掺矿渣粉和减水剂的HEMC水泥砂浆物理性能

研究了掺矿渣粉和高效减水剂的羟乙基甲基纤维素（HEMC）改性水泥砂浆的物理性能,其中包括新拌砂浆含气率、保水率、体积密度,硬化砂浆体积密度、孔隙率、毛细孔吸水率等,结果表明：矿渣粉和减水剂这两者对砂浆保水性和毛细孔吸水率的作用与羟乙基甲基纤维素的相同,而对含气率、体积密度和孔隙率的作用则与之相反,矿渣粉、减水剂和羟乙基甲基纤维素共同掺加时,可使砂浆体积密度和孔隙率保持在一定的范围内。     

羟乙基甲基纤维素对水泥砂浆性能的影响

研究了羟乙基甲基纤维素对新拌砂浆和硬化砂浆的改性效果。结果表明,羟乙基甲基纤维素明显提高了新拌砂浆的保水性,降低了新拌砂浆和硬化砂浆的体积密度,硬化砂浆的吸水率、抗压强度、抗折强度和弹性模量,对砂浆韧性改善不明显。     

聚合物干粉对水泥砂浆力学性能的影响

研究羟乙基甲基纤维素和乙烯基共聚物2种聚合物干粉对水泥砂浆力学性能的影响。结果表明,掺加羟乙基甲基纤维素会明显降低水泥砂浆抗折强度,而掺加乙烯基共聚物则能显著提高水泥砂浆抗折强度;2种聚合物干粉均能显著降低水泥砂浆的抗压强度和动弹性模量,改善砂浆柔韧性,提高水泥砂浆与混凝土以及聚苯板基材之间的粘结抗拉强度,且在一定掺量范围内,掺量越大,效果越明显。     

桥面用丁苯乳液改性水泥砂浆物理性能的研究

通过测定新拌砂浆保水性、含气率,硬化砂浆孔隙率、孔径分布、断面形貌以研究丁苯乳液D623对砂浆物理性能的改性效果,丁苯乳液D623对砂浆有良好的保水和引气作用,可使砂浆体积密度降低,孔径分布改变;聚合物成膜后形成网状结构,与水泥水化产物相互穿透;硬化砂浆的孔隙率与新拌砂浆的含气率没有对应关系,与新拌砂浆的体积密度反倒有一定的关系;砂浆抗压强度、抗折强度和弹性模量均与孔隙率、体积密度有对应关系,而粘结抗拉强度与它们的关系则不明确。     

材料组成对干粉砂浆性能的影响

研究了经改性处理的某无机矿粉(M)、甲基羟乙基纤维素和可再分散乳胶粉等在单掺和复掺条件下对干粉砂浆保水率、抗折抗压强度、粘结拉力和抗渗性能等的影响。研究结果表明:当甲基羟乙基纤维素的掺量达到水泥的0.35%时,砂浆的保水率达到99%;同时,改性无机矿粉(M)也能提高砂浆的保水率。采用正交试验方法,经过优化研究确定外加剂的最佳配比为0.3%甲基羟乙基纤维素、2%可再分散乳胶粉和6%改性无机矿粉(M),即能满足砂浆的施工性能,又能降低砂浆的成本。     

羟乙基甲基纤维素对机械喷涂砂浆性能的影响

纤维素醚是机械喷涂砂浆中必不可少的添加剂。研究了2种不同黏度的羟乙基甲基纤维素醚(HEMC)对机喷砂浆密度、保水性能等物理性能的影响。以及力学性能,抗压强度、抗折强度和弹性模量的影响。在物理性能方面,研究结果显示出,随着HEMC掺量的增加,砂浆的密度是逐渐下降的;相反保水性能得到明显的提升,并且在HEMC掺量大于0.15%时保水率都不小于90%。在力学性能上,随着HEMC掺量的增加会明显降低抗压强度、抗折强度、弹性模量,但砂浆的折压比会有一定上升趋势,砂浆的柔韧性更好。     

矿物掺合料对水泥基自流平砂浆性能影响研究

研究了不同掺量粉煤灰、矿渣、硅粉对水泥基自流平砂浆抗压强度、抗折强度和流动性的影响。结果表明:在砂浆中掺入粉煤灰时,砂浆流动性及强度随粉煤灰掺量的增加呈现先增大后减小的趋势;复掺时,等量矿渣和粉煤灰双掺及等量矿渣、粉煤灰和硅粉三掺砂浆的流动度提高最为显著,均达到350 mm,并且其抗压强度高于同龄期基准水泥及单掺粉煤灰10%的砂浆。     

