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1.
本文用计算机数字模拟方法研究了电活性分子多层Z型L-B膜修饰电极的循环伏安行为。计算了电极与修饰L-B膜分子第一层之间的电荷转移速度常数K_o,L-B膜分子层间的电荷转移速度常数k_i;对峰电位差△E_p及阳极峰面积Q的影响,以及在不同条件下各层分子的氧化态分数随扫描时间的变化。为研究和设计电活性分子修饰电极的实际体系提供了大量数据和信息。 相似文献
2.
In order to cumpare the peformance of different supply diffuers of ventilation air, the airflow passern, temperature stratifiation and contaminant dispersion in a furnitured office ventilated by three kinds of air diffuer were numerically investigated. The air diffuers studied in this paper are a quarter-cylinder displacement diffuer on the floor and mixing diffuers (linear and vortex diffuers) on the ceiling. The heat sources in the of-fice are considered to be 50% convective and 50% radiative. The k-? two-equatwn model of turbulence is employed to predict the turbulent diffusion. The results show that the displacement diffuser provides a rather uniform flow field with low velocify in most areas, and the vertical temperature difference from floor to ceiling is as high as 6 K. With the linear diffuser, the air velociry is high, and the temperature is uniform both horizontally and vertically. The air velocity generated by the vortex diffuser is moderate. The distributions of the temperature and the contaminant are rather uniform. 相似文献
3.
分析了目前公用交换电话网(PSTN)中存在的问题和下一代网络(NGN)的优越性,分析了NGN中的关键技术媒体网关控制技术,探讨了媒体网关控制技术在Alcatel5020MGC中的实际应用,讨论了Alcatel5020MGC的软硬件系统架构。最后强调了在PSTN向NGN发展过程中基于演进产品的方法的重要性。 相似文献
4.
M. J. O'sullivan 《国际能源研究杂志》1985,9(3):319-332
This paper is intended to be a state of the art review of geothermal reservoir simulation. Its recent application to the modelling of real geothermal reservoirs is described and put in the context of an emerging general approach to reservoir modelling. The use of computer simulation for geothermal well test analysis is described. One of the main recent uses of reservoir simulators has been for conducting numerical experiments aimed at improving the understanding of geothermal reservoir physics. Such studies on fractured reservoirs, the thermal structure of reservoirs and the effects of non-condensable gases and dissolved salts are outlined. 相似文献
5.
Z. Gruba? 《Materials Letters》2007,61(3):794-798
The initial stage of copper electrodeposition on the electrochemically activated assembly of carbon microelectrodes from an acid solution of copper sulfate was investigated using cyclic voltammetry, potentiostatic pulse technique and electrochemical impedance spectroscopy. Analysis of the experimental current transients has been carried out using a non-linear fitting procedure according to the model that takes into account spherical diffusion towards a disc-shaped microelectrode. The higher values of diffusion coefficient in comparison with those observed on planar electrodes were explained with an increased diffusion caused by the electrode geometry. Impedance spectra showed two time constants, the high-frequency related to the charge transfer process and the low-frequency corresponded to the deposit morphology. 相似文献
6.
Hitoshi Kurokawa Taku Nakayama Yasunori Kobayashi Ken Suzuki Mutsumi Takahashi Seiichi Takami Momoji Kubo Naotsugu Itoh Parasuraman Selvam Akira Miyamoto 《Catalysis Today》2003,82(1-4):233-240
A modified Monte Carlo (MC) simulation was performed to investigate the hydrogen absorption behavior in Pd and Pd–Ag alloys of the composition PdxAg1−x (x=0.7–0.8) under H2 pressure (0.1 MPa) at different temperatures. The present method employed can consider the dissociative adsorption of hydrogen molecule and the subsequent absorption of hydrogen atom by formalizing the relationship between the pressure of hydrogen molecule and hydrogen atom. The potential parameters were determined to reproduce the solution enthalpy of hydrogen in pure metals. The results are in good agreement with experimental findings as well as previous theoretical studies. We confirmed that our method is useful to simulate the absorption of hydrogen in metals and alloys. 相似文献
7.
《Drying Technology》2007,25(11):1803-1808
Malting is a very intensive, energy-consuming process and, from the point of view of energy, green malt drying is one of the most important operations. Double-deck kiln drying, a variant of single-deck kiln drying, is the most commonly used process, but it is usually manually controlled under empirical control actions. These are the reasons why a research project was carried out based on the computer modeling of these process operations including a software tool named CIMFOOD. A knowledge-based system (KBS) allowing the entire processing-plant dynamic behavior simulation and scheduling concerning thermal energy requirements was developed. 相似文献
8.
Agnieszka J Klemm Piotr Klemm Kazimierz Rozniakowski Tomasz W Wojtatowicz 《Building and Environment》2002,37(12):1221-1232
This paper present the results of the investigation into a potential application of laser radiation for the detection of phase transition processes occurring on the surface layers of porous materials. An attempt was made to discuss in the approximation equations, the relationships between coefficients of the reflected light, the temperature and humidity of the surrounding environment. Laser light reflected from the porous surface carries information about the roughness of the structure. The presence of water microdrop on the surface of the porous material, as a result of condensation and thus a phase transition, leads to the phase displacement of individual rays, which is represented by different images. Therefore, a comprehensive analysis of the reflected light parameters allows a dynamic study of the phase transition phenomena without mechanical intervention. 相似文献
9.
This article presents a two-dimensional transient model for gas-solids flow and heat transfer through pipes using the coupled Computational Fluid Dynamics and Discrete Element Method approach. Numerical simulations have been conducted to examine the modification of fluid thermal structure due to the presence of particles in a pneumatic transport pipeline. Modeled results have demonstrated the key role of transversal motion of rebounding particles in the pipe cross section in altering fluid temperature. Further implementation of this modeling technique in air-drying processes is discussed and possible experimental methods for the measurement of in situ particle and fluid motion and temperature profile are cited. 相似文献
10.
Reviews the book, ILe choc de l'informatique: Les répercussions psychosociales et le r?le des attitudes by Serge Guimond and Guy Bégin (1987). This monograph is concise and easy to read. The reader knows immediately that technological questions will be explored, as well as the psychological and human questions being attached to the new use of information technology. Three fields are covered, each one the subject of a chapter: 1) computers in the educational circle; 2) computers and work; and 3) computers in the house. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献