共查询到20条相似文献,搜索用时 46 毫秒
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MAGNETOSTRICTIVEBEHAVIOUROFR(Fe_(1-x)Al_x)_yALLOYS(R=Dy_(0.65)Tb_(0.25)Pr_(0.1))¥WANGBowen;WUChangheng;ZHUANGYuzhi;JINXimei;LIJi... 相似文献
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LIN Yijian HU Jian YOU Yunlong JING Chunyong YU Quanqin Shanghai Iron Steel Research Institute Shanghai China LIN Yijian Measuring Testing Centre Shanghai Iron Steel Research Institute Shanghai China 《金属学报(英文版)》1990,3(9):185-190
The formation of borides M_3B_2 M_2B_2 and M_(23)B_6 may be carried out from the melt-quenchedFe_(70)Cr_(18)Mo_2SiB_9 during 700—1150℃ annealing.As the temperature raising,the M_2B,themajority being Fe_2B.may be gradually replaced by Cr_2B via the co-existence between Fe_2Band Cr_2B.The Cr_2B may be formed by trans formation of Fe_2B through the atomic substitu-tion and structural adjustment.The thin slice of remaining Fe_2B is sandwiched between(100)faces of(Cr,Fe)_2B as stacking fault.The M_2B_2 is virtually composed of theMo_(1+x)(Fe,Cr)_(2-x)B_2 where x(0≤x≤1)increases with the increase of temperature. 相似文献
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用Ga取代部分Fe对R3(Fe,Mo)29结构及磁性的影响 总被引:1,自引:1,他引:0
潘洪革 《中国有色金属学报》1998,8(3):375-378
详细研究了Ga取代R3(Fe,Mo)29(R=Sm,Y)(Ga<0.15)中的部分Fe对其结构和内禀磁性的影响,包括不同的Ga取代对R3(Fe,Mo)29化合物的晶胞常数、居里温度、饱和磁化强度、磁晶各向异性的影响。结果表明:在R3(Fe,Mo,Ga)29化合物中,随着Ga含量的增加,晶胞体积膨胀,居里温度升高,饱和磁化强度下降,Fe原子的平均磁矩降低,Sm3(Fe0.966-xMo0.034Gax)29化合物的各向异性由平面向锥面结构转变,继续增加Ga含量,有可能出现单轴各向异性。 相似文献
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MAGNETIC MOMENT,CURIE TEMPERATURE AND SPIN WAVE EXCITATION FOR AMORPHOUS Fe_(90-x)Si_xZr_(10) ALLOYS
SHEN Baogen ZHANG Zhiying GUO Huiqun ZHAO Jiangao Institute of Physics Academia Sinica Beijing ChinaGU Benxi Nanjing University Nanjing China 《金属学报(英文版)》1991,4(7):31-36
The magnetization curves at 1.5 K and thermomagnetic curves for amorphous Fe_(90-x)Si_xZr_(10)(x=0,4,7 and 10)alloys prepared by the drum spinning technique have been measured with an extracting sample magnetometer.It is obtained that the average magnetic moment,,per magnetic atom and Curie temperature,T_c,in the amorphous FeSiZr alloys increase with increasing Si content.The and T_c are found to be quite small,compared with amorphous FeSiB alloys.This unusual behavior is suggested to be due to the presence of the Fe—Fe antiferromagnetic interactions.The temperature dependence of magnetization at lower temperature is in accordance with Bloch's T~(3/2) law.Calculation shows that the spin wave stiffness constant,D,increases with increasing Si content from 0.37 meV·nm~2 for x=0 to 0.538 meV·nm~2 for x=10.The values ofindicate that the range of the exchange interaction is roughly the mean atomic distance of nearest neighbours. 相似文献
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LI Yinfeng GUO Huiqun XU Rufeng SHEN Baogen Laboratory of Magnetics Institute of Physics Academia Sinica Beijing China 《金属学报(英文版)》1992,5(11):340-345