大掺量粉煤灰矿渣粉普通干混砂浆的试验研究

本文通过试验研究了大掺量粉煤灰-矿渣粉对普通干混砂浆的主要技术性能的影响。试验结果表明,粉煤灰-矿渣粉掺量在50%～80%时,砂浆和易性能够满足设计要求,但抗压强度和拉伸粘结强度随着复掺掺量的增加而降低;掺加胶凝材料总用量6%～8%的脱硫石膏,砂浆和易性变化不大,但可显著提高大掺量粉煤灰-矿渣粉干混砂浆的抗压强度及拉伸粘结强度,砂浆收缩率降低10%以上,抗碳化能力提高,体积更稳定。     

乙烯—醋酸乙烯酯乳胶粉对砂浆力学性能的影响

研究了不同掺量下乙烯一醋酸乙烯酯乳胶粉对砂浆抗压强度、抗折强度、粘结强度的影响.结果表明:随着乳胶粉掺量的增加,砂浆的抗折强度和粘结强度有大幅度提高,但抗压强度随之降低;乙烯-醋酸乙烯酯乳胶粉的适宜掺量为胶凝材料重量的2%～3%.     

HPMC对铝酸盐水泥-石膏二元胶凝体系砂浆性能的影响

研究了羟丙基甲基纤维素（HPMC）及其掺量对铝酸盐水泥-石膏二元胶凝体系砂浆物理力学性能的影响,并采用压汞仪和扫描电镜对砂浆宏观性能的变化作出了合理解释.结果表明：HPMC会大幅度改变砂浆的保水率、含气量、凝结时间、流动度、稠度值和体积密度,明显提高新拌砂浆的可塑性,增加可操作时间,但却会降低硬化砂浆的抗折强度、抗压强度和拉伸黏结强度;硬化砂浆强度的降低归因于HPMC会大幅度增加砂浆孔隙率和孔尺寸,并改变水化产物形态.因而在实际应用中,应慎重考虑使用HPMC来改性铝酸盐水泥-石膏二元胶凝体系砂浆的两面性.     

HEMC改性水泥砂浆在硫酸盐侵蚀作用下的力学性能

研究了羟乙基甲基纤维素(HEMC)改性水泥砂浆在硫酸盐侵蚀作用下的力学性能演变规律及HEMC的作用机理.结果表明:HEMC会明显降低水泥砂浆在硫酸盐侵蚀作用下的抗压强度和抗折强度,但能显著提高黏结抗拉强度;硫酸盐短期侵蚀作用能提高HEMC改性水泥砂浆的力学性能,但长期侵蚀作用会显著降低力学性能;HEMC改性水泥砂浆在硫酸盐长期侵蚀作用下仍具有优良的力学性能,原因在于HEMC能优化水泥砂浆的孔结构及内部界面结构,显著降低水分和硫酸根离子的渗透和扩散;就硫酸盐长期侵蚀作用下的力学性能而言,HEMC在水泥砂浆中存在着较佳掺量范围.     

桥面用丁苯乳液改性水泥砂浆的力学性能

用德国标准和规范研究了丁苯乳液D623对桥面用水泥砂浆力学性能的改进效果;丁苯乳液D623对砂浆有良好的减水作用,对提高抗折强度和粘结抗拉强度也有显著作用,并可大幅度降低压折比、提高折弹比,综合抗压强度、抗折强度、抗拉粘结强度和弹性模量等力学性能,桥面用改性砂浆的聚合物D63掺量范围为10.1%～17.5%。     

Influence of aggregates grading and water/cement ratio in workability and hardened properties of mortars

Mortar is the material responsible for the distribution of stresses in masonry structures. The knowledge about the fresh and hardened properties of mortar is fundamental to ensure a good performance of masonry walls. Water/cement ratio and aggregates grading are among several variables that influence physical and mechanical behaviour of mortars. An experimental program is presented in order to evaluate the influence of aggregates grading and water/cement ratio in workability and hardened properties of mortars. Eighteen compositions of mortar are prepared using three relations cement:lime:sand, two types of sand and three water/cement ratios. Specimens are analyzed through flow table test, compressive and flexural strength tests. Results indicate that the increase of water/cement ratio reduces the values of hardened properties and increases the workability. Besides, sands grading has no influence in compressive strength. On the other hand, significant differences in deformation capacity of mortars were verified with the variation of the type of sand. Finally, some correlations are presented among hardened properties and the compressive strength.     

Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar

The development of new binders, as an alternative to traditional cement, by the alkaline activation of industrial by-products (i.e. ground granulated slag and fly ash) is an ongoing research topic in the scientific community [Puertas F, Amat T, Jimenez AF, Vazquez T. Mechanical and durable behaviour of alkaline cement mortars reinforced with polypropylene fibres. Cem Concr Res 2003;33(12): 2031–6]. The aim of this study was to investigate the feasibility of using and alkaline activated ground Turkish slag to produce a mortar without Portland cement (PC).Following the characterization of the slag, mortar specimens made with alkali-activated slag were prepared. Three different activators were used: liquid sodium silicate (LSS), sodium hydroxide (SH) and sodium carbonate (SC) at different sodium concentrations. Compressive and flexural tensile strength of alkali-activated slag mortar was measured at 7-days, 28-days and 3-months. Drying shrinkage of the mortar was measured up to 6-months. Setting times of the alkali-activated slag paste and PC paste were also measured.Setting times of LSS and SH activated slag pastes were found to be much slower than the setting time of PC paste. However, slag paste activated with SC showed similar setting properties to PC paste.LSS, SH and SC activated slag mortar developed 81, 29, and 36 MPa maximum compressive strengths, and 6.8, 3.8, and 5.3 MPa maximum flexural tensile strengths at 28-days. PC mortar developed 33 MPa compressive strength and 5.2 MPa flexural tensile strength. LSS and SH activated slag mortars were found to be more brittle than SC activated slag and PC mortars.Slag mortar made with LSS had a high drying shrinkage, up to six times that of PC mortar. Similarly, slag mortar made with SH had a shrinkage up to three times that of PC mortar. However, SC activated slag mortar had a lower or comparable shrinkage to PC mortar. Therefore, the use of SC as an activator for slag mortar is recommended, since it results in adequate strength, similar setting times to PC mortar and comparable or lower shrinkage.     

矿物掺合料对干粉砂浆物理性能及孔结构的影响

研究了石灰石、矿渣和粉煤灰3种矿物掺合料分别对干粉砂浆的工作性能和力学性能的影响,并探讨了掺有掺合料时干粉砂浆的宏观力学性能和其微观孔结构之间的关系。结果表明:粉煤灰在掺量小于30%时能够提高砂浆的流动度,但掺量再继续增大时,砂浆流动度反而下降;掺入矿渣粉略能提高砂浆的流动度;石灰石粉在一定程度上降低砂浆流动度;同时石灰石粉能够提高砂浆的保水率,而矿渣粉和粉煤灰却降低砂浆的保水率。随着石灰石、矿渣和粉煤灰掺量的增加,砂浆28 d强度均有不同程度的降低,影响顺序为石灰石>粉煤灰>矿渣;与空白样相比,内掺占水泥质量50%的石灰石粉和矿渣粉时,28 d砂浆硬化体的总孔隙率分别增加10.2%、7.7%,而掺等量粉煤灰时总孔隙率则基本不变。以石灰石替代50%的水泥时,28 d砂浆硬化体中d>100 nm的多害孔增加24.0%,而以粉煤灰替代50%的水泥时,砂浆中多害孔基本不变,以等量的矿渣粉替代时d>100 nm的多害孔减少6.5%。     

聚合物改性水泥砂浆含气量对力学性能的影响

通过试验研究了相同流动度情况下,聚丙烯酸酯乳液(VIVID400)、乙烯/醋酸乙烯酯共聚乳液(CP149)和丁苯乳液(SD623)改性水泥砂浆含气量对其力学性能的影响.结果表明:3种聚合物乳液引入气泡量有所不同;随着消泡剂掺量的增加,改性水泥砂浆体积密度有不同程度的提高,含气量降低,而抗折、抗压强度则有较大幅度的提高;VIVID400改性水泥砂浆拉伸黏结强度随消泡剂掺量的增加呈先升高后降低的趋势,这可能与消泡剂对改性水泥砂浆孔结构的影响有关.