γ-radiation effects on metal oxide particles and their wetted surfaces

ABSTRACT

Typical metal oxide corrosion products of structural materials have been irradiated with γ-rays in ultra-pure water to investigate the effect of radiation on the surface oxide and the nature of adsorbed water. Analysis techniques including thermal gravimetric analysis, differential thermal analysis, diffuse reflectance infrared Fourier transform spectroscopy, and X-ray photoelectron spectroscopy before and after γ-irradiation were employed to investigate surface structural effects and adsorbed water behaviour. The production of H₂ in the oxide nanoparticle mixtures was investigated by gas chromatography to probe the mechanism of radiolysis in the water/oxide mixtures and the relationship with surface water. The nature of water at the surface of the oxides was affected by γ-radiation and the relationship was dependent on the particle composition. The rate of H₂ production was shown to be oxide dependent, and higher rates of H₂ formation were attributed to the decomposition of surface adsorbed water. Changes to the surface chemistry and H₂ production rates were found to be highly dependent on the surface chemistry of the metal oxide nanoparticle and no bulk structural changes were observed.     

Three-dimensional layered porous graphene aerogel hydrogen getters

Organic getters are often introduced into sealed systems to remove the excessive reactive hydrogen gas. In this work, the formable graphene aerogel hydrogen getters are prepared by integrating the alkyne-containing molecules (e.g., DEB) into the palladium-loaded three-dimensional layered porous graphene aerogel (Pd-GA). The performance of Pd-GA/DEB composite materials in reducing reactive hydrogen gas is examined at pressures of 0.1–1 bar at a temperature of 25 °C, and the hydrogen consumption is measured as a function of time. Results suggest that the hydrogen uptake capability of Pd-GA/DEB getters increases with the loading of Pd particles on the GA and the content of Pd⁰. The highest hydrogen absorption capacity is up to 215.5 cm³/g, and the hydrogenation rate of DEB molecules is 89.3%. This study promotes the fundamental understanding of solid-phase catalytic hydrogenation and the applications of 3D layered porous graphene aerogel in hydrogen absorption.     

空压机站的振动与噪声治理

分析了空压机站振动和噪声产生的原因,提出了减振消声的具体办法,介绍了振动与噪声治理工程取得的成果。     

浅议SMC轻质内隔墙板在工程中的应用

阐述了SMC隔墙板组成材料及主要技术性能指标，介绍了SMC轻质内隔墙板在工程中的工艺流程及安装要点，提出具体的质量要求，指出SMC隔墙板质轻、隔音、性能稳定，有广泛的应用前景。     

两功能溴化锂吸收式直燃机与电动压缩式冷水机组的经济性分析比较

对深圳市某一建筑物集中空调系统机房主要设备分别采用溴化锂吸收式直燃机和电动式冷水机及其配套设备进行了详细的比较。指出前者的初投资、年运行费用、设备占地面积均比后者大。     

独栋住宅土壤源热泵系统冬季供暖实证研究

本文以1栋上海地区独栋住宅为对象,对土壤源热泵系统冬季供暖性能和能效进行了实证研究.通过对系统运行参数的连续监测,实证了地埋管换热器每米埋管取热量、机组与系统的COP及系统节能率等指标.结果表明:地埋管换热器出水温度及循环温差较为稳定,埋管换热量为27 ～ 32 W/m;系统能效受部分负荷率影响较大,整个测试期系统COP在3.3～3.9之间;在满足同等舒适性条件下,土壤源热泵系统比空气源热泵节能31.0％,节能效果明显.     

CISPR 20:2005介绍

介绍了CISPR 20:2005新增及变化的内容.对新增加的测试项目如电快速脉冲群、静电放电等进行了说明,增加了图像质量客观评价的方法、频率范围、性能判据变化等内容,并对屏蔽效果新的测试方法进行了介绍.     

Enhanced sound absorption properties of porous ceramics modified by graphene oxide films

Under the condition of constant thickness, improving the low-frequency sound absorption performance of conventional sound-absorbing materials is a challenging research topic. To address this issue, a new reduced graphene oxide/polyvinyl alcohol (RGO/PVA) porous composite ceramic was fabricated using freeze-drying and optimized by redesigning the internal connecting pores of porous ceramic matrixes with a reticular microstructure using RGO and PVA. The as-prepared porous structure showed significant enhancement in the low-frequency sound absorption band compared with pristine porous ceramics. In addition, the hybrid porous ceramics exhibited low thermal conductivity. These favorable properties indicate that the hybrid sound-absorbing ceramics have potential application prospects for noise reduction in the fields of construction and electrical and mechanical devices.     

平均声压级的简化算法及其误差修正

首先利用傅里叶级数的理论分析了机器噪声测试中平均声压级近似计算的误差,推导出了最大误差计算公式,其次基于误差公式指出国际标准中仅凭借测点声压级的波动范围来决定该近似方法的适用性是不合理的,还要考虑声压级的算数平均/10-最小声压级/10的值,最后对超过允许误差而不能使用该近似方法的情况加以修正,拓展了该方法的应用范围,有利于该方法的推广应用.     

Pharmacokinetic Comparison of Berberine in Rat Plasma after Oral Administration of Berberine Hydrochloride in Normal and Post Inflammation Irritable Bowel Syndrome Rats

In the present study, post inflammation irritable bowel syndrome (PI-IBS) rats were firstly established by intracolonic instillation of acetic acid with restraint stress. Then the pharmacokinetics of berberine in the rat plasma were compared after oral administration of berberine hydrochloride (25 mg/kg) to normal rats and PI-IBS rats. Quantification of berberine in the rat plasma was achieved by using a sensitive and rapid UPLC-MS/MS method. Plasma samples were collected at 15 different points in time and the pharmacokinetic parameters were analyzed by WinNonlin software. Compared with the normal group, area under the plasma concentration vs. time curve from zero to last sampling time (AUC_0–t) and total body clearance (CL/F) in the model group significantly increased or decreased, (2039.49 ± 492.24 vs. 2763.43 ± 203.14; 4999.34 ± 1198.79 vs. 3270.57 ± 58.32) respectively. The results indicated that the pharmacokinetic process of berberine could be altered in PI-IBS pathological conditions.