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原油乳状液的稳定性及新型破乳剂的研究 总被引:1,自引:0,他引:1
介绍了原油乳状液的形成条件,分析了原油乳状液中的天然乳化剂,如沥青质、胶质、石蜡及固体黏性颗粒对乳状液稳定性的影响,概括了破乳剂的破乳机理及几种研究应用较多的新型破乳剂. 相似文献
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pH值对原油乳状液稳定性的影响 总被引:1,自引:0,他引:1
研究了pH值对原油乳状液稳定性的影响, 测定了胶质和沥青质在油水界面上的聚集和铺张情况, 不同pH值下油水界面张力以及胶质和沥青质模拟乳状液的稳定性变化, 并且完成了不同pH值下的乳状液化学破乳以及电场破乳实验。沥青质相对胶质更易在界面上聚集和铺展, 形成高黏弹性的界面膜。pH值为酸性或碱性时都能有效降低油水界面张力, 增加乳状液稳定性, 使其化学破乳脱水困难, 而破乳实验也验证了这一观点。随着pH值从2增加到10, 胶质模拟乳状液和沥青质模拟乳状液稳定性变化大, 变化趋势则刚好相反, 胶质模拟乳状液稳定性增加, 油水分离速度减慢;沥青质模拟乳状液稳定性减弱, 体系电导率0.21~1.8mS/cm。因此pH<7时, 沥青质稳定能力强, 而胶质稳定能力弱, 电脱水过程中电脱装置正常工作;pH>7时, 结果相反, 表明电脱装置短路现象与沥青质、胶质稳定能力变化相关。 相似文献
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低渗透油田原油属轻质原油,针对低渗透油田采出轻质原油乳状液破乳难度大,低温(<60℃)条件下常规破乳剂破乳效果不佳的问题,根据某油田现场采出液制备模拟乳状液,并分别采用瓶试法、稳定性分析仪研究不同类型破乳剂的破乳效果以及乳状液的微观动力学变化特性,优选出较佳低温破乳剂配方;应用界面流变仪等探讨油水界面黏弹性、油水界面张力、破乳剂在油水界面的动态吸附规律,揭示低温破乳剂的作用机理;最后,分析模拟现场采出乳状液破乳状态,从乳状液脱水率、挂壁程度及破乳剂质量浓度等多个角度综合评价了不同类型破乳剂的低温破乳效果。为低渗透油田采出液低温破乳工艺技术的研发提供了理论及现场应用基础。 相似文献
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胜利孤岛注聚原油破乳剂的筛选与性能评价 总被引:1,自引:0,他引:1
以研究孤岛注聚原油乳状液破乳为目的,通过瓶试法和界面性质的测定,筛选了多种类型的原油破乳剂,考察了破乳剂质量浓度、聚合物和原油组分对破乳效果的影响,探讨了原油乳状液的破乳机理。结果表明,破乳剂BF-069质量浓度在100mg/L,50℃条件下,脱水率达到70%以上,现场温度稍微升高,脱水率达到85%左右,破乳剂BF-069已在胜利油田应用,现场使用效果良好;聚合物质量浓度在50mg/L时,原油乳状液最难破乳;原油中不同组分对破乳效果的影响不同,油水界面性质的测定表明,胶质和沥青质是影响原油破乳的主要因素。 相似文献
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针对辽河曙光稠油乳状液粘度大、破乳难、破乳温度高等问题,以曙光稠油为研究对象,从中分离出沥青质和胶质,用傅里叶变换红外光谱法分析其主要官能团,考察沥青质和胶质对稠油乳状液粘度及破乳效果的影响。测定了不同含量胶质、沥青质对稠油油/水界面张力的影响。结果证实,沥青质比胶质含有羟基多,分子间氢键作用强烈,更容易造成原油粘稠。随着叫(胶质)、训(沥青质)升高,稠油乳状液脱水率降低,w(沥青质)超过2.1%,或w(胶质)超过32%时,稠油乳状液的破乳十分困难。w(胶质)、w(沥青质)的增高会使破乳剂水溶液与原油的界面张力增大,w(沥青质)增加0.7%比叫(胶质)增加7%原油的界面张力升高还要大,所以训(沥青质)的增加对油水界面张力影响更大。 相似文献
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稠油在热采高温作用下,容易在油层中发生乳化行为,形成稳定的油包水乳状液,给地面产出液处理流程造成一定的负担。通过分析热采放喷后产出液的含水率为28%、脱水原油的黏度为2 300 mPa·s、胶质与沥青质含量和为24.33%,从醇类、酚醛树脂类、多烯多胺类、复配类的防乳破乳剂中优选出防乳破乳剂PEC-12,幵分析了破乳温度、防乳破乳剂浓度、乳状液含水率对PEC-12防乳破乳剂破乳效果的影响。结果表明,随着破乳温度从50℃升高至80℃,防乳破乳剂的破乳率从44.6%逐渐升至98.2%。防乳破乳剂最经济有效的浓度为200ppm。乳状液中含水率从20%增至40%时,防乳破乳剂的脱水率从62.5%增至93.8%。矿场试验表明,在注热过程中添加防乳破乳剂是一种能有效抑制稠油反相乳化的有效措施,添加PEC-12防乳破乳剂后,地面处理流程显示油包水乳状液总量降低80%,稠油乳状液破乳效果好,处理负担明显减轻,同时跟地面产出液破乳剂发生了协同破乳作用,使处理后的污水中含油量达到设计要求,满足回注地层的水质要求。 相似文献
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《分离科学与技术》2012,47(7):1144-1163
There are an increasing number of crude oil fields that are now producing both crude oil and water emulsions; such fields are both onshore and offshore. These emulsions are formed during oil exploitation due to the presence of natural surfactants, such as asphaltenes and resins. These molecules strongly stabilize the water/oil interface and prevent coalescence of water droplets. As water/oil phase separation is necessary before oil transportation and refining, demulsifiers are used to break water-in-oil emulsions. This review presents the crude oil emulsion formation, factors affecting demulsification of crude oil emulsion such as demulsifier chemical structure, water content, partition coefficient (KP), and demulsifier concentration. This review also covers the kinetics and mechanism of the demulsification process. 相似文献
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基于乳状液中液滴在电场中的受力情况的分析,建立了W/O乳状液中液滴振荡固有频率公式,从理论角度分析和解释了高频脉冲电场对W/O乳状液的破乳机理,从力学的角度分析了最佳频率存在的理论基础,并推导出了最佳频率的计算公式。该固有频率与液滴尺寸、界面张力、黏度、温度、密度等有关。为了验证最佳频率公式的可靠性,用正辛烷乳状液进行了室内实验。实验结果表明,理论最佳频率公式的预测结果与实验测得的最佳频率结果吻合,经修正后与白油实验结果也非常接近。 相似文献
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石油醚W/O乳状液及其液膜稳定性 总被引:17,自引:0,他引:17
以破乳率为衡量标准,借助显微镜直接观察,探讨了乳状液含水量、表面活性剂用量、乳化时间、乳化强度等因素对石油醚W/O型乳状液体系稳定性的影响。在实验范围内,乳状液含水量的提高及表面活性剂用量的增加,有利于乳状液的稳定;存在较优的乳化时间20min和乳化强度4000rmin-1。选取脂肪烃、芳香烃、混合烃共6种不同油相制备乳状液,对比其稳定性的差异。此外,还初步考察了石油醚W/O/W液膜溶胀和泄漏问题,结果表明该乳状液膜泄漏率低于3.5%,表观溶胀率约为20%。 相似文献
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《分离科学与技术》2012,47(4):427-445
