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Steam-gasification of biomass with CaO as catalyst for hydrogen-rich syngas production
Affiliation:1. School of Chemical Engineering, Guizhou Institute of Technology, Guiyang, 550003, China;2. School of Chemistry and Chemical Engineering, Shihezi University, Shihezi, 832003, China;3. School of Mechanical Engineering, Guangxi University, Nanning, 530004, China;1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems (Chongqing University), Ministry of Education of China, Chongqing, 400044, PR China;2. College of Power Engineering, Chongqing University, Chongqing, 400044, PR China;1. Graduate Institute of Environmental Engineering, National Central University, Tao-Yuan City, 32001, Taiwan;2. Industrial Technology Research Institute, Green Energy and Environment Research Laboratories, New Energy Technology Division, Hsin-Chu, 31040, Taiwan
Abstract:Biomass is extensively considered as a feed-stock for bio-chemicals and bio-fuels production. Among all options for the utilization of biomass, gasification process is more popular because of its environmental advantages. In this study, biomass gasification with CO2 removal by CaO sorbent was simulated by using a commercial simulator. The model accuracy was validated with reported results from steam only gasification of biomass in presence of CaO. The system was evaluated through tar yield, carbon conversion, gas quality and H2 yield by varying the reaction temperature, steam flow rate and CaO flow rate. The hydrogen yield enhanced slightly from 187.32 ml/g to 198.49 ml/g with the increase of CaO/B from 1.0 to 1.5. However, a further enhancement in CaO/B from 1.5 to 2 sharply enhanced the hydrogen yield approximately 1.55 times (from 198.49 ml/g to 308.54 ml/g).
Keywords:Biomass  Gasification  Aspen plus  Hydrogen
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