Copper–4,4′-dipyridyl coordination compound as solid reagent for spectrophotometric determination of reducing sugar employing a multicommutation approach

In this work a multicommuted flow system employing copper–4,4′- dipyridyl coordination compound as the solid-phase reagent for the spectrophotometric determination of reducing sugar was developed. The coordination compound was synthesized through a reaction of the 4,4′-dipyridyl and copper (II) nitrate, under hydrothermal conditions. The complex was characterized by infrared spectroscopy (FTIR), power X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and thermogravimetric analysis (TGA). Based on the characterization, a multicommuted spectrophotometric procedure for the determination of reducing sugar using copper (II) complex as solid reagent is proposed. The proposed method was based on the redox reaction between a monosaccharide, such as fructose and glucose (reducing sugar) and Cu(II). This reaction, mediated in an alkaline medium, produces a yellow compound that can be determined by absorption electronic spectroscopy (λ_ABS = 420 nm). Under optimum experimental conditions, a linear response ranging from 1.0 to 20.0 g L⁻¹ (R = 0.9978 and n = 5), a detection (3σ criterion) and quantification (10σ criterion) limit estimated at 0.23 and 0.75 g L⁻¹, respectively, a standard deviation relative of 4.7% (n = 7), for a reference solution of 10.0 g L⁻¹ reducing sugar, and a sampling rate of 75 determinations per hour were achieved. The proposed system was applied to the determination of reducing sugars in coconut water and juices. The analysis of ten samples and the application of the t-test to the results found, and those obtained using reference procedures (AOAC), provided no significant differences at a 95% confidence level. This system enabled the analysis of reducing sugar with ease and simplicity, providing a significant economy of the solid reagent (600 μg per determination) and reducing effluent generation.     

软β核素内部样品塑料闪烁探测器

本文评价了塑料闪烁片用作软β核素探测器时的计数效率、β谱、本底谱和康普顿电子谱的特征。文中强调:采用胶合光导剂构成的系统是一种新型探测器(软β核素内部样品塑料闪烁探测器)。本文提出内部样品固体探测器、胶合光导剂和胶合闪烁光导剂的新概念。     

甘三酯立体专一分析的研究：（Ⅱ）甘三酯立体专一分析方法初探

在第一部分综合讨论的基础上对甘三酯立体专一分析方法作了初步探讨。以液体油(菜油)及固体脂(猪脂)为基质,系统地研究了这一分析方法,取得了经验并补充了一些具体验证方法。分析液体油的结果与文献数据相一致,分析猪脂的结果欠佳,还存在一些问题需待进一步研究。     

二烷基硫代磷酸铵的捕收性能

本文研究了二烷基硫代磷酸铵（ＲＯ）２ＰＳＯＮＨ４（Ｒ＝乙基、丁基、己基、烯丙烯）系列捕收剂对非硫化矿孔雀石、锡石、赤铁矿、白铅矿、方解石和菱锌矿的浮选性能，并就药剂结构与性能关系进行了分析讨论．     

10000m^3天然气球罐用WEL—TEN610CF钢焊接冷裂纹敏感性

WEL-TEN610CF钢是日本新日铁公司生产的低裂纹敏感性高强钢,结合我国首台国产化10 000 m3天然气球罐用37 mm厚WEL-TEN610CF钢焊接性试验研究,对该钢焊接冷裂纹敏感性进行了综合评定,为其焊接工艺的制订提供了可靠的依据。     

新显色剂AAATAR在光度分析测定微量钯中的应用

介绍了４种对钯有高灵敏和选择性的安替比林偶氮胂酸类试剂。试剂在较高酸度介质中能与钯形成稳定的２：１红色络合物。表观摩尔吸光系数为３．５～５．１×１０４。用ＡＡＡＴＡＲ测定镍铜合金中的钯，结果满意。     

Comparison of six methylation methods for analysis of the fatty acid composition of albacore lipid

Six methods widely used to produce methyl esters for the gas chromatographic determination of the fatty acid composition of a marine lipid were compared. Four acid-catalyzed methods (1% H₂SO₄: CH₃OH; 5% HCl: CH₃OH; 7% and 14% BF₃: CH₃OH) and two base-catalyzed methods [0.5M NaOCH₃: CH₃OH; (1:4) tetramethylguanidine: CH₃OH] were used.
The use of BF₃: CH₃OH (7% and 14%) gave a lower content of 18:1 n9 than the other methods and produced an artefact (2.7–3.2% of total fatty acid content) eluting between the 20:5 and 24:1 fatty acid methyl esters. No significant differences were obtained between the other four methods.
Accordingly the use of BF₃: CH₃OH for transmethylation of marine lipids is not recommended. Results obtained in the other four methods showed that all are comparable.     

Synthesis and characterization of polyaniline films using Fenton reagent

The chemical oxidation of aniline to form polyaniline (PANI) films and powder samples was made using Fenton reagent as an oxidizing agent in aqueous sulfuric acid medium. The PANI films were monitored by using the quartz crystal microbalance and the electronic absorption techniques. The optimum concentration was determined and the results were justified by measuring the UV–vis absorption spectra for the in situ PANI films. The conductivity for the PANI films and powder samples, prepared in different conditions, was measured. Also, the IR spectra, X‐ray and the thermogravimetric analysis for the PANI powder formed in the bulk were measured and compared with the polymer prepared using ammonium peroxydisulfate. A preliminary investigation to the dielectric properties of the polymer powder was measured and discussed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

活性石灰/粉煤灰制备烧结烟气脱硫剂配比试验研究

本文研究了以钢铁企业常用物料活性石灰和自备电厂粉煤灰制备的脱硫剂,在循环流化床脱硫试验装置上进行了烧结烟气脱硫剂配比试验.试验结果表明,活性石灰与粉煤灰的质量比按1:2配置时,脱硫剂钙的利用率较高,具有较好的经济性.