Emission of trace toxic metals during pulverized fuel combustion of Czech coals

A study of the trace elements emission (As, Se, Cd, Co, Cr, Cu, Zn, Hg, Tl, Pb, Ni, Sn, Sb, V, Mn and Fe) from pulverized coal combustion has been made at six heating and power stations situated in the Czech Republic. The amount of chlorine in coal has considerable influence on volatilization of some elements such as Zn, Cu, Pb, Hg and Tl, which is explained by the formation of thermodynamically stable compounds of these elements with chlorine. Generally, the affinities for Cl follows the order Tl > Cu > Zn > Pb > Co > Mn > Sn > Hg. The experimental data indicates enrichment of some of the trace toxic elements in the emissions (Cu, Zn, As, Se, Cd, Sn, Sb, Hg and Pb) and good agreement was obtained by thermodynamic equilibrium calculations with a few exceptions. In the case of Fe, Mn, Co, Cr and Sn calculated values are overestimated in the bottom ash and there are zero predicted amounts of these elements in the fly ash. In comparison, the results from experiments show up to 80% of these elements retained in fly ash. This implies that there exist additional steps leading to the enrichment by Fe, Mn, Co, Cr and Sn of small particles. Such mechanisms could include the ejection during devolatilization of small inorganic particles from the coal of bottom ash particles, or disintegration of the char containing these metals to small particles of fly ash. On the other hand, there are slightly overestimated or similar values of relative enrichment factors for As, V, Cu, Cd, Sb, Tl and Pb in the fly ashes and zero predicted values for bottom ashes. Our experimental results show about 5% or less of these elements are retained in bottom ashes, so they probably remain in the bottom ash inside unburned parts of coal. Copyright © 2003 John Wiley & Sons, Ltd.     

鞍钢现有人造富矿产能及1600万t/a生铁规模的合理炉料结构的探讨

简要介绍了鞍钢现有人造富矿生产能力，分析了鞍钢生产1600万t／a生铁所需要的炉料数量、品种和质量，并提出了解决炉料缺口的方法和措施。     

Pool boiling on a superhydrophilic surface

Titanium Dioxide, TiO₂, is a photocatalyst with a unique characteristic. A surface coated with TiO₂ exhibits an extremely high affinity for water when exposed to UV light and the contact angle decreases nearly to zero. Inversely, the contact angle increases when the surface is shielded from UV. This superhydrophilic nature gives a self-cleaning effect to the coated surface and has already been applied to some construction materials, car coatings and so on. We applied this property to the enhancement of boiling heat transfer. An experiment involving the pool boiling of pure water has been performed to make clear the effect of high wettability on heat transfer characteristics. The heat transfer surface is a vertical copper cylinder of 17 mm in diameter and the measurement has been done at saturated temperature and in a steady state. Both TiO₂-coated and non-coated surfaces were used for comparison. In the case of the TiO₂-coated surface, it is exposed to UV light for a few hours before experiment and it is found that the maximum heat flux (CHF) is about two times larger than that of the uncoated surface. The temperature at minimum heat flux (MHF) for the superhydrophilic surface is higher by 100 K than that for the normal one. The superhydrophilic surface can be an ideal heat transfer surface. Copyright © 2002 John Wiley & Sons, Ltd.     

JETS,PLUMES AND BUOYANT JETS IN STATIC ENVIRONMENT

Turbulence represents an essential aspect in atmospheric and oceanic circulations.In particu-lar,it is a preponderant factor in the dispersion of pollutants of artificial or natural origin.Thevertical turbulent jets,plumes and buoyant jets discharging into static environment is one of themost important and basic flow patterns related with the environment pollution.These flows havenumerous important applications,for example,thrust augmentors,waste disposal plumes fromstacks and combustion systems,and significant problems of turbulent diffusion.     

