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Biodegradable Bicomponent Fibers from Renewable Sources: Melt‐Spinning of Poly(lactic acid) and Poly[(3‐hydroxybutyrate)‐co‐(3‐hydroxyvalerate)] |
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| Authors: | Rudolf Hufenus Felix A. Reifler Katharina Maniura‐Weber Adriaan Spierings Manfred Zinn |
| Affiliation: | 1. Laboratory for Advanced Fibers, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, CH‐9014 St. Gallen, Switzerland;2. Laboratory for Materials/Biology Interactions, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, CH‐9014 St. Gallen, Switzerland;3. Inspire AG für Mechatronische Produktionssysteme, Institute for Rapid Product Development IRPD, Lerchenfeldstrasse 5, CH‐9014 St. Gallen, Switzerland;4. Laboratory for Biomaterials, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstrasse 5, CH‐9014 St. Gallen, Switzerland |
| Abstract: | PHBV is produced by bacteria as intracellular carbon storage. It is advantageous concerning biocompatibility and biodegradability, but its low crystallization rate hinders the melt‐processing of fibers. This problem can be overcome by combining PHBV with PLA in a core/sheath configuration and introducing a new spin pack concept. The resulting PHBV/PLA bicomponent fibers show an ultimate tensile stress of up to 0.34 GPa and an E‐modulus of up to 7.1 GPa. XRD reveals that PLA alone is responsible for tensile strength. In vitro biocompatibility studies with human fibroblasts reveal good cytocompatibility, making these fibers promising candidates for medical therapeutic approaches.  |
| Keywords: | bicomponent fibers biocompatibility biopolyester biopolymers processing |