全文获取类型
收费全文 | 21322篇 |
免费 | 2088篇 |
国内免费 | 971篇 |
专业分类
电工技术 | 768篇 |
综合类 | 2759篇 |
化学工业 | 2426篇 |
金属工艺 | 2065篇 |
机械仪表 | 403篇 |
建筑科学 | 6281篇 |
矿业工程 | 877篇 |
能源动力 | 281篇 |
轻工业 | 336篇 |
水利工程 | 1042篇 |
石油天然气 | 346篇 |
武器工业 | 143篇 |
无线电 | 513篇 |
一般工业技术 | 2601篇 |
冶金工业 | 3199篇 |
原子能技术 | 86篇 |
自动化技术 | 255篇 |
出版年
2024年 | 68篇 |
2023年 | 256篇 |
2022年 | 453篇 |
2021年 | 520篇 |
2020年 | 584篇 |
2019年 | 474篇 |
2018年 | 493篇 |
2017年 | 584篇 |
2016年 | 605篇 |
2015年 | 662篇 |
2014年 | 1076篇 |
2013年 | 936篇 |
2012年 | 1324篇 |
2011年 | 1539篇 |
2010年 | 1266篇 |
2009年 | 1247篇 |
2008年 | 1235篇 |
2007年 | 1447篇 |
2006年 | 1470篇 |
2005年 | 1228篇 |
2004年 | 1053篇 |
2003年 | 1020篇 |
2002年 | 828篇 |
2001年 | 734篇 |
2000年 | 623篇 |
1999年 | 513篇 |
1998年 | 404篇 |
1997年 | 317篇 |
1996年 | 296篇 |
1995年 | 264篇 |
1994年 | 196篇 |
1993年 | 151篇 |
1992年 | 143篇 |
1991年 | 95篇 |
1990年 | 74篇 |
1989年 | 57篇 |
1988年 | 29篇 |
1987年 | 39篇 |
1986年 | 15篇 |
1985年 | 9篇 |
1984年 | 8篇 |
1983年 | 12篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 12篇 |
1979年 | 5篇 |
1964年 | 3篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Effect of Stoichiometry on Properties of Rare-Earth-Based Hydrogen Storage Alloy for Nickel-Metal Hydride Secondary Battery 总被引:2,自引:0,他引:2
Effect of stoichiometry on microstructures, electrochemical properties and PCT characteristics of the alloys MI(Ni0.71Co0.15-Al0.06Mn0.08)x (MI=Lanthanum-rich Michmetal, x=4.6~5.2) have been investigated. The lattice constants a, c, and cellvolumes of non-stoichiometric alloys are bigger than those of the stoichiometric alloy. With the increasing stoichiometry x,the value of a decreases, and the value of c and cell volume increases except for those of the stoichiometric alloy; the plateaupressure of PCT curve, discharge capacity and cycling stability all increase. The alloy with x=5.2 shows the highest dischargecapacity and the best cycling stability among the studied alloys. 相似文献
2.
从测得的竞聚率计算了单体链节在聚[苯乙烯-甲基丙烯酸β(甲基亚硫酰基)乙酯](PSM)中的序列分布。苯乙烯(S)或甲基丙烯酸β(甲基亚硫酰基)乙酯(M)的长序列的概率随着PSM中相应单体含量的增加而增加。对于S和M摩尔分数大致相等的PSM,单体链节的长序列分布函数值相接近。用与此结构相近的PSM合成的稀土金属络合物,其催化活性不佳。在M短序列分布和S长序列分布较高的情况下,络合物的催化活性最好。所得聚丁二烯的微观结构与PSM中单体单元的分布无关。 相似文献
3.
本文研究了HPMBP与伯胺N_(1923)的二甲苯溶液,从盐酸介质中协同萃取希土(Ⅲ)的机理。用斜率法、恒摩尔法确定了协萃配合物的组成为:RNH_3Ln(PMBP)_4。求得关于Pr(Ⅲ)协萃反应的平衡常数及协萃配合物的生成常数分别为:logK_(12)=-1.95;logβ_(12)=3.94。实验发现,协萃系数(R)随希土元素的原子序数(Z)递变而呈现“双峰效应”。还研究了协萃配合物的IR,NMR谱。 相似文献
4.
