the material, e.g. m12 for a German reactor pressure vessel steel (20 Mn Mo Ni 5 5). Using these parameters for the distribution of the Weibull stress the size effect in fracture toughness values is predicted and an improved agreement between theory and experiments is obtained compared to the Weakest Link model.     

稻壳基碳量子点对废水中Pb(Ⅱ)的检测

为了进一步实现生物质废弃资源的综合利用,以及对废水中污染物的检测,以稻壳粉为原料,在600℃和N2氛围下煅烧完成后使用一步水热法制备了钝化剂修饰的碳量子点,得到荧光为蓝绿光的二酸铵(ACA-CQDs)改性稻壳基碳量子点.采用SEM/EDS、HRTEM、FTIR等现代分析技术对碳量子点进行了理化特性表征,发现二酸铵(ACA-CQDs)量子点可以成功检测水中的Pb(Ⅱ).建立了一种有效的检测水体中Pb(Ⅱ)简便快速高效的方法.     

Kinetics of the methanation of carbon dioxide over a supported Ni-La2O3 catalyst

The kinetics of the methanation of carbon dioxide was investigated using an alumina supported Ni-La₂O₂ catalyst in a differential and integral reactor. In the differential reactor the molar ratio of H₂ to CO₂ was varied from 0.6 to 30. In the integral reactor the rates were measured with up to 90% conversion. Both reactor tests were carried out at temperatures between 513 and 593 K. The experimental results were described by a Langmuir-Hinshelwood type equation. The kinetics can be explained by assuming equilibrium of dissociative carbon dioxide and hydrogen adsorption, and assuming hydrogenation of surface carbon as the rate determining step.     

离子色谱法测定配煤、焦炭和焦油中的氯含量

研究了用带电导检测器的离子色谱对配煤、焦炭和焦油中的Cl- 进行测定的方法。在YSA型8126A-4# 阴离子分离柱上用3.5mmol/LNa2CO3、5.3mmol/LNaHCO3做淋洗液对Cl-进行测定,方法简便快速。Cl-的检出限为2×10-6。该法也适用于F-、NO2-、NO3-、SO42-等的测定。