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1.
We report the study of conductive polyaniline (PANI) chain embedded Ti-MOF functionalized with CoS as a cocatalyst for hydrogen evolution reaction (HER) application. The post synthetically modified hybrid photocatalyst PANI/Ti-MOF/CoS greatly influences the redox and e? ? h+ separation process and exhibits an impressive rate of HER (~1322 μmol h?1g?1), suppressing the pristine Ti-MOF (~62 μmol h?1g?1) with apparent quantum yield (AQY) of ~3.2 and transient current response of ~46.4 μA cm?2. In this system, Ti-MOF provides the circulation of Ti3+ and Ti4+ to the reaction of photocatalytic H2 generation, where the additional PANI and CoS amended the performance of H2 production through electron enrichment and thereby improving the stability and integrity of Ti-MOF. The Electrochemical studies demonstrated increased photocurrent by interweaving Ti-MOF crystal with PANI through cation-π interaction thereby enhancing interface connection and then promoting electron transfers. The charge dynamics revealed the initial charge transfer from photoexcited PANI to encapsulated MOF framework to boost the photocatalytic performance of the system. Further, the electron movement at the Ti-MOF/CoS interface is investigated through work function and electrochemical potential of electrons (Fermi level). DFT results demonstrate the importance of CoS in improving the photocatalytic performance of hybrid Ti-MOF catalyst, which leads to superior catalytic behaviour. These results establish that the encapsulation of catalytic active sites inside MOFs with desirable energy band gaps would be an ideal choice for the production of solar fuels.  相似文献   
2.
An alternative for reducing emissions from marine fuel is to blend bio-oil from lignocellulose non-edible feedstocks to diesel fossil fuels. Phase diagrams of the ternary systems were built to represent the transition from heterogeneous regions to homogeneous regions. Four homogeneous blends of bio-oil of eucalyptus-bioethanol-marine gasoil were experimentally characterized with respect to the most important fuel parameters for marine engines: water content, flash point, low heating value, viscosity, and acidity. Blends with closer properties to marine gasoil replacement, lower costs, and environmental impacts should be tested for large engines.  相似文献   
3.
The intermittent wind power in isolated hybrid distributed generation (IHDG) may cause serious problems associated with frequency (f) and power (P) fluctuation. Energy storage devices such as battery, super capacitor, and superconducting magnetic energy storage (SMES) may be used to reduce these fluctuations associated with f and P. This paper presents a study of IHDG power system for improving both f and P deviation profiles with the help of SMES. The studied IHDG power system is consisted of wind turbine generator and diesel engine generator. Both f and P control problems of the studied power system model are addressed in presence or absence of SMES. Fuzzy logic based proportional–integral–derivative (PID) controller with SMES is used for the purpose of minimization of f and P deviations. The different tunable parameters of the PID controller and those of the SMES are tuned by a novel quasi-oppositional harmony search algorithm. Performance study of the IHDG power system model is carried out under different perturbation conditions. The results demonstrate minimum f and P deviations may be achieved by using the proposed fuzzy logic based PID controller along with SMES.  相似文献   
4.
睡眠期间连续且准确的呼吸量监测有助于推断用户的睡眠阶段以及提供一些慢性疾病的线索。现有工作主要针对呼吸频率进行感知和监测,缺乏对呼吸量进行连续监测的手段。针对上述问题提出了一种基于商用无线射频识别(RFID)标签的无线感知用户睡眠期间呼吸量的系统——RF-SLEEP。RF-SLEEP通过阅读器连续收集附着在胸部表面的标签阵列返回的相位值及时间戳数据,计算出呼吸引起的胸部不同点的位移量,基于广义回归神经网络(GRNN)构建胸部不同点的位移量与呼吸量之间的关系模型,从而实现对用户睡眠期间呼吸量的评估。RF-SLEEP通过在用户肩膀处附着双参考标签,消除用户睡眠期间翻转身体对胸部位移计算造成的误差。实验结果表明,RFSLEEP对不同用户睡眠期间的呼吸量连续监测的平均精确度为92.49%。  相似文献   
5.
