Efects of Washing and Drying on Crystal Structure and Pore Size Distribution（PSD） of Zn4O13C24H12 Framework（IRMOF-1）

In this study,the efects of various methods of washing and drying of MOF-5 nanocrystals on structure formation were investigated.Eight samples of MOF-5 were synthesized under diferent conditions.TGA,XRD and PSD analysis were applied to characterize of the samples.The methods of washing and drying were found to be important in determining the final structure of MOF-5s.MOF-5 with high BET surface area can be obtained by choosing a suitable method of washing and drying.According to the results obtained in this work,it was found that vacuum drying at 425℃ is sufcient to dissolve the MOF-5-DMF.Similar results were obtained by washing method(with℃H2Cl2and℃HCl3),when compared with vacuum drying at 425℃ according to XRD test.The pore size distribution of samples 1-5 and 8 were calculated by SHN1 method and results showed that the samples in which solvent vacuum was DMF,have lower pore volume,uniform pore size distribution and the pore size are smaller than samples 3,4 and 8.It was also found that activated MOF-5can be converted to its deactivated form prior to drying of the samples.     

Organic–inorganic interface enhancement for boosting mechanical and tribological performances of carbon fiber reinforced composites

The limitation in the poor interface would severely affect the further development and application of carbon fiber reinforced composites (CFRP). Unique organic–inorganic hybrid architectures of MOF-5-NH₂ and carboxymethyl cellulose (CMC) were established on the fiber/matrix interphase for promoting mechanical and tribological performances of the composites. The existence of above interfacial reinforced structure was in favor of generating abundant micromechanical interaction sites for enhancing mechanical interlocking. Meanwhile, high-density chemical crosslinking networks played a positive role in elevating interfacial adhesion, further relieving stress concentration and hindering crack propagation. The tensile strength of CFRP-2, CFRP-3, CFRP-4, and CFRP-5 exhibited a significant rising of 27.18%, 30.64%, 27.75%, and 36.88%, respectively. The friction coefficient of MOF-5-NH₂/CMC modified sample increased from 0.0953 to 0.1219, while the drop in the wear rate of the composites achieved 68.51%. This work provides an effective method for achieving the structure–function integrated design of composite materials according to the organic–inorganic interface enhancement of MOF-5-NH₂/CMC.     

数字电压电流表之硬件设计

采用ATMEGA8芯片和一些外设电路来完成数字电压电流表的设计,能够对输入的0~30 V电压及0~5 A电流进行测量,并通过一个四位一体的8段LED数码管进行轮流显示,测量精度应小于1%。使用Protel99 SE软件进行绘制电路原理图以及PCB图,并在proteus软件上进行仿真,经设计后的系统具有集成度高、灵活性强、易于开发、维护、扩展等特点。最后结合了软件进行调试,该系统达到设计的目的,高精度地显示了所测量的电压电流值。     

Updated estimates of HAL n and RN− effects on pork quality: Fresh and processed loin and ham

A 1000-pig F2 intercross QTL detection experimental population was generated using two commercial sire lines. Independent carriers of HAL n and RN− mutations (10% and 14%, respectively) were included in this population as control genotypes. The effects of HAL n and RN− heterozygous genotypes on fresh and transformed loins and hams were estimated using a mixed model methodology. The results document the unfavorable effects of both mutations on meat quality. Smaller effects of HAL Nn genotype compared to HAL nn or RN−rn+ genotypes were estimated. Interestingly, effects of HAL Nn genotype on meat pH and loin color could be insignificant at 24-h postmortem, but translate into higher water losses on storage and cooking, and result in tougher cooked loin. Using the same methodology, significant effects of the PRKAG3 (RN) I199 allele on ultimate pH values but not on glycolytic potential were observed.     

