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排序方式: 共有126条查询结果,搜索用时 15 毫秒
1.
STUDY OBJECTIVE: To assess the efficacy of laser laparoscopic photocoagulation of endometriomas (2-18 cm) in patients with pain, infertility, or a combination of the two. DESIGN: Retrospective review of all patients with endometriomas from June 1, 1983, to December 31, 1993. SETTING: Department of gynecology and obstetrics at a district general hospital and national training center in minimal access surgery. PATIENTS: One hundred sixty-five women with large endometriomas present at the time of laser laparoscopy. INTERVENTIONS: Carbon dioxide laser or potassium-titanyl-phosphate laser laparoscopic surgery. MEASUREMENTS AND MAIN RESULTS: Ninety (74%) of 122 patients reported improvement or resolution of pain; and 30 of 66 achieved a pregnancy, for a cumulative conception rate of 45%. CONCLUSION: Laser laparoscopy is a practical, safe, and effective technique for the management of large ovarian endometriomas. 相似文献
2.
Hitoshi Kurokawa Taku Nakayama Yasunori Kobayashi Ken Suzuki Mutsumi Takahashi Seiichi Takami Momoji Kubo Naotsugu Itoh Parasuraman Selvam Akira Miyamoto 《Catalysis Today》2003,82(1-4):233-240
A modified Monte Carlo (MC) simulation was performed to investigate the hydrogen absorption behavior in Pd and Pd–Ag alloys of the composition PdxAg1−x (x=0.7–0.8) under H2 pressure (0.1 MPa) at different temperatures. The present method employed can consider the dissociative adsorption of hydrogen molecule and the subsequent absorption of hydrogen atom by formalizing the relationship between the pressure of hydrogen molecule and hydrogen atom. The potential parameters were determined to reproduce the solution enthalpy of hydrogen in pure metals. The results are in good agreement with experimental findings as well as previous theoretical studies. We confirmed that our method is useful to simulate the absorption of hydrogen in metals and alloys. 相似文献
3.
Isomorphously substituted cobalt(II) hexagonal mesoporous aluminophosphate (CoHMA) molecular sieves were synthesized hydrothermally and characterized by various analytical and spectroscopic techniques. It was deduced that cobalt ions exhibit a divalent oxidation state in tetrahedral coordination in mesoporous aluminophosphates. Further, unlike cobalt-containing microporous aluminophosphate molecular sieves, Co(II) ions remain in a tetrahedral geometry even after calcination. The catalytic activity of CoHMA was tested for the cyclohexane oxidation reaction under mild conditions. Remarkable substrate conversion and product (cyclohexanol) selectivity were obtained compared to several previously reported heterogeneous catalysts. 相似文献
4.
5.
E. Subramanian G. Anitha M. Karthik Selvam M. Ibrahim Ali Badusha 《Bulletin of Materials Science》2005,28(1):55-61
An investigation on the effect ofβ-cyclodextrin (CD) in both free and inclusion-complexed forms with a guest anionic metal complex, dioxalatodiaquochromate(III)
(DDC), on the characteristics of conducting polyaniline (PANI) is carried out. Four materials, PANI (i.e. PANI-SO
4
2−
), PANI-DDC, PANI-CD and PANI-CD + DDC were prepared byin situ
chemical oxidative polymerization in aqueous H
2SO4 at pH 1 and subjected to electrical conductivity and spectral (IR and UV-vis bd measurements. DDC and CD when separately incorporated, reduce the conductivity of PANI by about half whilst their inclusion
complex CD + DDC enhances it. Spectral characterization reveals that DDC as a dopant and CD as an encapsule exhibit their
effects through adverse interaction with imine-amine N centres and benzenoid moiety of PANI. The inclusion complex CD + DDC,
on the contrary, functions as a dopant by lying in between the chains and seems to promote the extended conformation of PANI
chain and hence theπ
-electron delocalization. Exposure of the material to methanol vapour causes a decrease in conductivity in PANI and PANI-CD while an increase in PANI-CD
+ DDC. This study makes explicit the distinct role of CD as an encapsule and CD + DDC inclusion complex as a dopant in altering
the electrical property of PANI. 相似文献
6.
K. N. Srinivasan M. Selvam S. Venkata Krishna Iyer 《Journal of Applied Electrochemistry》1993,23(4):358-363
Electrodeposition of metals from solution is usually accompanied by the simultaneous discharge of hydrogen ions or water molecules. When hydrogen is liberated at an iron/steel surface during electrodeposition, a portion of the hydrogen is absorbed by the metal surface and then diffuses into the interior. The diffused hydrogen produces some detrimental effects, such as reduction in ductility and loss in mechanical strength, leading to hydrogen embrittlement. The present paper reports investigations on hydrogen permeation measurements in zinc-manganese alloy deposition using a modified electrode clamp for easy removal and fixing of the electrode. Hydrogen permeation studies indicate that the porosity of the deposit increases in the following order:Zn-Mn(14.3%), Zn-Mn(2.4%), Zn-Mn(24.8%) and Zn-Mn(37.5%).This is in agreement with the corrosion data obtained which indicates that Zn-Mn alloy deposits with low manganese content show better performance than pure zinc deposits. 相似文献
7.
Zeolitic materials with hierarchical porous structures 总被引:2,自引:0,他引:2
Lopez-Orozco S Inayat A Schwab A Selvam T Schwieger W 《Advanced materials (Deerfield Beach, Fla.)》2011,23(22-23):2602-2615
During the past several years, different kinds of hierarchical structured zeolitic materials have been synthesized due to their highly attractive properties, such as superior mass/heat transfer characteristics, lower restriction of the diffusion of reactants in the mesopores, and low pressure drop. Our contribution provides general information regarding types and preparation methods of hierarchical zeolitic materials and their relative advantages and disadvantages. Thereafter, recent advances in the preparation and characterization of hierarchical zeolitic structures within the crystallites by post-synthetic treatment methods, such as dealumination or desilication; and structured devices by in situ and ex situ zeolite coatings on open-cellular ceramic foams as (non-reactive as well as reactive) supports are highlighted. Specific advantages of using hierarchical zeolitic catalysts/structures in selected catalytic reactions, such as benzene to phenol (BTOP) and methanol to olefins (MTO) are presented. 相似文献
8.
Damodaran Selvam Paranche Srinivasan Vishvaksenan Kuttathati Rajakani Kalidoss 《The Journal of supercomputing》2019,75(12):7979-7993
The Journal of Supercomputing - By combining massive multiple-input and multiple-output (Ma-MIMO) and small-cell approaches, it is possible to improve the capacity of the network, with the features... 相似文献
9.
10.
Influence of chain length of diol on the swelling behavior of citric acid based pH sensitive polymeric hydrogels: A green approach 下载免费PDF全文
Synthesis of pH‐sensitive hydrogels of citric acid with varying diol units viz., 1,2 Ethane diol, 1,4 butane diol, and 1,6 hexane diol along with methacrylic acid towards the solventless green approach. The formations of the hydrogels were identified using FTIR spectroscopy. Thermal characterization (thermo gravimetric analysis, differential thermal analysis (DTA), and differential scanning calorimetry) and morphology of the synthesized hydrogels have been investigated. Swelling studies of hydrogels in various pH ranging from 4.0 to 10.0 have been investigated. The results of the swelling studies implied that percentage of swelling comparatively higher at neutral pH (7.4) than at acidic and alkaline pH. The inverse relationship was noticed, where ascending the diol units of hydrogel in swelling equilibrium. The hydrogels with the increasing chain length show a noticeable pH sensitivity and which could be considered as smart hydrogel. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41403. 相似文献