Very high resolution inverse synthetic aperture radar (ISAR) imaging of fast rotating targets is a complicated task. There may be insufficient pulses or may introduce migration through range cells (MTRC) during the coherent processing interval (CPI) when we use the conventional range Doppler (RD) ISAR technique. With compressed sensing (CS) technique, we can achieve the high-resolution ISAR imaging of a target with limited number of pulses. Sparse representation based method can achieve the super resolution ISAR imaging of a target with a short CPI, during which the target rotates only a small angle and the range migration of the scatterers is small. However, traditional CS-based ISAR imaging method generally faced with the problem of basis mismatch, which may degrade the ISAR image. To achieve the high resolution ISAR imaging of fast rotating targets, this paper proposed a pattern-coupled sparse Bayesian learning method for multiple measurement vectors, i.e. the PC-MSBL algorithm. A multi-channel pattern-coupled hierarchical Gaussian prior is proposed to model the pattern dependencies among neighboring range cells and correct the MTRC problem. The expectation-maximization (EM) algorithm is used to infer the maximum a posterior (MAP) estimate of the hyperparameters. Simulation results validate the effectiveness and superiority of the proposed algorithm.  相似文献   
6.
文章归纳了2020年电子电路产业一些技术热点,主要有5G电路板设计和基材,制造方面半加成法、3D打印、直接金属化孔电镀和垂直互连结构等技术,以及集成电路封装载板技术。  相似文献   
7.
赵鑫 《现代矿业》2019,35(9):92-94
山西某矿5308底抽巷在掘进过程中速度慢、效率低,直接影响工作面的瓦斯抽采,为了改善上述情形,对炮孔间距进行研究。通过使用ANSYS软件对不同炮孔间距下快速掘进效果的模拟分析,并经现场验证,得出了适应该矿的最佳炮孔间距。结果表明:炮孔间距为500 mm时,爆破产生裂隙发育范围和岩石损伤区域都最大,快速掘进的效果最好。  相似文献   
8.
Frequency band selection (FBS) in rotating machinery fault diagnosis aims to recognize frequency band location including a fault transient out of a full band spectrum, and thus fault diagnosis can suppress noise influence from other frequency components. Impulsiveness and cyclostationarity have been recently recognized as two distinctive signatures of a transient. Thus, many studies have focused on developing quantification metrics of the two signatures and using them as indicators to guide FBS. However, most previous studies almost ignore another aspect of FBS, i.e. health reference, which significantly affect FBS performance. To address this issue, this paper investigates importance of a health reference and recognize it as the third critical aspect in FBS. With help of the health reference, the frequency band where the fault transient exists could be located. A novel approach based on classification is proposed to integrate all three aspects (impulsiveness, cyclostationarity, and health reference) for FBS. Classification accuracy is developed as a novel indicator to select the most sensitive frequency band for rotating machinery fault diagnosis. The proposed method (coined by accugram) has been validated on benchmark and experiment datasets. Comparison results show its effectiveness and robustness over conventional envelope analysis, the kurtogram, and the infogram.  相似文献   
9.
In the harmonic active power measurement, the highest uncertainties are generally introduced by the current and voltage transducers. In a previous paper, the authors showed that the current transformer (CT) can introduce significant errors in such measurement, especially if the phase shift between voltage and current is close to ±90°. In such condition the errors on harmonic power measurement are mainly due to the CT phase displacement. This paper shows that better results can be achieved with more linear transducers, such as the Rogowski coil current transducers (RCCTs), whose metrological performance in distorted condition can be improved, by means of a proper compensation method. The proposed method for RCCTs compensation is based on the frequency response and it allows to reduce the errors on harmonic power measurement, also for phase shift close to ±90°. The study is supported by several experimental tests.  相似文献   
10.
Automatic load shedding is the ultimate countermeasure against imbalance in a power system and can effectively help preventing large blackouts. Taking into account a high penetration of renewable energy sources (RES) in the distribution grid, a clear distinction between load and generation at the PCC becomes increasingly more difficult. For that reason an adaptation of frequency relay parameters and their locations of installation are necessary. In Europe this is rest on a multi-step plan based on values such as the yearly peak load. In this paper a novel probabilistic method for automatic load shedding is presented that uses the average values instead of peak values for load shedding. Its applicability is verified by a dynamic power system model that was developed to compare the classical and novel probabilistic load shedding principle. The method is verified using data from a German TSO.  相似文献   
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