全文获取类型
收费全文 | 113207篇 |
免费 | 22625篇 |
国内免费 | 4331篇 |
专业分类
电工技术 | 6529篇 |
技术理论 | 5篇 |
综合类 | 5206篇 |
化学工业 | 28716篇 |
金属工艺 | 4872篇 |
机械仪表 | 6182篇 |
建筑科学 | 7211篇 |
矿业工程 | 2662篇 |
能源动力 | 3086篇 |
轻工业 | 12596篇 |
水利工程 | 1960篇 |
石油天然气 | 3963篇 |
武器工业 | 818篇 |
无线电 | 15928篇 |
一般工业技术 | 20140篇 |
冶金工业 | 4452篇 |
原子能技术 | 961篇 |
自动化技术 | 14876篇 |
出版年
2024年 | 400篇 |
2023年 | 1604篇 |
2022年 | 3116篇 |
2021年 | 4613篇 |
2020年 | 4546篇 |
2019年 | 5592篇 |
2018年 | 5787篇 |
2017年 | 6366篇 |
2016年 | 6466篇 |
2015年 | 7672篇 |
2014年 | 8408篇 |
2013年 | 10173篇 |
2012年 | 8481篇 |
2011年 | 8497篇 |
2010年 | 7565篇 |
2009年 | 7007篇 |
2008年 | 6541篇 |
2007年 | 5812篇 |
2006年 | 5265篇 |
2005年 | 4262篇 |
2004年 | 3382篇 |
2003年 | 3063篇 |
2002年 | 2932篇 |
2001年 | 2545篇 |
2000年 | 2335篇 |
1999年 | 1662篇 |
1998年 | 1064篇 |
1997年 | 926篇 |
1996年 | 791篇 |
1995年 | 658篇 |
1994年 | 531篇 |
1993年 | 364篇 |
1992年 | 306篇 |
1991年 | 251篇 |
1990年 | 211篇 |
1989年 | 198篇 |
1988年 | 126篇 |
1987年 | 106篇 |
1986年 | 85篇 |
1985年 | 66篇 |
1984年 | 44篇 |
1983年 | 53篇 |
1982年 | 40篇 |
1981年 | 36篇 |
1980年 | 39篇 |
1979年 | 28篇 |
1978年 | 23篇 |
1977年 | 16篇 |
1976年 | 22篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Pengfei Liang Jie Zhu Di Wu Hui Peng Xiaolian Chao Zupei Yang 《Journal of the American Ceramic Society》2021,104(6):2702-2710
Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO2-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag+/Nb5+ co-doped (Ag1/4Nb3/4)xTi1−xO2 (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 103 and 1.6 × 104 at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics. 相似文献
2.
Zhao Jiandong Lei Wei Li Zijian Zhao Dongfeng Han Mingmin Hou Xiaoqing 《Multimedia Tools and Applications》2022,81(4):4753-4780
Multimedia Tools and Applications - The crowding in bus is an important factor affecting passenger satisfaction and bus dispatching level. However, how to use video images to detect crowding... 相似文献
3.
Chao Chen Qixin Zhong Zhengxing Chen 《International Journal of Food Science & Technology》2022,57(5):2747-2755
The purpose of this study was to increase the water solubility and potential bioavailability of quercetin by encapsulation in whey protein isolate (WPI) based on a green, efficient pH-driven method. According to the results, the water solubility of quercetin increased by 346.9: times after loading into WPI nanoparticles. When the initial quercetin concentration was 0.25 mg mL−1 and WPI was 2% w/v, the encapsulation efficiency reached 94.1%, the Z-average diameter was 36.63 nm, and the zeta potential was −36.4 mV at pH 7.0. The fluorescence spectroscopy assay suggested the molecular complexation of quercetin and WPI at pH 12.0. X-ray diffraction assay indicated the enclosure of amorphous quercetin in WPI. Correspondingly, the bioaccessibility increased from 2.76% to 31.23% and the Caco-2 cell monolayer uptake increased from 0% to 2.12% after nanoencapsulation. This work confirmed that the pH-driven method is an effective approach to prepare WPI–quercetin nanocapsules to improve physical and potentially biological properties of quercetin. 相似文献
4.
