同位素中子源活化瞬发分析装置

一、基本原理自六十年代中期以来,中子活化瞬发γ射线元素分析技术(PNAA)得到人们广泛重视。与通常的中子活化分析(NAA)技术相比,它分析的是样品中的主要成分,若用同位素中子源,还可进行实时在线连续测定及现场分析。PNAA技术是用热中子与待测元素发生中子俘获反应,处于激发态的产物核在瞬间     

Physico-chemical properties of ceramic pigments for high-temperature application

Heat resistant coatings are required primarily for stacks, exhaust pipes, reactors, space crafts and similar equipments that are permanently or occasionally exposed to elevated temperatures. High-temperature coatings are generally based on silicone resin with ceramic and metallic pigments. In this study, iron oxide, cobalt oxide (thermo chromic compound) and aluminum oxide are used for the preparation of four new types of coloured pigments. The thermal resistant characteristics of these ceramic pigments were studied by differential thermal analysis, thermo gravimetric analysis and differential scanning calorimetric analysis. These ceramic pigments are found to be thermally stable up to 400 °C.     

N.m.r. line shape-relaxation correlation analysis of bitumen and oil sands

The first results of the analysis of bitumen and oil sands using the recently developed n.m.r. spingrouping technique are presented. The n.m.r. relaxation experiments were carried out on bitumen, and on natural and dried oil sands samples. The results indicate that the spin-grouping can resolve and quantify several components of the samples studied. The bitumen and bitumen fraction of the oil sands are resolved according to their spin-spin relaxation times into three major groups: solid-like (rigid), solid-like (mobile) and semi-liquid. The water in the oil sands exists in two different environments. Tentatively one environment is assigned to be the bridges between the sand grains, while the other is assigned to be the clay surface. One can conclude that with spin grouping of complex mixtures the decomposition (in which components are resolved according to their dynamic state) is possible. The accuracy of such resolution is of the order of a few per cent.     

可交易水权改革若干问题的思考

从水权制度变迁理论分析入手,认定水权制度的改革不仅是一个简单的资源配置或生产力布局问题,更是涉及制度建设和一个国家管理体制的演化的问题。通过对已建立可交易水权为基础的水权制度改革作进一步探讨,提出了建立“准市场”和“地方政治民主协商”机制、构建合约化的水权交易市场、加快水权市场的布设与推广等相应的建议。     

Introduction of a nonlinearity measure for principal component models

Although principal component analysis (PCA) is an important tool in standard multivariate data analysis, little interest has been devoted to assessing whether the underlying relationship within a given variable set can be described by a linear PCA model or whether nonlinear PCA must be utilized. This paper addresses this deficiency by introducing a nonlinearity measure for principal component models. The measure is based on the following two principles: (i) the range of recorded process operation is divided into smaller regions; and (ii) accuracy bounds are determined for the sum of the discarded eigenvalues. If this sum is within the accuracy bounds for each region, the process is assumed to be linear and vice versa. This procedure is automated through the use of cross-validation. Finally, the paper shows the utility of the new nonlinearity measure using two simulation studies and with data from an industrial melter process.     

Feasibility analysis of membrane reactors – discovery of reactive arheotropes

A feasibility analysis methodology adopted from reactive distillation is applied to membrane reactors. A model is formulated to depict the reactive liquid phase composition on the retentate side of a continuous type membrane reactor. The effects of both the chemical reaction kinetics and the membrane mass transfer kinetics on the feasible products are elucidated by means of retentate phase diagrams and bifurcation analysis. The proposed method can be applied to various membrane processes, independent of the specific structure of the membrane. Two quaternary reaction systems are considered to illustrate the methodology. In the first hypothetical system, it is shown how selective membranes can influence the sequence of effective volatilities which in turn affects the feasible products of the system. In the second example of practical importance, i.e. the heterogeneously catalysed synthesis of propyl acetate coupled with permeation through a porous polycarbonate membrane, the dusty gas model is applied to describe the component fluxes through the membrane. For the latter reaction system, the existence of reactive arheotrope is demonstrated. Arheotropes represent mass transfer controlled feasible products of membrane separation process.     

甘三酯立体专一分析的研究：（Ⅱ）甘三酯立体专一分析方法初探

在第一部分综合讨论的基础上对甘三酯立体专一分析方法作了初步探讨。以液体油(菜油)及固体脂(猪脂)为基质,系统地研究了这一分析方法,取得了经验并补充了一些具体验证方法。分析液体油的结果与文献数据相一致,分析猪脂的结果欠佳,还存在一些问题需待进一步研究。     

机械结构动态改进技术在电动机振动噪声防治中的应用

本文介绍了结构实验模态分析、灵敏度分析和局部结构改进分析等先进的结构动态改进技术的基本原理,并由此对Y112M-4型电动机的机座进行了计算和分析,确定出一个结构改进方案.经实际改进试验验证,这一改进可有效地抑制电动机电磁振动和电磁噪声的传递,具有明显的减振降噪作用.     

川西低渗气藏单井地应力计算方法综合研究

四川盆地新场气田是一个低孔低渗的裂缝性砂岩气田，储层物性差，自然产能低，需经压裂后才能投产，压裂后气井增加的产能与压裂的效果密切相关。提前认识储层当前地应力的特征，有助于压裂设计时确定裂缝产状、缝长、缝宽等参数，减少储层水力压裂改造的盲目性，降低中、低渗透油气田开发的风险。通过大量测井资料的计算，确定了新场气田储层地应力的大小和方向，并综合采用微地震测量、岩石声发射资料、古地磁等岩心测试资料和水力压裂等多种方法进行交互验证，各种方法求得的地应力特征十分相近，说明利用测井资料求取储集层地应力原理简单，计算结果符合实际的地应力特征，是一种低风险研究计算储层地应力特征的方法，可以用于指导低渗透油气田的井网部署和储层的单井压裂改造。     

美国国家公园申报准则及审议程序

本文所讲述的是美国国家公园服务中心在评估申请提案、制定审查方案过程中所应用的各种标准和准则 ,同时也列出了一些认识、保护未列入国家公园体系中其他重要资源的途径和方法。