Loss of Curing Agent During Thin Film (Droplet) Curing of Thermoset Material

Recently, it has been reported by our group and others^1.2 that loss of curing agent is encountered during the curing of small droplets or thin films of amine cured epoxies. In our earlier study³ results were reported on loss of curing agent in small droplets used in conducting the rnicrobond, single fiber test for determination of interfacial shear strength (ISS). It was reported that use of a volatile curing agent (meta-phenylene diamine (m-PDA) with DGEBA resin) resulted in increasing amounts of curing agent being lost (as measured by T₈ of the cured droplets) with decreasing droplet size during the processing procedure. Droplets smaller than 150 micrometers were seen to lose up to 40% of the curing agent leading to alteration of the mechanical properties of the droplet and, therefore, causing measured values of ISS to be exceedingly low. Use of a less volatile curing agent (Jeffamine 700, a polyether diamine, Texaco Specialty Chemicals) in combination with DGEBA resin produced results which indicated that loss of curing agent was not occuring. This study was undertaken to show the relationships between film (or droplet) size and the amount of curing agent lost (during the processing) for three different aminecured epoxy systems.     

Research on Variable Structure and Adaptive Control for Strap-on Rocket

固体捆绑运载火箭变结构自适应控制

陈曦,刘玉玺,汪轶俊

（上海宇航系统工程研究所）

创新点说明：

对于新型固体捆绑火箭而言,由于箭体安装固体助推器,存在推力偏差较大、推力同步性较大的问题,导致火箭的结构干扰增大。安装尾翼外干扰增大,如经过大风区时,风干扰对箭体产生较大的影响。同时考虑建立动力学模型的过程中存在的参数不确定性、参数摄动、三通道间耦合的问题,传统的控制方法难以满足新型固体捆绑火箭的要求,因此本文率先将基于模型参考的变结构自适应控制方法应用于固体捆绑运载火箭上。

研究目的：

本文针对固体捆绑运载火箭控制系统的特点,应用变结构自适应控制理论,设计适用于固体捆绑运载火箭的控制系统,保障固体捆绑运载火箭的正常飞行。

研究方法：

（1）建立固体捆绑运载火箭动力学模型,考虑模型中参数不确定性、未建模动态及通道间耦合;

（2）分析固体捆绑运载火箭存在的干扰,例如：四个固体助推带来的推力偏差、推力不同步性、推力线偏斜,质心横移、芯级、发动机及尾翼安装误差、芯级发动机液体燃料晃动、箭体弹性振动等各类结构误差及风干扰等外干扰;

（3）针对固体捆绑运载火箭设计变结构自适应控制律的设计并证明其稳定性;

（4）Simulink仿真分析验证。

结果：

本文使用变结构自适应控制理论设计的控制系统可全局渐进稳定,三通道姿态角跟踪误差较小,姿态角收敛速度较快,系统性能良好,可有效处理各类结构干扰、外干扰、气动参数不确定性及未建模动态等问题,该控制系统的动态特性及控制品质良好,具有工程应用的前景。

结论：

本文将基于模型参考的变结构自适应控制方法应用于新型固体捆绑运载火箭的控制系统的设计中。给出了仅有俯仰方向有大姿态变动的条件下的火箭动力学偏量模型,并在此基础上设计变结构自适应控制律,同时证明了该控制系统的稳定性。本文通过理论及仿真分析,证明了变结构自适应控制理论在新型固体捆绑运载火箭上的应用可行性,具有一定的工程应用前景。

关键词：运载火箭;模型参考;变结构控制;自适应控制

     

浅议高职院校科研成果转化问题

当前,高职院校科研工作发展迅速,但是往往"重研究,轻应用",科研成果转化数量少,这是一种资源的浪费。高职院校科研成果转化具有重要的现实意义,应该得到大力发展。文章分析了当前高职院校科研成果转化存在的问题,提出了促进高职院校科研成果转化的对策建议。     

TWO KINDS OF VARIANT IN SHAPE MEMORY MATERIAL

In shape memory materials,that have been trained to have a two way shape memory effect(TWSM),themartensitic variants are classified into two groups,i.e.,preferentially oriented variants and self-accommodatingvariants.Applied stress may promote or constrain the transition of preferentially oriented variants and so changetransformation temperatures but has no essential effect on self-accommodating variants.According to the pointof view mentioned above,some experimental phenomena during thermocycling of a TWSM device may be ex-plained,such as the absence of synchronization between the plot of resistance change.temperature and the plotof memory strain vs.temperature.     

马氏体相变研究的进展和瞻望SCIEI

叙述马氏体相变研究的一些进展和瞻望,包括马氏体相变的定义,马氏体相变热力学,奥氏体状态对马氏体相变的影响,动力学,形核和长大,以及马氏体相变晶体学。     

Abnormal Austenite-Ferrite Transformation Behaviors of Fe-ISi: Dilatometric Measurements

WITH THE APPEASING of competition of the totaloutput of iron and steels, the new generation of ultrahigh strength steel, based on the lessen the burden ofenvironment, double improvement of mechanicalproperties and elongation of the serving life, has beenfully outspreaded in the world. More and more researchwork shows that the solid-state microstructureevolution becomes the most effective route in thedevelopment of ultra-high strength steels. A process ofgreat interest in the steel produc…     

Stabilization of One‐Dimensional Schrödinger Equation with Variable Coefficient under Delayed Boundary Output Feedback

This article considers stabilization of a one‐dimensional Schrödinger equation with variable coefficient and boundary observation which suffers from an arbitrary given time delay. We design an observer and predictor to stabilize the system. The state is estimated in the time span where the observation is available, and also predicted in the time interval where the observation is not available. It is shown that the estimated state feedback stabilizes the system exponentially. A numerical simulation is presented to illustrate the effect of the stabilizing controller.     

C语言中有关内存概念的教学研究

为使学生能快速掌握C语言的相关概念,为今后进行程序设计打下良好的基础,针对在教学过程中学生难以理解的几个问题,结合实例探讨了C语言中有关内存概念的教学方法,着重分析了内存与数组、函数参数、变量的作用域和生成期之间的关系。