Abstract The application of liquid emulsion membrane technology to the extraction of nitrophenols from aqueous solutions is discussed. The effects of various parameters such as hydrophilic lipophilic balance of the surfactants, speed of agitation, water volume fraction in the water-in-oil emulsion, treatment ratio, and the concentration of surfactant on the extraction of p-nitrophenol are studied, and a suitable formulation for a liquid emulsion membrane is developed. The same formulation was used to extract o-nitrophenol and 2,4-dinitrophenol, and the results are compared with those of p-nitrophenol. The swelling of the emulsion during extraction is minimized by the addition of cyclohexanone to the membrane phase. The demulsification of the emulsion phase after extraction is also carried out by a chemical demulsification technique. Acetone is used for demulsification. 相似文献
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Wei Liu Bing Xiao Guolong Yang Yanlan Bi Fusheng Chen 《European Journal of Lipid Science and Technology》2020,122(2)
Aqueous enzymatic extraction (AEE) is an environmentally friendly edible‐oil‐extraction process that can also provide edible protein. However, the AEE process may form a stable emulsion in most cases, which seriously limits the large‐scale industry applications for producing vegetable oils. In this study, the salt‐assisted microwave radiation demulsification of the oil‐rich emulsion prepared with AEE from peanuts is investigated. The microwave demulsification method is compared with other conventional demulsification methods, including heating, and freezing–thawing. The salt‐assisted microwave demulsification of the emulsions shows a greater free oil yield than conventional heating demulsification. Moreover, the microwave demulsification shows a similar free oil yield in less time than freezing–thawing method. Under the optimal operating conditions of demulsification, the free oil yield can reach 92.3% with CaCl2‐assisted microwave demulsification for only 2 min. In addition, the oxidative properties and the fatty acid compositions of the demulsified peanut oil are investigated. No significant difference in the fatty acid composition is observed among salt‐assisted microwave, freezing–thawing, and heating demulsified oil. The oxidative properties of the salt‐assisted microwave demulsified peanut oil is better than the conventional heating demulsified oil. Thus, salt‐assisted microwave demulsification provides a quick and effective demulsification method to obtain vegetable oils with high quality. Practical Applications: Aqueous enzymatic extraction (AEE) is an environmentally friendly edible‐oil‐extraction process. To solve the problem of stable emulsion formed during AEE process, the salt‐assisted microwave demulsification of the oil‐rich emulsion prepared with AEE is developed with high efficiency (demulsification for 2 min). In addition, the oxidative properties of the microwave demulsified oil is better than the conventional heating demulsified oil. 相似文献
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Demulsification of emulsified water-in-oil droplets was worked out with the employment of wetting coalescence materials. Demulsification is carried out in conventional stirred-column and packed-column. Among the four kinds of natural fibers and two kinds of inorganic materials tested, natural fiber A, originated from wood shavings was found to give the best performance of demulsification. The demulsification efficiency can exceed 96.5% when demulsification conditions are optimized. The packed-column showed much better performance both in terms of demulsification efficiency and repeated use of the recovered oil phase for extracting cadmium in simulated wastewater. Operating variables governing the demulsification efficiency were investigated. 相似文献