Thermal oxidative degradation of bicomponent PP/PET fiber during thermal bonding process

The effects of the thermal bonding temperature, dwell time, and the type of mold materials on the thermal oxidative degradation of the PP sheath of bicomponent fibers were investigated using the Fourier Transform Infrared Spectra (FTIR) and Thermal Gravimetry/Differential Scanning Calorimetry (TG‐DSC) techniques. The samples were prepared on a new 3D nonwovens process based on air‐laying and through‐air thermal bonding. The fiber material was a commercial polypropylene (PP)/polyester (PET) (sheath/core) bicomponent staple fiber. The results reveal that ketone developed following β‐scission in the thermally bonded nonwovens. The level of thermal oxidative degradation increases with increase in the bonding temperature, dwell time, and the thermal conductivity of the mold material. Such thermal oxidative degradation led to the slight widening of the melting peaks of the fiber PP sheath in the thermally bonded nonwovens, and a slight decreasing of melting point compared with those of the as‐received fiber. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 391–397, 2007