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排序方式: 共有6659条查询结果,搜索用时 17 毫秒
1.
《Ceramics International》2022,48(16):23341-23347
In recent years, the rapid development of Li(NixCoyMn1-x-y)O2 (LNCM) materials for application in ternary lithium-ion batteries has led to an increased demand for refractory kiln saggars in industries. However, saggars used for firing ternary Li-ion battery cathode materials are often subjected to severe corrosion and spalling. To investigate the damage mechanism of the saggar materials, non-contact corrosion experiments were designed to study the effects of the precursor additions, calcination temperature, and number of calcinations during the interaction between mullite saggar and LNCM materials. The phase composition and microstructure of the mullite saggar specimens before and after corrosion were characterized using X-ray diffraction and scanning electron microscopy, respectively, to obtain a comprehensive understanding of the causes of the deterioration of mullite saggar materials during corrosion. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(64):27680-27689
The low performance of open-cathode proton-exchange-membrane fuel cells (OCPEMFCs) is attributed to the low-humidity ambient air supplied to the cathode using electric fans. To improve the OCPEMFC performance, this paper proposes a novel humidification method by collecting water purged from the anode and supplying it to the open cathode. The OCPEMFC performance is evaluated at various humidifier distances from the cathode inlet, and it is compared with that where no humidifier is used when the OCPEMFC operates under three different current levels of 1, 5, and 8 A. The results show that the novel design improves the stack power, and optimal performance is achieved at a humidifier distance of 2 cm. The energy efficiency achieves an improvement between 1.4% and 1.8% when a humidifier is used. 相似文献
3.
Bing Huang Meng Wang Guodong Xu Lin Hu Lin Chen Yijie Gu 《Ceramics International》2021,47(6):7700-7710
In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li+ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material. 相似文献
4.
AbstractBa0.95Ca0.05Ti1-xZrxO3 (BCTZO) ceramics were prepared by a solid state reaction method. The samples were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and X-ray absorption near edge structure (XANES). The ceramics exhibit a pure perovskite structure. The average grain size gradually decreases with increasing Zr concentration. XANES results indicate that the intensities of pre-edge peaks dropped with increasing Zr concentration. The BCTZO ceramic of x?=?0.05 has the optimum electrical properties with the maximum dielectric constant (ε'm), remanent polarization (2Pr), coercive electric field (2Ec) and piezoelectric charge constant (d33) of 7,244, 12.54 (μC/cm2), 5.29 (kV/cm) and 288 (pC/N), respectively. 相似文献
5.
《Ceramics International》2022,48(13):18278-18285
We report the improved energy storage density and efficiency after 2.5% of Samarium substitution in ferroelectric Pb[(Mg1/3Nb2/3)0.80Ti0.20]O3 (PMNT) electroceramic. The microstructure and surface morphology were analyzed and correlated with various functional properties. The energy storage density, leakage current density, ferroelectric and dielectric properties were investigated thoroughly, indicating that Samarium's substitution significantly modified the microstructure, the dielectric strength, breakdown electric field, and turned ferroelectric PMNT to relaxor ferroelectrics. Due to the relaxor nature, the gap between remanent polarization and maximum polarization increases with the substitution of Samarium in PMNT matrix, which further increases the recoverable energy storage density and energy efficiency. A nearly 100% increase in recoverable energy density and efficiency was obtained at an electric field strength of 35 kV/cm at room temperature (~296 K). The electroceramic shows maximum energy density near the ferroelectric phase transition temperature (325 K–345 K) region and provides a moderate energy storage density for possible applications in power microelectronics. 相似文献
6.
Yang Yang Yibei Zhou Juan Ren Qiaoji Zheng Kwok Ho Lam Dunmin Lin 《Journal of the European Ceramic Society》2018,38(2):557-566
Perovskite ferroelectrics possess the fascinating piezoelectric properties near a morphotropic phase boundary, attributing to a low energy barrier that the results in structural instability and easy polarization rotation. In this work, a new lead-free system of (1-x)BaTiO3-xCaHfO3 was designed, and characterized by a coexistence of ferroelectric rhombohedral-orthorhombic-tetragonal (R-O-T) phases. With the increase amount of CaHfO3 (x), a stable coexistence region of three ferroelectric phases (R-O-T) exists at 0.06 ≤ x ≤ 0.08. Both large piezoelectric coefficient (d33~400 pC/N), inverse piezoelectric coefficient (d33*~547 pm/V) and planar electromechanical coupling factor (kp~58.2%) can be achieved for the composition with x = 0.08 near the coexistence of three ferroelectric phases. Our results show that the materials with the composition located at a region where the three ferroelectric R-O-T phases coexist would have the lowest energy barrier and thus greatly promote the polarization rotation, resulting in a strong piezoelectric response. 相似文献
7.
8.
铁电存储器的研究进展 总被引:1,自引:1,他引:0
介绍了铁电存储器的存储原理,同时对两种铁电存储器(铁电随机存取存储器和铁电场效应晶体管存储器)的研究进展、当前存在的问题以及我国目前在这一领域的研究现状进行了简单介绍,并对今后的技术发展进行了展望。 相似文献
9.
荧光显示管直丝氧化物阴极有效逸出功的计算 总被引:1,自引:1,他引:0
阴极的逸出功是表征阴极发射能力的物理量,求定荧光显示管直丝氧化物阴极有效逸出功时,因其零场发射电流密度难于准确取值,温度无法直接测量,显得困难,须予解决,为此提出了一种计算阴极有产逸出功的办法,对某显示管的发射欠佳和“低温高效”的两种氧化物阴极的有效逸出功进行计算,有效逸出功率是靠测量相关物理量再同计算得出,精度不很高,文中所用办法也不例外,但所得结果能反映阴极发射能力,所需仪器少,是实用方法。 相似文献
10.