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排序方式: 共有5665条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(16):23341-23347
In recent years, the rapid development of Li(NixCoyMn1-x-y)O2 (LNCM) materials for application in ternary lithium-ion batteries has led to an increased demand for refractory kiln saggars in industries. However, saggars used for firing ternary Li-ion battery cathode materials are often subjected to severe corrosion and spalling. To investigate the damage mechanism of the saggar materials, non-contact corrosion experiments were designed to study the effects of the precursor additions, calcination temperature, and number of calcinations during the interaction between mullite saggar and LNCM materials. The phase composition and microstructure of the mullite saggar specimens before and after corrosion were characterized using X-ray diffraction and scanning electron microscopy, respectively, to obtain a comprehensive understanding of the causes of the deterioration of mullite saggar materials during corrosion. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(64):27680-27689
The low performance of open-cathode proton-exchange-membrane fuel cells (OCPEMFCs) is attributed to the low-humidity ambient air supplied to the cathode using electric fans. To improve the OCPEMFC performance, this paper proposes a novel humidification method by collecting water purged from the anode and supplying it to the open cathode. The OCPEMFC performance is evaluated at various humidifier distances from the cathode inlet, and it is compared with that where no humidifier is used when the OCPEMFC operates under three different current levels of 1, 5, and 8 A. The results show that the novel design improves the stack power, and optimal performance is achieved at a humidifier distance of 2 cm. The energy efficiency achieves an improvement between 1.4% and 1.8% when a humidifier is used. 相似文献
3.
Bing Huang Meng Wang Guodong Xu Lin Hu Lin Chen Yijie Gu 《Ceramics International》2021,47(6):7700-7710
In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li+ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material. 相似文献
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Ph. D. Candidate:Chen Xue-fengState Key Laboratory of Offshore Coastal Engineering Dalian University of Technology Dalian China e-mail: cxfeng @ student dlut. edu.cn 《水动力学研究与进展(B辑)》2003,15(6)
The reflection coefficient of perforated caissons and the total horizontal forces acting on them were experimentally and numerically analyzed and discussed when wave propagates normally. To consider the viscosity effect of fluid and nonlinear action of waves on structures, the VOF (Volume Of Fluid) method combined with the k-ε turbulence model was used to simulate the interaction between waves and structures. Governing equations were solved with the finite difference method. Through 2D experimental study in the wave flume, the empirical relationship between the reflection coefficient of perforated caissons and the main affecting factors were obtained from the experimental data using the least square method. Also the correlation between the ratio of the total horizontal force acting on perforated caisson and the force acting on solid caisson and the main affecting factors were regressed from the experimental data. 相似文献
6.
荧光显示管直丝氧化物阴极有效逸出功的计算 总被引:1,自引:1,他引:0
阴极的逸出功是表征阴极发射能力的物理量,求定荧光显示管直丝氧化物阴极有效逸出功时,因其零场发射电流密度难于准确取值,温度无法直接测量,显得困难,须予解决,为此提出了一种计算阴极有产逸出功的办法,对某显示管的发射欠佳和“低温高效”的两种氧化物阴极的有效逸出功进行计算,有效逸出功率是靠测量相关物理量再同计算得出,精度不很高,文中所用办法也不例外,但所得结果能反映阴极发射能力,所需仪器少,是实用方法。 相似文献
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河口水流、波浪、潮流、泥沙、河床变形二维数学模型 总被引:19,自引:0,他引:19
根据河口“波浪掀沙,潮流输沙”的泥沙运动机制,引入“波浪幅射应力”反应波浪对水体和泥沙的驱动力.考虑波浪对底部泥沙作用力、波浪对水流挟沙能力的影响及风场对水流和泥沙运动的影响.同时考虑泥沙粒径大小、水体含盐度、含沙量及水流紊动程度等因素对絮凝沉速的影响.用ADI算法求解沿水深平均方程,破开算子法解悬移质不平衡输沙方程及河床变形方程,引入通度概念处理岸滩不规则边界,建立河口水流、波浪、潮流、泥沙、河床变形二维数学模型.通过实测资料及卫星摇感图像对所建数学模型进行检验,表明它可以较好地预测河口泥沙的运动 相似文献
10.
LiNi0.5Mn1.5O4 powder was synthesized via sol-gel method and coated with ZnO in order to test the electrochemical cyclability of the material as a cathode for the secondary Li battery in the 5 V range at 55 °C. The ZnO-coated LiNi0.5Mn1.5O4 powder nearly maintained its initial capacity of 137 mA h g−1 after 50 cycles whereas the uncoated powder was able to retain no more than 10% of the initial capacity after 30 cycles. TEM analysis of the cycled cathodes suggests that the formation of the graphitic surface phase, hindering the Li migration, may be responsible for the rapid capacity loss of the uncoated material while no such phase was observed on the surface of the ZnO coated LiNi0.5Mn1.5O4 powder. 相似文献