Heterofullerene C48B12-impregnated MOF-5 and IRMOF-10 for hydrogen storage: A combined DFT and GCMC simulations study

The H₂ storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C₄₈B₁₂ molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C₄₈B₁₂ molecules play a crucial role in improving the H₂ storage properties of IRMOFs. Among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C₄₈B₁₂ with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C₄₈B₁₂ always shows the best hydrogen storage properties among the pure and C₄₈B₁₂-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C₄₈B₁₂ has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C₄₈B₁₂ molecules, and steric hindrance effect of C₄₈B₁₂ molecules on IRMOFs mainly affects the H₂ uptake capacity by comparing the absolute H₂ molecules in individual IRMOFs units, C₄₈B₁₂ molecules, and IRMOFs-nC₄₈B₁₂ compounds. The absolute hydrogen adsorption profiles show that eight C₄₈B₁₂ molecules impregnating into MOF-5 can exert obvious steric effects for H₂ adsorption. The saturated gravimetric and volumetric H₂ densities of IRMOF-10-8C₄₈B₁₂ higher than those of MOF-5-8C₄₈B₁₂ due to with larger free volume.     

Tuning the hydrogen storage properties of MOF-650: A combined DFT and GCMC simulations study

Combined density functional theory and grand canonical monte Carlo (GCMC) calculations were performed to study the electronic structures and hydrogen adsorption properties of the Zn-based metal-organic framework MOF-650. The benzene azulenedicarboxylate linkers of MOF-650 were substituted by B atoms, N atoms, and boronic acid B(OH)₂ linkers, and the Zn atoms were substituted by Mg and Ca atoms. The calculated electronic densities of states (DOSs) of MOF-650 showed that introduction of B atoms reduces the band gap but damages the structure of MOF-650. Introduction of single N bonds cannot provide active electrons to attract H₂ molecules. Thus, substitutions of B and N into MOF-650 are not suggested. B(OH)₂ substitute in MOF-650 decreased its band gap, slightly improved its hydrogen storage ability and made H₂ molecules more intensively distributed besides organic linkers. GCMC calculations were carried out by estimating the H₂ storage amount of the pure and modified MOFs at 77 and 298 K and from 1 bar to 20 bar. B(OH)₂ linker and Mg/Ca co-doped MOF-650 showed increased H₂ adsorption by approximately 20 wt%. The adsorption of H₂ around different bonds showed the order N–C < C = C < B–C < C–O < B–O.     

Impact of RN genotype and ageing time on colour characteristics of the pork muscles longissimus dorsi and semimembranosus

The effect of RN genotype on pH decline, ultimate pH, pigment content, blooming and colour stability during 6 days of display at 5 °C was studied in two pig muscles, M. longissimus dorsi (LD) and M. semimembranosus (SM), and furthermore the effect of anaerobic storage time (2 days vs. 9 days of ageing) on the same parameters was examined. The postmortem pH decline was faster and the ultimate pH lower in LD and SM of the RN⁻ genotype compared with corresponding muscles from the rn⁺ genotype. Pork of the RN⁻ genotype was initially lighter and more red and yellow than pork of the rn⁺ genotype due to a higher degree of blooming, which might be explained by the faster pH decline and/or lower ultimate pH. The level of oxymyoglobin (MbO₂) was decisive for the redness of both muscles during display in air despite a higher presence of metmyoglobin (MetMb). Pork of the RN⁻ genotype was thus redder than that of the rn⁺ genotype throughout display in air despite higher oxidation to MetMb. Ageing for 9 days in chill improved the blooming potential in pork of both genotypes compared with 2 days of ageing, resulting in superior meat colour. However, only in pork from the RN⁻ genotype, the colour was not negatively affected by ageing time upon display in air.     

酸性染料橙RXL及酸性染料黄A-4R合成技术解析与应对

该文就酸性染料橙RXL及酸性染料黄A-4R合成工艺分步反应解析与应对作出介绍,并提示一些可供进一步研究完善的意向,以利该两产品达到高质、低耗、低成本和循环利用之目的。     

Protel99在逻辑电路中的应用

介绍了可编程逻辑器件(ＰＬＤ)应用和相应软件的发展及利用ＥＤＡ工具Ｐｒｏｔｅｌ９９的ＰＬＤ设计简单逻辑电路的一般方法。