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1.
Reliable prediction of flooding conditions is needed for sizing and operating packed extraction columns. Due to the complex interplay of physicochemical properties, operational parameters and the packing-specific properties, it is challenging to develop accurate semi-empirical or rigorous models with a high validity range. State of the art models may therefore fail to predict flooding accurately. To overcome this problem, a data-driven model based on Gaussian processes is developed to predict flooding for packed liquid-liquid and high-pressure extraction columns. The optimized Gaussian process for the liquid-liquid extraction column results in an average absolute relative error (AARE) of 15.23 %, whereas the algorithm for the high-pressure extraction column results in an AARE of 13.68 %. Both algorithms can predict flooding curves for different packing geometries and chemical systems precisely. 相似文献
2.
3.
Pyrolysis experiments were performed in high vacuum and under reduced air pressure (100 Pa). The volatile products of pure cellulose and cellulose containing various amounts of flame retardant 2,2′-oxybis (5,5-dimethyl-1,3,2-dioxaphosphorinane-2,2′-disulfide), i.e., Sandoflam 5060 of Sandoz AG, were studied by means of gas chromatography in combination with mass spectroscopy. The volatile products were characterized with infrared spectroscopy. The studied revealed that the incorporation of the flame retardant enhanced the water release and shifted the onset of this reaction to lower temperature. On the basis of these findings an explanation for the mechanism of flame retardancy in generated cellulose fibers modified with this particular flame retardant is attempted. From experiments with different residual air pressure the influence of oxygen on the primary processes of the pyrolytic degradation of cellulose is being discussed. 相似文献
4.
Heidi Bernas Arie J. Plomp Johannes H. Bitter Dmitry Yu. Murzin 《Catalysis Letters》2008,120(1-2):8-13
The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt6 particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (Eads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites. 相似文献
5.
Pre-pruning and Post-pruning are two standard techniques for handling noise in decision tree learning. Pre-pruning deals with noise during learning, while post-pruning addresses this problem after an overfitting theory has been learned. We first review several adaptations of pre- and post-pruning techniques for separate-and-conquer rule learning algorithms and discuss some fundamental problems. The primary goal of this paper is to show how to solve these problems with two new algorithms that combine and integrate pre- and post-pruning. 相似文献
6.
An analog circuit structure for the realization of discrete-time cellular neural networks (DTCNNs) is introduced. The computation is done by a balanced clocked circuit based on the idea of conductance multipliers and operational transconductance amplifiers. The circuit is proposed for a one-neighborhood on a hexagonal grid, but can also be modified to larger neighborhoods and/or other grid topologies. A layout was designed for a standard CMOS process, and the corresponding HSPICE simulation results are given. A test chip containing 16 cells was fabricated, and measurements of the transfer characteristics are provided. The functional behavior is demonstrated for a simple example. 相似文献
7.
The improved performance of gain-coupled DFB lasers incorporating a titanium surface Bragg grating and a strained layer multiquantum well active region for operation at 1.55 μm is presented. Besides the essentially simplified fabrication process, the incorporation of the metallic, absorptive grating yields stable singlemode operation with a high sidemode suppression 相似文献
8.
Johannes Bröcker 《The Annals of Regional Science》1998,32(1):91-114
The question posed in the title of the paper is answered by simulating EU-integration of the Visegrád-countries by a spatial
computable general equilibrium (SCGE) model. A two-sector model is calibrated for a system of almost 100 regions covering
the whole area of Europe and a rest of world region. The sectors are a local sector, producing non-tradables under perfect
competition, and a tradables sector, producing a large number of tradable varieties under monopolistic competition. Trade
between regions is costly, with costs depending on geographic distance and national impediments to trade. The model is calibrated
such that the equilibrium solution reproduces benchmark data about international trade and regional incomes. Economic integration
is simulated by reducing impediments to trade between integrating countries and calculating a new counterfactual equilibrium. 相似文献
9.
Johannes Lehrhofer 《电子产品世界》2002,(13):69,51
引言 电子商务是建立在信任基础上的.在现实世界中,信任是通过人际关系、签名及其他证明方式建立起来的.而在电子世界里,信任的创建必须脱离这些书面的证明方式.事实上,电子身份证可提供确凿的证据,表明客户及厂商的真实身份. 相似文献
10.
Johannes Klopf Christine Brostjan Wolf Eilenberg Christoph Neumayer 《International journal of molecular sciences》2021,22(2)
Neutrophils are primary effector cells of innate immunity and fight infection by phagocytosis and degranulation. Activated neutrophils also release neutrophil extracellular traps (NETs) in response to a variety of stimuli. These NETs are net-like complexes composed of cell-free DNA, histones and neutrophil granule proteins. Besides the evolutionarily conserved mechanism to capture and eliminate pathogens, NETs are also associated with pathophysiological processes of various diseases. Here, we elucidate the mechanisms of NET formation and their different implications in disease. We focused on autoinflammatory and cardiovascular disorders as the leading cause of death. Neutrophil extracellular traps are not only present in various cardiovascular diseases but play an essential role in atherosclerotic plaque formation, arterial and venous thrombosis, as well as in the development and progression of abdominal aortic aneurysms. Furthermore, NETosis can be considered as a source of autoantigens and maintains an inflammatory milieu promoting autoimmune diseases. Indeed, there is further need for research into the balance between NET induction, inhibition, and degradation in order to pharmacologically target NETs and their compounds without impairing the patient’s immune defense. This review may be of interest to both basic scientists and clinicians to stimulate translational research and innovative clinical approaches. 相似文献