双相不锈钢00Cr18Ni5Mo3Si2试制

本文介绍了00Cr18Ni5Mo3Si2奥氏体 铁素体双相不锈钢的基本特点，对3．2t大锭冶炼、轧制开坯工艺进行了研究和生产试制，总结出了生产00Cr18Ni5Mo3Si2双相不锈钢的冶炼、轧制开坯工艺要点。     

00Cr22Ni5Mo3N双相不锈钢生产工艺

简述了00Cr22Ni5Mo3N双相不锈钢的基本特性,详细介绍了00Cr22NiSMo3N双相不锈钢的冶炼、轧制、退火及酸洗工艺要点,给出了00Cr22Ni5Mo3N双相不锈钢生产中的注意事项。     

不锈钢-钢爆炸复合板结合区组织的分析

铁素体不锈钢0Cr13Al—钢 16MnR、奥氏体不锈钢1Cr18Ni9Ti—钢Q23SA和双相不锈钢00Cr22NiSMo3N—钢Q345C3种爆炸复合钢板结合界面呈波状结合，热处理后结合区基板脱碳、复板渗碳。而且在结合区复板侧有一个约30μm宽的亚微米级的超细晶粒带，结合区的硬度高于基体的硬度。     

00Cr22Ni5Mo3N钢大口径厚壁无缝管热穿孔工艺的开发

研究了00Cr22Ni5Mo3N钢的热扭转性能,结果表明,通过对化学成分和扭转温度的合理控制,可以使00Cr22Ni5Mo3N钢获得良好的热塑性,并使其变形抗力小于1Cr18Ni9Ti钢.根据试验结果制订了生产工艺,采用热穿孔工艺成功试制出00Cr22Ni5Mo3N钢大口径厚壁无缝管.     

00Cr18Ni5Mo3Si2双相不锈钢的性能与应用

Cr-Ni双相(α+γ)不锈钢具有耐氯化物应力腐蚀、强度高、导热系数大、线膨胀系数小等一系列特点,因而在解决18Cr-8Ni钢应力腐蚀事故中获得日益广泛的应用。本文全面介绍了00Cr18Ni5Mo3Si2双相不锈钢的性能和应用经验。     

新型高硅不锈钢的发展

国内很久以前就开发了高硅奥氏体不锈钢（Si≥4％），如00Crl4Nil4Si4、00Crl7Nil5Si4Nb、00Cr20Ni24Si4Ti等及高硅双相（Y ｜ α ）小锈钢，如1Crl8Nf11Si4A1Ti等钢号。但这些钢号均属于高硅奥氏体不锈耐酸钢或高硅双相抗高温氧化、抗硫化不锈钢。本文简要介绍国外高硅结构用钢、耐蚀用钢、耐磨用钢、耐热用钢^[1-5]的开发应用，希望能为我国高硅不锈钢的发展提供帮助。     

AOD炉冶炼含氮不锈钢氮合金化工艺开发

介绍了AOD炉运用氮气在不锈钢中溶解与脱除理论所开发的氮合金化工艺。在40tAOD炉上冶炼0Cr19Ni9N,0Cr19Ni9NbN,1Cr17Mn6Ni5N,00Cr18Ni5Mo3Si2（N）,00Cr22Ni5Mo3N等舍氮不锈钢钢种。不需在线分析钢中氮含量，较为准确地预测与控制钢中氮溶解度值及舍氮不锈钢成品的氮含量。     

00Cr25Ni7Mo4N超级双相不锈钢

介绍了00Cr25Ni7Mo4N超级双相不锈钢的化学成分及重点元素的作用,给出了00Cr25Ni7Mo4N超级双相不锈钢的物理性能、力学性能、耐蚀性能,给出了00Cr25Ni7Mo4N超级双相不锈钢的显微组织,叙述了该钢的热处理工艺、冷热加工工艺、焊接工艺,列出了该钢的适用技术条件、产品形状及用途,介绍了国内该钢近年来的一些研究情况。     

00Cr25Ni6Mo2N无缝钢管管坯生产工艺

研究并实践了00Cr25Ni6Mo2N双相不锈钢的冶炼、锻造／轧制与穿管等加工过程,总结了 00Cr25Ni6Mo2N无缝钢管管坯制造过程中的相比例控制、冶炼工艺、热加工工艺等难点问题,对类似双相不锈 钢的冶炼、加工具有指导意义。     

高温下00Cr25Ni7Mo4N超级双相不锈钢的相组织及其元素含量变化研究

本文通过XRD、扫描电镜和能谱研究了00Cr25Ni7Mo4N超级双相不锈钢在1200℃和1320℃不同热处理制度状态下的组织结构及α和γ两相中的主要化学成分含量。实验发现，在1200℃和1320℃附近00Cr25Ni7Mo4N超级双相不锈钢内无新相产生，随处理温度升高，00Cr25Ni7Mo4N超级双相不锈钢α相含量增加，α相和γ相中的Cr、Mo、Si、Ni含量相差越来越小，而Mn元素在α相和γ相中含量趋于一致。     

超塑性奥氏体-铁素体双相不锈钢00Cr25Ni7Mo3N的研制

通过电弧炉-电渣重熔工艺开发研制了成分为(%):0.021C,24.16Cr,7.21Ni,2.87Mo,0.17N,0.48Cu超塑性双相不锈钢00Cr25Ni7Mo3N。试验结果表明,00Cr25Ni7Mo3N超塑性双相不锈钢的耐孔蚀性和耐缝隙腐蚀性远高于传统的304L和316L奥氏体不锈钢。在变形温度960℃、应变速率2×10^-3/s时,00Cr25Ni7Mo3N超塑性双相不锈钢的最高延伸率为960%,该钢超塑性变形的均匀性优于TC4钛合金,可显著减轻构件的重量。     

