Applications and Technologies of All-Solid State Blue Laser

1 Introduction Along with the matureness of laser diode (LD) manufacturing technology, the performance of LD has been improved greatly since 1980s, so various kinds of laser devices based on LD have been developed rapidly, especially the all-solid state lasers. After early experiments and researches, the all-solid state lasers have been commercialized successfully.     

High-performance MIM capacitor using ALD high-k HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectrics

For the first time, we successfully fabricated and demonstrated high performance metal-insulator-metal (MIM) capacitors with HfO/sub 2/-Al/sub 2/O/sub 3/ laminate dielectric using atomic layer deposition (ALD) technique. Our data indicates that the laminate MIM capacitor can provide high capacitance density of 12.8 fF//spl mu/m/sup 2/ from 10 kHz up to 20 GHz, very low leakage current of 3.2 /spl times/ 10/sup -8/ A/cm/sup 2/ at 3.3 V, small linear voltage coefficient of capacitance of 240 ppm/V together with quadratic one of 1830 ppm/V/sup 2/, temperature coefficient of capacitance of 182 ppm//spl deg/C, and high breakdown field of /spl sim/6 MV/cm as well as promising reliability. As a result, the HfO/sub 2/-Al/sub 2/O/sub 3/ laminate is a very promising candidate for next generation MIM capacitor for radio frequency and mixed signal integrated circuit applications.     

Quantitative analysis of ephedrines in urine by HPLC

Simultaneous determination of six ephedrines in urine sample has been achieved by high performance liquid chromatography on a Lichrospher RP-18 column, using methylamphetamine as internal standard. The 6 ephedrines are well separated in 25 minutes with resolution better than 1.8. This method has high recovery, selectivity and reproducibility, and the linearity is satisfactory from 1.5 micrograms/ml to 25 micrograms/ml with correlation coefficients better than 0.999.     

具有阻力特性材料的σ_f－σ关系及一种新的阻力曲线测定方法

通过对相变增韧陶瓷及一种可切削玻璃－陶瓷动态疲劳（恒应力速率）试验中高应力速率区断裂应力下降现象的理论分析，发现这种现象与材料的阻力特性（Ｒ－ｃｕｒｖｅ）密切相关。确立的σ_ｆ－σ理论关系能够很好地描述整个应力速率区间内的动态疲劳试验结果。高应力速率区σ_ｆ－σ在双对数坐标下为负斜率直线，直线斜率为（ｍ为阻力曲线ＫＲ＝ｋ（△ａ）~ｍ的指数），断裂主要由材料阻力行为控制；低应力速率区，σ_ｆ－σ在双对数坐标下为正斜率直线，直线斜率为　（ｎ为应力腐蚀指数），断裂主要由材料应力腐蚀行为控制。建立了测定材料阻力特性的一种新方法，分别用这种方法及压痕／弯曲方法对一种可切削玻璃－陶瓷的阻力特性进行了实验测定，两种方法所得结果有很好的一致性。     

HNO3和有机介质中U（Ⅳ）的稳定性研究

研究了ＨＮＯ＿３和ＴＢＰ－煤油介质中Ｕ（Ⅳ）的稳定性。测定了两种介质中Ｕ（Ⅳ）、ＨＮＯ＿３、ＴＢＰ浓度和气相中氧浓度对Ｕ（Ⅳ）氧化速率的影响。Ｕ（Ⅳ）的氧化速率都随温度提高而明显增加．其表观活化能分别为９１ｋＪ／ｍｏｌ（ＨＮＯ＿３介质）和４２ｋＪ／ｍｏｌ（ＴＢＰ－煤油介质）。对两种介质中Ｕ（Ⅳ）的氧化速率规律进行了比较。     

Kinetics of two-step anionic polymerization

This article deals with the kinetics of two-step anionic polymerization by way of a non-steady state method. Several molecular parameters can be evaluated using the formulae developed. A bimodal molecular weight distribution function for the resulting polymer is derived from the set of kinetic differential equations, which is in agreement with the experimental data reported.     

Trace elements in particles of motor vehicle exhaust in Shanghai

A nuclear microprobe with high spatial resolution and high analytical sensitivity was applied to analyze trace elements,especially lead,in vehicle exhaust of Shanghai city.The result shows that the chemical composition and its corresponding x-ray relative intensity are different among different vehicle exhausts.There are many kinds of metal elements in particles of vehicle exhaust.most are harmful to people,such as Ti,Cr,Mn,Pb,etc.We found that the lead concentration was 6820μg/g and the bromine concentration was 5300μg/g in the exhaust from Santana using leaded gasoline(SULG).which is higher than any other kinds of vehicle exhausts.We have also detected the minimum lead in the particles of unleaded gasoline and its content varies from one to another.Its mean concentration was 450μg/g and the highest reached 6210μg/g.The unleaded gasoline‘s Pb existed in the whole particle while the leaded gasoline‘s enriched in the surface of the particle and was more harmful to the human beings.     

A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry