共查询到20条相似文献,搜索用时 609 毫秒
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以3-甲氧基-4-羟基苯甲醛(香兰素)为原料,经与盐酸羟胺反应得到3甲氧基-4-羟基苯腈,再与碱金属卤化物经脱甲基化反应合成3,4-二羟基苯腈,产品含量99.8%,以香兰素计总收率75.2%。与其他合成方法比较,这条合成路线更适合于工业化。 相似文献
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4-羟基吡啶的合成工艺进展 总被引:2,自引:0,他引:2
分别介绍了以草酸二乙酯、丙酮、氨气为原料经缩合、水解、氨化和热解反应合成4-羟基吡啶;以吡啶、氯化亚砜为起始原料经氯化和水解反应合成4-羟基吡啶;以4-氨基吡啶为起始原料经重氮和水解反应合成4-羟基吡啶;并对这些合成路线进行了探讨. 相似文献
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介绍已有的合成路线,经过评价提出新的合成方法,即在硫酸催化下用对羟基苯乙酮α-溴化合成了α-溴-4-羟基苯乙酮。反应条件:反应物摩尔比为1·01·0,反应温度80~90℃;催化剂用量为反应物酮的70%(质量比),反应时间4h。收率为83·5%。 相似文献
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Brian E. Hayden 《Catalysis Today》1997,38(4):17964-481
The results of electrochemical studies of CO oxidation on clean and bismuth modified Pt(1 1 0)-(1×2) and Pt(1 1 1) surfaces and a supported platinum catalyst are compared. The effect of sub-monolayers of bismuth is to increase the CO oxidation potential on Pt(1 1 0)-(1×2), and decrease it on Pt(1 1 1). This primarily reflects the rather low potential for CO oxidation characteristic of the more open packed Pt(1 1 0)-(1×2) surface, and the higher potential characteristic of the close packed Pt(1 1 1) face. The oxidation potential of CO in the intermixed CO/Bi phases on the single crystals is very similar. The effect of bismuth on the supported platinum catalyst is to increase the CO oxidation potential by a similar amount to that found for Pt(1 1 0)-(1×2). In addition, modification by bismuth results in a concomitant reduction in the CO tolerance of the commercial catalyst. CO oxidation on the catalyst exhibits poisoning by bismuth in a similar fashion to Pt(1 1 0)-(1×2), and the bismuth redox couple on the catalyst is the same as that found on Pt(1 1 0)-(1×2). High coverages of bismuth on the catalyst do not appear to reduce its activity for hydrogen oxidation. These results are discussed in the context of the requirement for surface mediated oxygen transfer during CO electro-oxidation. 相似文献
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介绍利用酒精废液生产有机-无机复混肥的工艺流程、原料配比及关键设备的操作控制。酒精废液利用列管式蒸发器浓缩至w(H2O)约40%,再与尿素、磷酸一铵、氯化钾等通过转鼓造粒机生产的11-7-7-20(有机质)有机-无机复混肥符合国家标准。 相似文献
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采用固相反应法制备La2/3Sr1/3MnO3(LSMO3)粉体,用溶胶-凝胶法分别制备La1 4Sr1 6Mn2O7(LSMO7)和Ce0.8Gd0.2O2-δ(CGO)粉体.分别将LSMO3和LSMO7粉体与CGO粉体以1∶1的质量比均匀混合,在300MPa下冷等静压成型,并在1 500℃烧结2 h,制备了LSMO3/CGO和LSMO7/CGO复合阴极材料.研究了2种复合阴极材料的微观结构和热膨胀性能.结果表明:LSMO3/CGO与LSMO7/CGO烧结体在150~1 000℃温度范围内的平均线性热膨胀系数分别为1.52×10-5/K和1.53×10-5/K,与CGO固体电解质具有相近的热膨胀性能.烧结体断面形貌分析表明:LSMO3/CGO复合阴极具有与CGO相似的断面显微结构. 相似文献
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甲氧头孢菌素中间体7-AMCA的合成工艺优化 总被引:1,自引:0,他引:1
7β-氨基-3-(1-甲基-1H-四唑-5-硫甲基)-3-头孢烯-4-羧酸(7-AMCA)是合成甲氧头孢菌素关键中间体7β-氨基-7α-甲氧基-3-(1-甲基-1H-四唑-5-硫甲基)-3-头孢烯-4-羧酸二苯甲酯(7-MAC)的重要中间体。采用7-氨基头孢霉烷酸(7-ACA)和1-甲基-1H-1,2,3,4-四唑-5-硫醇(5-MMT)为原料,以乙酸为溶剂,甲磺酸为催化剂,经亲核取代制备得到7-AMCA。本文主要探讨了物料配比、催化剂用量、反应时间和温度等因素对反应的影响,并通过二次回归建立了数学模型,确定了合成7-AMCA的最佳工艺条件。在此基础上合成的产品收率高达93.24%,HPLC纯度98.76%。产品结构经^1H NMR和IR表征确认。 相似文献
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Ioannis D. Petsalakis John C. Polanyi Giannoula Theodorakopoulos 《Israel journal of chemistry》2005,45(1-2):111-126
Theoretical Austin model 1 (AM1) calculations on the adsorption of benzene and toluene on Si(111)7×7 are presented. Both physisorbed and chemi-sorbed states have been calculated for up to three adsorbed molecules per half unit cell of the Si(111)7×7 surface. Secondly, theoretical calculations on the induced attachment of benzene as well as rationalization of the dynamics of the halogenation reaction of 1,2- and 1,4-dibromobenzene on Si(111)7×7 are reviewed. The main incentive for this study was the interpretation of recent experimental scanning tunneling microscopy (STM) results from the Toronto laboratory on a new electron-induced or photo-induced attachment process for benzene on Si(111), and, particularly, experimental results related to the thermal dissociative reactions of 1,2- and 1,4-dibromobenzene on a Si(111)7×7 surface. The central objective is to relate the reagent geometry in 1,2-dibromobenzene and 1,4-dibromobenzene to the Br-Br pair distance of dibrominated Si(111)7×7. For benzene, we propose a possible path for the conversion from the normal strained di-sigma-bound state (S) at Si(111) to a more strongly bound state (B) consisting of a phenyl plus an H-atom adsorbed species. For 1,2- and 1,4-dibromobenzene dibromination of silicon, evidence has been found for two mechanisms of reaction. One reaction pathway involves intermediate binding of the organic molecule on the Si surface through C-Si bonds, analogous to the benzene S structure. The second dynamical pathway involves intermediate binding through weak Br. Si attachment followed by formation of pairs of covalently-bound Br-Si. The outcomes from the two dynamical pathways are consistent with the observed STM patterns for pairs of Br-Si at Si(111) 7×7 due to the reaction of 1,2- and 1,4-dibromobenzene. 相似文献
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介绍了硫酸法和氯化法钛白粉生产工艺.钛白粉生产是硫酸主要非化肥用户,硫酸消费量7 000~7 500 kt/a.过去10年亚洲钛白粉需求量每年以5% ~ 6%的速率递增,其中中国则以6.5%的速率增长.预计到2020年全球钛白粉总需求为7 600 kt,其中中国需求达到2 800 kt;届时钛白粉行业耗酸量会达到8 000 ~9 000 kt.未来硫酸法钛白粉产能将继续扩张,尤其是在中国、印度、巴西和越南等国家. 相似文献
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Large‐Scale X‐Ray Microtomography Analysis of Fiber Orientation in Weld Line of Short Glass Fiber Reinforced Thermoplastic and Related Elasticity Behavior 下载免费PDF全文
Large‐scale X‐ray microcomputed tomography (μ‐CT) is used to investigate microstructural features of weld lines in a short glass fiber reinforced polymer. The main originality of this work is related to the evaluation of local structural and mechanical characteristics in zones of unmastered heterogeneities. Complete and incomplete injection molded plates are considered to investigate weld lines with and without process‐induced porosity. Using a helical scanning trajectory, the full 3D microstructure is obtained at centimetric scale to cover a large zone including first contact between colliding fronts at a voxel size of 3 μm. Microstructure analyses show that weld line area is ill‐ordered at the fiber and structure length scales. Near the first contact point, fiber orientations show the signature of vortexes, which mark the presence of repulsive forces. The presence of micrometric porosity is only confirmed in incomplete plates. μ‐CT images are used as inputs to create a full‐scale finite element model for assessing strain localization. Predicted principal strains are compared to digital image correlation measurements performed during uniaxial tensile tests. Full‐scale modeling combined to 3D high‐resolution imaging proves high potential to correlate local fiber heterogeneities with strain localization effects.
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Distribution coefficients for the liquid-liquid extraction of 2,3-butanediol (5wt%) in aqueous solutions with binary mixtures of 4-nonylphenol (0-67 vol%), toluene and several alcohols, (2-ethyl-l-hexanol, 1-oclanol and 1-decanol) at 25°C are reported. The distribution coefficients were in the following ranges: 4-nonylphenol + toluene (0-0·23), 4-nonylphenol + 2-ethyl-l-hexanol (0·23 - 0·27), 4-nonylphenol + 1-octanol (0.21-0·33) and 4-nonylphenol + 1-decanol (0·22-0·37). The largest distribution coefficient was found to be 0·37 for the mixed solvent 4-nonylphenol+1-decanol (50vol%), which shows a slight decrease in the separation factor. Activity coefficients at infinite dilution were determined using the MOSCED model and a similar trend for all the solvent mixtures of 4-nonylphenol and alcohols was found. 相似文献