湖北省谷城县蒋家沟金矿地质特征与成因浅析

总结了蒋家沟金矿成矿地质背景和矿床地质特征,对矿床成因进行了探讨。蒋家沟金矿赋存于中-上元古界武当岩群变酸性火山岩建造中,受顺层韧性剪切带控制,成矿物质主要来自火山岩围岩,成矿流体来自岩浆水和大气降水,矿床类型属韧性剪切带型。     

富氧氰化法从砷钴硫化矿浸钴渣中提金的研究

从含砷的多金属硫化矿中提金,一向棘手。本文提供了采用富氧氰化法从砷钴硫化矿加压氧化浸钴渣中提金的试验结果,其目的是要开辟一条湿法提金新工艺,解决这一难题。扩大试验结果完全验证了小型试验结果的可靠性。文中详细地叙述了富氧氰化原理,并对酸浸渣(细菌浸钴渣)做了富氧氰化与常规空气氰化提金的对比扩大试验。扩试数据表明,富氧氰化比常规空气氰化提金效果好,指标高,是一种很有前途的提金方法。     

某新生代红土型金矿选矿试验研究

针对云南某新生代红土型露天金矿金的粒度分布呈粗细极不均匀的特点,采用高离心力场重选工艺进行研究,较好地解决了粗粒金以及微细粒金的回收难题,当原矿金品位1.1g/t,精矿金品位47.23g/t,金回收率达到86.09%,获得了满意的选别指标。     

黑龙江黑河市争光岩金矿床地质特征及成因浅析

争光金矿床产于中奥陶统多宝山组中性火山岩和燕山期中酸性侵入体中,赋存于NWW、NNW向断裂构造带内,矿体呈脉状,具有膨缩和尖灭再现特点.中奥陶统多宝山组中性火山岩地层为金矿之矿源层,燕山期中酸性侵入体岩浆作用为金矿的形成提供了热源,构造作用对含金热液的流动与迁移提供了通道.该金矿矿床成因为热液-构造蚀变岩型.     

Heterogeneous Gold‐Catalyzed Selective Reductive Transformation of Quinolines with Formic Acid

Single phase rutile titania supported gold nanoparticles (Au/TiO₂‐R) are found to be efficient and versatile catalysts for chemo‐ and regioselective transfer hydrogenation of quinoline derivatives to 1,2,3,4‐tetrahydroquinolines (THQs) using formic acid (FA) as a safe and convenient hydrogen source under mild conditions. The activity and chemoselectivity of the Au/TiO₂‐R catalyst towards THQs is excellent, with a substrate to catalyst ratio (S/C) of 1000 being feasible. Furthermore, a straightforward and selective route to N‐formyltetrahydroquinolines (FTHQ) directly from quinoline compounds and FA by one‐pot, gold‐catalyzed reductive N‐formylation protocol is also established.

     

Methanobactin-Mediated Synthesis of Gold Nanoparticles Supported over Al2O3 toward an Efficient Catalyst for Glucose Oxidation

Methanobactin (Mb) is a copper-binding peptide that appears to function as an agent for copper sequestration and uptake in methanotrophs. Mb can also bind and reduce Au(III) to Au(0). In this paper, Au/Al₂O₃ catalysts prepared by a novel incipient wetness-Mb-mediated bioreduction method were used for glucose oxidation. The catalysts were characterized, and the analysis revealed that very small gold nanoparticles with a particle size <4 nm were prepared by the incipient wetness-Mb-mediated bioreduction method, even at 1.0% Au loading (w/w). The influence of Au loading, calcination temperature and calcination time on the specific activity of Au/Al₂O₃ catalysts was systematically investigated. Experimental results showed that decomposing the Mb molecules properly by calcinations can enhance the specific activity of Au/Al₂O₃ catalysts, though they acted as reductant and protective agents during the catalyst preparation. Au/Al₂O₃ catalysts synthesized by the method exhibited optimum specific activity under operational synthesis conditions of Au loading of 1.0 wt % and calcined at 450 °C for 2 h. The catalysts were reused eight times, without a significant decrease in specific activity. To our knowledge, this is the first attempt at the preparation of Au/Al₂O₃ catalysts by Mb-mediated in situ synthesis of gold nanoparticles.     

分级微球BiOBr和BiOI的制备及光催化活性比较

以五水硝酸铋、溴化钠和碘化钾为原料,乙二醇为溶剂,采用一步溶剂热法制备了分级结构微球BiOBr和BiOI。比较了两种催化剂在可见光和模拟日光下对罗丹明B的降解效果。结果表明,在模拟日光和可见光下,BiOBr的催化活性要好于BiOI,同时对机理进行了深入探讨。     

一种新型含咪唑基壳聚糖衍生物的合成方法和吸附性能研究

本文发现了一种合成新型氨基螯合物——N-4(5)-甲基咪唑壳聚糖(IMC),本文还通过凝胶合成法直接对4(5)-羟甲基咪唑的羟基进行取代。以上所得聚合物的结构均通过核磁共振确定。实验中,我们将样品分别与表氯醇、乙二醇缩水甘油醚、二乙二醇缩水甘油醚交联,并对吸附作用进行了研究。我们得到以下结论:聚合物的吸附作用和溶胀度取决于交联剂及其交联度;IMC对AuIII、PtIV和PdII离子的吸附作用高于非改性聚合物;随着交联度的增加,IMC从氯化物溶液中提取贵金属离子的过程变得更加有选择性;IMC对Co II和Ni II离子的吸附能力高于壳聚糖及其N杂环衍生物。     

W掺杂BiOCl光催化剂的制备及其可见光催化性能研究

在以Bi(NO3)3为铋源、WCl6为氯源和钨源、乙二醇为溶剂、尿素为添加剂形成的新Bi-W-Cl-O体系下采用一步溶剂热法合成W掺杂BiOCl光催化剂,应用XRD、FSEM、XPS和UV-Vis对样品进行表征,并以苯气体作为降解物,考察了W掺杂BiOCl光催化剂的光催化性能。结果表明,由于金属W的掺杂,BiOCl的吸收波长发生明显红移,相比于纯BiOCl提高了对太阳光的利用率,同时大大提高了BiOCl在可见光下的光催化降解苯效率。     

甘肃阳山金矿的三源成矿模式与找矿方向

阳山金矿位于陕甘川“金三角”的松潘—摩天岭金矿带,为一热液成矿的岩金矿床。区内成矿物质来源较复杂,包括矿区的赋矿地层三河口群和中生代花岗斑岩以及矿区南部的碧口地体;总体上阳山金矿带的成矿流体主要是岩浆水,在成矿晚阶段则有大气降水热液进入;区内多期次的岩浆活动为金矿的形成提供了热源。区内矿源、热源、水源丰富,成矿地质条件优越,符合“三源”成矿模式,具成矿远景。下步应加强对矿区成矿规律的研究,寻找新的矿体,同时布置工程进行验证,进一步扩大矿区的找矿规模。