纤维混凝土在水工建筑工程中的应用(上) 总被引:1,自引:0,他引:1
概述改性混凝土垢发展情况,介绍纤维混凝土在国内外水工建筑物上的应用实例,提出钢纤维增强钢筋混凝土水工建筑结构强度计算方法。包括受弯构件正截面强度,斜截面抗剪强度的计算;重点介绍了网状钢纤维增强混凝土(FOC)在水工建筑物上的应用,包括在渡槽,闸门,小型拦河坝,轻型岸型等工程上的应用实例,T新梁正斜截面的强度计算,板材承载力计算的方法。 相似文献
5.
The results of a comprehensive experimental program, aimed at providing a fundamental understanding of the behavior of shear-critical exterior reinforced concrete (RC) joints strengthened with fiber reinforced polymers (FRP) under simulated seismic load, are presented in this study. The role of various parameters on the effectiveness of FRP is examined through 2/3-scale testing of 18 exterior RC joints. Conclusions are drawn on the basis of certain load versus imposed displacement response characteristics, comprising the strength (maximum lateral load), the stiffness, and the cumulative energy dissipation capacity. The results demonstrate the important role of mechanical anchorages in limiting premature debonding, and they provide important information on the role of various parameters, including: area fraction of FRP; distribution of FRP between the beam and the column; column axial load; internal joint (steel) reinforcement; initial damage; carbon versus glass fibers; sheets versus strips; and effect of transverse beams. 相似文献
6.
Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)3) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)3 exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 104 g mol?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)3 has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)3 is 69.6 kJ mol?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry 相似文献
7.
对称配筋小偏心受压构件的截面设计 总被引:4,自引:1,他引:3
对小偏心受压构件在对称配筋情况下的截面配筋计算,提出用最佳一次逼近多项式简化基本公式,直接按二次方程求解ξ的近似方法,具有精度高,相对误差小,计算方便等优点,可供工程设计人员参考。 相似文献
8.
The catalysts of CeO2 and the mixture of CeO2 and CuO were prepared, and the activities of these catalysts for completely oxidizing benzene were studied.The results show that the optimal proportion of CeO2/CuO is 6: 4.The highest temperature at which benzene was completely oxidized on these catalysts at different airspeed was measured.Compared these catalysts with the noble metal used, our catalysts had superiority in the resources and the industrial cost besides good activities. 相似文献
9.
10.
Peter H. Bischoff 《Canadian Metallurgical Quarterly》2007,11(1):4-14
Fundamental concepts of tension stiffening are used to explain why Branson’s equation for the effective moment of inertia Ie does not predict deflection well for fiber reinforced polymer (FRP) reinforced concrete beams. The tension stiffening component in Branson’s equation is shown to depend on the ratio of gross-to-cracked moment of inertia (Ig/Icr), and gives too much tension stiffening for beams with an Ig/Icr ratio greater than 3. FRP beams typically have an Ig/Icr ratio greater than 5, leading to a much stiffer response and underprediction of computed deflections as observed by others in the past. One common approach to computing deflection of FRP reinforced concrete beams has been to use a modified form of the Branson equation. This paper presents a rational development of appropriate modification factors needed to reduce the tension stiffening component in Branson’s original expression to realistic levels. Computed deflections using this approach give reasonable results with the right modification factor, and compare well with a more general unified approach that incorporates a realistic tension stiffening model. Comparison is made with the existing and past correction factors recommended by ACI 440 for predicting deflection of FRP beams. The method presently used by ACI 440 gives reasonable estimates of deflection for glass and carbon FRP reinforced beams. However, this method underestimates deflection of aramid FRP reinforced beams and is restricted to rectangular sections. A proposal is made for adoption of a simple modification factor that works well for all types of FRP bar and beam cross-sectional shape. 相似文献