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胶粉“核—壳”活化改性:核改性 总被引:9,自引:4,他引:9
探讨了胶粉的活化核改性理论,用溶胀度表征胶粉的核改性效果,筛选出松化膨润剂(核改性剂)品种及用量。考察了活化改性胶粉地NR胶料硫化性能及力学性能的影响,并通过扫描电镜观察了胶粉及活化性胶粉与基质胶间的相界面形态,得出添加改性胶粉的NR硫化胶性能明显改善的理论依据。 相似文献
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在RD-F机械化学法活化胶粉的过程中,高速搅拌器使活化剂在胶粉表面涂覆均匀,开炼机对胶粉产生强烈的剪切细化作用,促进活化剂同胶粉结合。活化剂中,硫化剂提高胶粉--基质胶相界面的交联密度塑解剂促进胶粉表面塑化,防老剂提高胶料动态性能,酚醛树脂进一步增强胶粉-基质胶相界面“粘合”。确定RD-F活化剂体系为:防老剂RD1.酚醛树脂1.420油1.5,促进剂0.4,硫黄0.5,促进剂CZ0.5,乙烯焦同。 相似文献
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用透视电镜对GMS-1接枝改性胶粉在胶料中的形态进行观察,并对GMS-1胶粉在运输带中的应用进行了研究。结果表明,在胶粉与基质胶界面由于可能产生了化学的和物理的作用,而改善了胶粉与基质胶的相容性,并在硫化后生成多相复台网络结构,使得某些力学性能如耐磨耗得到提高。所以GMS-1胶粉具有良好的分散性;而且在运输带复盖胶中应用,能提高胶料的磨耗性能,降低产品成本。 相似文献
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在RD-F机械化学法活化胶粉的过程中,高速搅拌器使活化剂在胶粉表面涂覆均匀,开炼机对胶粉产生强烈的剪切细化作用,促进活化剂同胶粉结合。活化剂中.硫化剂提高胶粉-基质胶相界面的交联密度,塑解剂促进胶粉表面塑化,防老剂提高胶料动态性能,酚醛树脂进一步增强胶粉一基质胶相界面“粘合”。确定RD-F活化剂体系为:防老剂RD1,酚醛树脂1,420#油1.5,促进剂H0.4,硫黄0.5,促进剂CZ0.5,乙烯焦油8。RD-F活化剂体系活化的胶粉能较大地提高胎面胶料的耐磨性。 相似文献
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复合改性水性聚氨酯乳液的合成及表征 总被引:2,自引:0,他引:2
以甲苯二异氰酸酯(TD I)、聚醚二元醇(N220)、1,4-丁二醇(BDO)和二羟甲基丙酸(DMPA)为原料,采用丙酮法合成了水性聚氨酯(WPU)分散体。在此基础上,采用三羟甲基丙烷(TMP)对其进行了交联改性并通过环氧树脂和丙烯酸酯对其进行共聚改性,制得了以丙烯酸酯为核,聚氨酯为壳的核壳交联型水性聚氨酯分散体。通过乳液粒度、黏度和涂膜的耐水性和硬度、接触角等分析以及透射电镜观测研究了二羟甲基丙酸(DM-PA)、TMP、环氧树脂以及MMA用量对水性聚氨酯涂膜耐水性等性能的影响,确定了最佳物料配比。结果表明,当DMPA、E-20、TMP和MMA在聚氨酯水性分散体中的质量分数分别为7.5%、6%、1%和20%时,合成的水性聚氨酯乳液平均粒径80 nm,黏度适中,胶膜的物理力学性能较好,耐水性提高。 相似文献
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Waste rubber powder/polystyrene (WRP/PS) blends with different weight ratio were prepared with styrene grafted styrene butadiene rubber copolymer (PS-g-SBR) as a compatibilizer. The graft copolymer of PS-g-SBR was synthesized by emulsion polymerization method and confirmed through Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC). The copolymer at different weight ratio was subsequently added into the blends. The effects of weight ratio of WRP/PS and compatibilizer loading on mechanical properties were investigated. PS/WRP blends in a weight ratio of 80/20 showed higher impact strength. Moreover, the impact strength of the blend materials increased with the addition of SBR-g-PS, however, decreased at a high loading of the copolymer. The morphology and thermal properties of WRP/PS blends were examined by DSC, scanning electron microscopy (SEM), thermogravimetry (TG). DSC indicated that compared with PS/WRP blend, the glass transition temperature (T g) of PS matrix phase in PS/WRP/SBR-g-PS blend shifted to low temperature because of the formation of chemical crosslinks or boundary layer between PS and WRP, and the T g of WRP phase of both the PS/WRP and PS/WRP/SBR-g-PS blends did not appear. SEM results showed that interfacial adhesion in the blends with the PS-g-SBR copolymer was improved. The morphology was a typical continuous–discontinuous structure. PS and WRP presented continuous phase and discontinuous phase, respectively, indicating the moderate interface adhesion between WRP and PS matrix. TG illustrated that the onset of degradation temperature in the PS/WRP/PS-g-SBR blend decreased slightly by contrast with PS/WRP blend and the degradation of PS/WRP blends with and without SBR-g-PS was completed about at the same values. 相似文献
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Post‐polymerization modification is an attractive approach to extend applications and convert commodity plastics into products with new, desirable and tunable properties. Among the post‐polymerization modification methods, the nitroxide radical coupling (NRC) reaction has been shown to be a convenient and versatile way to graft specific functionalities onto polymer chains and to control the onset and yield of polymer crosslinking during peroxide‐initiated processes. The use of 2,2,6,6‐tetramethylpiperidine‐1‐oxyl (TEMPO) and its derivatives as controllers of scorch in crosslinking and as functionalizers in functionalization reactions is thoroughly described. Examples are also given of graft polymerization from macroalkoxyamines generated by NRC and grafting of nitroxides by irradiation processes. In addition, in this review we attempt to demonstrate the broad applications of the NRC reaction in the preparation of polymers with a multitude of functionalities and elaborate architectures. The examples discussed here concern the use of atom transfer and single electron transfer NRC reactions to design a variety of polymers with asymmetrical structure and the use of the radical crossover reaction, based on the alkoxyamine dynamic covalent bond, to generate reversible polymer structures and switchable functional polymers. © 2018 Society of Chemical Industry 相似文献
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The surface of waste rubber powder (WRP) was graft-modified with styrene (St) by bulk polymerization method. The effects of
styrene content, initiator mass, time of reaction, and temperature on the graft efficiency were investigated. The results
showed that the graft efficiency (%) was highest when 89 wt% styrene and 0.11 g of initiator were added for reaction time
of 25 h at 85 °C. The surface of graft-modified rubber powder was characterized by Fourier transform infrared spectroscopy
(FTIR), scanning electron microscope (SEM), energy dispersive X-ray (EDXS) analysis, and thermogravimetric (TG/DTG) analysis.
The results showed that polystyrene (PS) was grafted onto waste rubber powder, which formed a WRP/PS core–shell structure. 相似文献
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以天甲橡胶MG49改性陶土。采用IR、SEM及结合胶质量分数、表观交联密度、界面作用强度表征值、蠕变和力学性能的测定,研究了MG49改性陶土与NR的相互作用及改性效果。结果表明:MG49湿法改性陶土提高了混炼胶的结合胶质量分数,增加了材料的表观交联密度,增强了陶土与NR间界面的作用强度,改善了硫化胶的网络结构,提高了硫化胶的力学性能。 相似文献
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