Computer analysis,design and simulation of horizontal ground heat exchangers

This paper presents a new computerized procedure for dealing with the design of horizontal ground heat exchangers (HGHE). The computer program is based on the transient model of coupled nonlinear partial differential equations governing heat and mass flow in soils. The model is two-dimensional and delineates the operation of ground heat storage with the HGHE and such phenomena as freezing/thawing and drying/rewetting of soil moisture. Comprehensive climatological data, such as ambient temperature, solar radiation, wind velocity, rainfall, snowfall, snow characterstics, and water vapour pressure is used to simulate conditions at the ground surface over any required length of time. The package can be applied to any geographical location by changing climatic and soil data input. The designer has the possibility of selecting any of 12 types of soils from sand to clay, 12 commercial heat pumps, nine different configurations of the HGHE, 16 plastic pipes for ground coils, and 13 ground coil fluids. The program, however, does not calculate the length of the HGHE but it evaluates the thermodynamic performance of a ground heat pump system and provides comprehensive data on thermal and hydraulic conditions in ground heat storage. The length of the ground heat exchanger is obtained from a line source theory model or from site dimensions and pipe spacing. Computed results for ground heat exchanger operation correlate fairly well with experimental data. Simulation of temperature and moisture content in the ground for natural conditions (no heat extraction/deposition) showed a fair agreement with field data. The entire computer program is user-friendly, interactive, menu-driven, and written in FORTRAN 77.     

Analysis of brushless three-phase synchronous generator without exciter

Recently, a demand for small-capacity generators has been increasing as electric sources in small ships and automobiles or as portable electric sources driven by engines. It is desired that the structure of small-capacity generators be simple and robust, and that the generators be highly reliable, easily maintained and controlled. This paper describes an analysis of the original brushless synchronous generator without exciter. The output voltage can be adjusted in the wide range by controlling the stator dc current. To analyze the characteristics of this generator, the finite element method is applied. It is found that the results of theoretical analysis agree well with the experimental results.     

A feasibility study of a direct-mapping parallel processing method to solve linear equations in load-flow calculation

With the growing size and complexity of power systems, system analysis—such as transients calculation—takes much time. Hence, fast calculation methods are required. Although parallel processing is a hopeful method, there have been difficulties in the parallel solution of linear equations which appear in power-flow calculations by the Newton-Raphson method. This paper aims at the fast calculation of the power-flow problem by means of parallel processing. In order to improve the suitability to the parallel solution of the differential equation in transients calculation, we assume the use of a direct-mapping parallel processing machine to map directly the network of a power system onto a network of processors. Under this assumption, we propose a new parallel-processing-oriented method in which the linear equation is solved by linear iterations between nodes with Aitken acceleration. We simulate the method on three model power systems and compare this Parallel Iterative Method (PIN) with a Parallel Direct Method (PDM) which uses the banded matrix according to the number of operations required. As a result, we can expect that PIM may solve linear equations faster than PDM with m processors, although the PIM might be inferior to the PDM with m × m processors, where m denotes the half-band width of the banded matrix.     

Characterization and modification of fillers for paints and coatings

This paper highlights the possibility of inverse gas chromatography for the surface characterization of common fillers (CaCO₃, talc, SiO₂,) for paints and coatings. Divided solids are described, on the one hand, by the dispersive component of their surface energy and, on the other, by a specific parameter indicating their acid-base interaction potential. The role of the surface morphology at a molecular level is also examined. It is demonstrated that steric effects play an important role in the adsorption of probes on lamellar solids like talc. The consequences of surface treatments as well as examples of practical applications are also reported.     

Comparative studies on Ar and He closed-cycle MHD power plants combined with fossil fuel

Comparative studies on Ar and He closed-cycle MHD power plants combined with fossil fuel are performed. The sizes of a regenerative heat exchanger and a boiler are expected to be smaller for He than for Ar. The pressure loss of a working gas in a regenerative heat exchanger is reduced for He. The purification subsystem for He is expected to be more compact and economical than that for Ar; but a larger compressor is required for He than for Ar.     

Estimation of fouling in a plate heat exchanger through the application of neural networks

Pasteurization is an important, if not the most important, process step in the packaging of milk. It is subject to alterations stemming from the variation in the temperature, pH and raw milk quality. The variability may manifest itself in changes in the formation of the deposit (fouling) in the pasteurization unit, such that there is a need for tools, both instrumentation and computational, to help in monitoring the process and keeping it on the desired course. In this paper we describe a practical procedure based on artificial neural networks (ANN) that allows prediction of the deposit thickness, the overall heat transfer coefficient and the critical time (the time that the unit has to be stopped for cleaning) for reducing the impact of fouling on such processes. The procedure determines when the cleaning operation is required once the system is under critical conditions of operations. A combination of fundamental studies and plant measurements were used for study of the operating conditions and thus evaluation of the trades‐offs between operating conditions and longer operating life span. The results are encouraging, enough to validate current operating industrial techniques. Copyright © 2005 Society of Chemical Industry