Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

Applications and Technologies of All-Solid State Blue Laser

1 Introduction Along with the matureness of laser diode (LD) manufacturing technology, the performance of LD has been improved greatly since 1980s, so various kinds of laser devices based on LD have been developed rapidly, especially the all-solid state lasers. After early experiments and researches, the all-solid state lasers have been commercialized successfully.     

超低密度硬胶极压型油包水乳化钻井液在广安002-H9井的应用

在超低密度钻井液的使用方面，传统的油基钻井液和油包水钻井液存在易着火、安全性差的问题，而最近使用的美国3M公司的中空玻璃微珠聚磺钻井液又存在固控困难、钻井液费用很高等难题。为此，从选择合适的润湿反转剂和阻燃剂入手，在室内对获得的超低密度硬胶极压型油包水乳化钻井液成果配方进行了全面评价，并应用在广安002 H9井水平段欠平衡钻井中取得了良好效果。室内研究与现场应用表明，超低密度硬胶极压型油包水乳化钻井液能够很好地满足广安构造水平井段欠平衡钻井的需要。该钻井液体系具有防塌、润滑、携砂能力强，密度容易控制，钻井液单位成本合理并可重复使用，安全性好等显著特点，适合在类似广安构造的水平井段中推广应用。     

在役超高压水晶釜主要检测方法

介绍了在役超高压水晶釜的常见缺陷以及应用超声波探伤、磁粉探伤、金相分析等无损检测方法对其进行在役检验的要点.     

A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

憎水性栀子蓝色素制备的研究

以浓盐酸为催化剂,采用乙酸酐酯化处理水溶性栀子蓝色素,制备了憎水性栀子蓝色素.探讨了栀子蓝色素与乙酸酐料液比、反应时间和反应温度等因素对憎水性栀子蓝色素色价的影响.结果表明:采用料液比1:20,在常温下反应4 h,为制备憎水性栀子蓝色素的最优条件.同时,通过红外光谱、可见吸收光谱及溶解性对栀子蓝色素的酯化改性进行了初步的探讨.     

Tri-Gate Bulk MOSFET Design for CMOS Scaling to the End of the Roadmap

A tri-gate bulk MOSFET design utilizing a low-aspect-ratio channel is proposed to provide an evolutionary pathway for CMOS scaling to the end of the roadmap. 3-D device simulations indicate that this design offers the advantages of a multi-gate FET (reduced variability in performance and improved scalability) together with the advantages of a conventional planar MOSFET (low substrate cost and capability for dynamic threshold-voltage control).