Hot Ductility of DSS and Its Microstructure Observation During Hot Deformation

By selecting several typical duplex stainless steels (DSS), i. e., 00Cr22Ni5Mo3N, 00Cr21Ni2Mn5N and 00Cr25Ni7Mo4N, as research materials, hot ductility characteristic of DSS was studied by thermal simulation method and microstructure evolution during hot compression was observed through TEM. The results show that the optimum hot ductility temperature range of DSS is 1050–1200°C. 00Cr25Ni7Mo4N exhibits the worst hot ductility and 00Cr21Ni2Mn5N has similar hot ductility to 00Cr22Ni5Mo3N. During hot compression, the dynamic recovery of austenite occurs in DSS while the dynamic recovery and reerystallization of ferrite take place in 00Cr22NioMo3N and 00Cr21Ni2Mn5N, but only the dynamic recovery of ferrite can be observed in 00Cr25Ni7Mo4N.     

Effect of solution treatment on structure of oxide scales for 2205 duplex stainless steel

The oxide scales of 2205 duplex stainless steel plates were studied at hot- rolled state and solid- solution state by SEM, XRD and EDS. The oxide scales on the surface of 2205 duplex stainless steel are composed of a variety of oxides, such as Fe2O3, Cr2O3, FeO??Cr2O3 and NiO??Fe2O3 with spinel structure. After the solution treatment, the oxide scales on the surface changed, in the meantime, the oxidation occurred in the stainless steel substrate. The content of Cr, Ni, Mo increased in the oxides contacting with the substrate, in addition, the distribution of Cr and Ni was more evenly in the oxide scales. The content of Si, Mo increased significantly in the contacting part with the substrate. The surface of the steel plate was formed by a certain outside- in hierarchical oxide phase of Fe, Mo, Ni, Cr and Si. The stability and complexity of the oxide film increased, so it was more difficult to be removed by acid pickling.     

Corrosion Resistance and Semiconducting Properties of Passive Films Formed on 00Cr13Ni5Mo2 Supermartensitic Stainless Steel in Cl- Environment

The semiconducting properties of passive films grown on 00Crl3Ni5Mo2 supermartensitic stainless steel were investigated in comparison with conventional 2Cr13 martensitic stainless steel. Cyclic vohammetry and electro- chemical impedance spectroscopy （EIS） were used for the studies. 00Crl3NiSMo2 steel exhibited a good corrosion resistance performance, attributing to its passive capability. The results of Mott-Schottky analysis demonstrated n- type semiconductors for the passive films with doping densities of about 1020- 1021 cm -3, and the thickness of space- charge layers was also calculated. The experimental results confirmed that Mo plays an important role in improving the corrosion resistance of 00Crl3Ni5Mo2 steel due to its impact on the doping density.     

00Cr22Ni5Mo3N热变形动态软化机理研究

通过平面应变压缩的试验方法,研究了变形温度对00Cr22Ni5Mo3N热塑性的影响,并通过TEM观察,探讨00Cr22Ni5Mo3N两相组织热变形动态软化机理。结果表明,变形温度对00Cr22Ni5Mo3N试样的峰值应力影响显著,在热变形过程中,其铁素体相的软化通过动态回复及再结晶实现,而奥氏体相的软化则只能通过动态回复实现。     

超级双相不锈钢S32760凝固过程Thermo-Calc热力学软件的应用

利用Thermo-Calc热力学计算软件得到S32760（022Cr25Ni7Mo3WCuN）超级双相不锈钢凝固过程中的相图,确定了S32760双相钢是FA （铁素体-奥氏体）凝固模式,通过改变奥氏体和铁素体的形成元素的含量,确定在不同的化学成分下的热加工性能、Cr₂N和σ相析出温度,得到S32760双相钢热加工温度区间随着奥氏体形成元素C、N、Ni、Mn含量的增加而变大,随着铁素体形成元素Si、Cr、Mo含量的增加而减小,而W对热加工性能没有影响。根据热力学计算,确定了最优的化学成分（/%:0.022C,0.30Si,0.80Mn,25.60Cr,6.20Ni,0.54Cu,3.50Mo,0.54W,0.27N）,S32760双相钢最佳热塑性温度为1195℃, Cr₂N相的析出温度为1050℃, σ相析出温度为1020℃,热加工区间为145℃,并且通过了后续的现场实践验证。     

典型Cr-Ni-Mo-N高合金双相不锈钢热加工性能研究

试验钢的典型高合金双相不锈钢S32707 (022Cr27Ni7Mo5N)、S32750 (022Cr25Ni7Mo4N)、S32205(022Cr23Ni5Mo3N)、S31803(022Cr22Ni5Mo3N)在生产坯料上取样,采取了不同的热处理、热加工和热穿孔以及调整化学成分等方法,研究了组织及工艺对其热加工性能的影响。结果表明:两相比例和σ相的析出情况与热穿孔温度和冷变形的中间退火密切相关,S32707钢的二次相的析出速度和析出量远超过S32750、S32205及S31803双相不锈钢。对S32707双相不锈钢需适当降低Cr(Cr≤27%)、N(N≤0.4%)含量,提高Mo(4%～5%Mo)含量,合理控制加热速度(2～2.5℃/min)及终轧(锻)温度(≥1060℃),并注意回炉加热和圆管坯中心钻孔的影响,可提高热加工塑性,防止开裂。