有机-无机压电材料是一种分子铁电体,具有柔性、结构灵活、易成膜、全液相合成及环保节能等优点,可满足新一代薄膜器件及可穿戴设备的需求。该文以三甲基卤代甲基铵(TMXM, X=F, Cl, Br)为有机部分,MnCl2为无机部分,通过溶液蒸发法制备了具有钙钛矿分子结构的有机-无机压电材料三甲基氯三氯化锰(TMCM-MnCl3),并对其分子结构组成、压电、热学、声学及铁电性进行表征。结果表明,TMCM-MnCl3的压电常数为106 pC/N,居里温度为130 ℃,声阻抗值约为16.5 MRayl,低于压电陶瓷PZT-4(大于33 MRayl),具有广阔的应用前景。 相似文献
5.
6.
8.
Pengfei Chen Honggang Chang Tao Peng Yongfan Tang Youquan Liu Chao Xiang 《应用聚合物科学杂志》2021,138(30):50314
Hydraulic fracturing with slickwater is a field-proven stimulation technology used in tight reservoirs. Because of the high pumping rate associated with slickwater fracturing, drag reduction (DR) is critical in minimizing pressure drop and the success of oilfield operations. In this paper, a new type of drag reducer (SPR) was synthesized with acrylamide and 12-allyloxydodecyl acid sodium, and its drag reduction performance was evaluated. The results showed that the new drag reducer features low molecular weight, fast-dissolving rate and low interfacial tension. The algorithm of estimating the drag reduction rate of non-Newtonian fluid SPR was proposed and validated. Empirical or semianalytical models for estimating the friction ratio (σ) or friction factor (λ or f) were used to simulate the turbulence behavior of the SPR drag reducer under different Reynolds numbers (Re). The modified Virk's correlation could accurately model the turbulent behavior of the SPR drag reducer. A unified calculation formula was established in this study for different pipe diameters. 相似文献
9.
Qian Wu Xiangmei Liu Bo Li Lei Tan Yong Han Zhaoyang Li Yanqin Liang Zhenduo Cui Shengli Zhu Shuilin Wu Yufeng Zheng 《材料科学技术学报》2021,67(8):70-79
Pathogens pose a serious challenge to environmental sanitation and a threat to public health.The frequent use of chemicals for sterilization in recent years has not only caused secondary damage to the environment but also increased pathogen resistance to drugs,which further threatens public health.To address this issue,the use of non-chemical antibacterial means has become a new trend for environmental disinfection.In this study,we developed red phosphorus nanoparticles(RPNPs),a safe and degradable photosensitive material with good photocatalytic and photothermal properties.The red phosphorus nanoparticles were prepared using a template method and ultrasonication.Under the irradiation of simulated sunlight for 20 min,the RPNPs exhibited an efficiency of 99.98%in killing Staphylococcus aureus due to their excellent photocatalytic and photothermal abilities.Transmission electron microscopy and ultraviolet–visible spectroscopy revealed that the RPNPs exhibited degradability within eight weeks.Both the RPNPs and their degradation products were nontoxic to fibroblast cells.Therefore,such RPNPs are expected to be used as a new type of low-cost,efficient,degradable,biocompatible,and eco-friendly photosensitive material for environmental disinfection. 相似文献
10.
Chunsheng Wang Yishuang Wang Mingqiang Chen Defang Liang Zhonglian Yang Wen Cheng Zhiyuan Tang Jun Wang Han Zhang 《International Journal of Hydrogen Energy》2021,46(7):5852-5874
Given the continuing issues of environment and energy, methane dry reforming for syngas production have sparked interest among researchers, but struggled with the process immaturity owing to catalyst deactivation. This review summarizes the recent advances in the development of efficient and stable catalysts with strong resistance to coking and metal sintering, including the application of novel materials, the assessment of advanced characterizations and the compatibility to improved reaction system. One feasible option is the crystalline oxide catalysts (perovskite, pyrochlore, spinel and LDHs), which feature a fine metal dispersion and surface confinement effect via a metal exsolution strategy and exhibit superior reactivity and stability. Some new materials (h-BN, clays and MOFs) also extend the option because of their unique morphology and microstructure. It also is elaborated that progresses were achieved in advanced characterizations application, leading to success in the establishment of reaction mechanisms and attributions to the formed robust catalysts. In addition, the perspective described the upgrade of reaction system to a higher reaction efficiency and milder reaction conditions. The combination of efficient reaction systems and robust catalysts paves a way for a scaling-up application of the process. 相似文献