The disaccommodation(DA)measurements of initial susceptibility were performed inamorphous Fe_(90-x)Ni_xZr_(10)(x=10,20,30)alloys.The DA was measured for two differentamorphous states:as-quenched and pretreated at 537 K for 45 min.For all the as-quenched samples,in the isochronal spectra of DA a well defined relaxation peak around350 K is accompanied by a samll but distinct peak near the Curie temperature ofFe_(90)Zr_(10) phase(T_c=230 K).The reversibility and annealing effect on DA are analyzedwithin the framework of two-level model.The fits of the theory to the experimentaldata of reversible relaxation processes gave a spectrum,of activation energies and pre-exponential factor. 相似文献
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含Fe和Mn的Ni_(30)Cu_(70)固溶体团簇模型与耐蚀性研究 总被引:2,自引:0,他引:2
提出了一个极限田溶体合金的团簇模型,在此基础上优化设计了添加Fe和Mn的Ni_(30)Cu_(70)(原子分数,%)固溶体合金成分.在该模型中,固溶的Fe和Mn以Ni为第一近邻形成12配位立方八面体原子团簇(Fe_(1-x)Mn_x)Ni_(12)而分散到Cu基体中,因此极限固溶体合金成分为[M_1/_(13)Ni_(12)/_(13)]30Cu_(70)=[(Fe_(1-x)Mn_xNi_(12)]Cua_(30.3),M=(Fe_(1-x)Mn_x).采用X射线衍射和电化学腐蚀测试等方法,研究了[(Fe_(1-x)Mn_x)Ni_(12)]Cu_(30.3)合金的微观组织与耐腐蚀性能的关系.实验结果表明,对应于极限同溶体状念的[(Fe_(0.75)Mn_(0.25))Ni_(12)]Cua_(30.3)合金,在3.5%NaCl溶液中具有相对好的耐腐蚀性能. 相似文献
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1.IntroductionThenewhard-magneticNdFeBall0yswithlowNdc0ncentration(35at.%)havebeenobtainedbycrystallization0fam0rphous.ibbo.sI1-3].Theirmagneticpr0pertiesatr0omtemperatureareasfollows:coercivityHc=16O-24OkA/m,remanenceB,=1'2-1.25T,andmagneticenergy(BH).ax=64108kJ/m'.ThevaluesofB.and(BH).axaremuchhigherthanth0se0fthewidelyusedanis0tropic(Ba,Sr)Fe12Ol9ferritesandAlNiC0alloys.Inpreyi0uspapers['-'1,wehavereportedthestructuralandmagneticpr0perties.Recentlywestudiedtheinfluenceofthesubstit… 相似文献
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为改善多晶Fe-Ga合金的磁致伸缩性能,在Fe-Ga合金中掺杂稀土Ce、Tb和Dy元素。 研究了Fe83Ga17和Fe83Ga17R0.6 (R=Ce、Tb和Dy)合金的结构和磁致伸缩性能。结果表明,Fe83Ga17合金由单一bcc结构Fe(Ga)固溶体相组成,而掺杂稀土后的Fe83Ga17R0.6合金中除保持bcc结构的Fe(Ga)固溶体相外,还出现了R2Fe17第二相。掺杂稀土后的Fe83Ga17R0.6合金磁致伸缩系数明显大于Fe83Ga17合金。掺杂不同种类的稀土元素对Fe-Ga合金磁致伸缩性能改善的程度不同。在外磁场为557 kA/m时,Fe83Ga17Ce0.6合金的磁致伸缩系数(206×10-6)明显大于Fe83Ga17Tb0.6 (165×10-6)和Fe83Ga17Dy0.6 (161×10-6)合金的磁致伸缩系数。 相似文献
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研究了Cr部分取代Fe对Sm_2(Fe_(1-x)Cr_x)_17N_(~2.7)磁粉磁特性的影响.添加少量Cr(x=0-0.1),该化合物的结构不变化。随Cr含量的增加,它的Curie温度、各向异性场、饱和磁化强度、平均Fe原子磁矩和平均超精细场均有所降低.材料的单相性显著改善,矫顽力提高.Sm_2(Fe_(0.95)Cr_(0.05))_17N_(~2.7)磁粉的矫顽力_iH_c达到1592kA/m. 相似文献
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<正> 本文用Mossbauer技术结合DTA和电阻分析,对两种非晶态合金(Ⅰ)Fe_(77.8)Si_(7.5)B_(14.7)和(Ⅱ)Fe_(78.5)Si_(8.9)B_(12.6)的结构弛豫进行了研究。 Ⅰ和Ⅱ两种非晶态合金的DTA曲线如图1,晶化开始温度分别为530和500℃,晶化前均出现较长的放热峰,预示其结构弛豫过程中可能发生某种结构变化。 相似文献
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退火温度对纳米晶Ni_(0.5)Zn_(0.5)Fe_2O_4吸波性能的影响 总被引:1,自引:1,他引:0
采用溶胶-凝胶自燃烧法制备了Ni_(0.5)Zn_(0.5)Fe_2O_4纳米晶,将其分别在550、800和1050℃下二次退火2h,利用XRD和微波矢量网络分析方法对二次热处理产物及其电磁性质进行了研究.结果表明,自燃烧后已形成完整的结晶尖晶石型Ni_(0.5)Zn_(0.5)Fe_2O_4纳米晶.在0.1~1.5 GHz的测试频率,纳米晶具有介电损耗和磁损耗,且随着热处理温度的升高,电损耗逐渐减小.在1050℃下退火后获得的Ni_(0.5)Zn_(0.5)Fe_2O_4纳米晶材料的μ'、μ"以及磁损耗正切tanδ_m明显大于在室温及550、800℃退火后的试样,在所测频率内具有优异的磁吸收性能. 相似文献
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用粉末冶金法(磁场压制烧结)制备(Mn1-xFex)5Sn3(x=0.1~0.5)合金,对其晶体结构、居里温度进行研究。室温XRD分析表明,该系列合金均保持Mn5Sn3的InNi2型相结构,计算发现合金的晶格常数随着x量增大而减小。通过M-T曲线测量结果表明:居里温度TC在室温附近244~391K连续可调,且随着Fe含量的增加而提高,居里温度随成分近似呈线性变化;成分为(Mn0.70Fe0.30)5Sn3合金的居里温度为295K,在外加磁场为0~1.5T下,最大磁熵变约为0.87J·(kg·K)-1,是一种成本低廉的室温磁制冷候选材料。 相似文献
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《稀有金属(英文版)》2020,(3)
Sm(Co,Cu,Fe,Zr)_z magnets have drawn much attention for high-temperature applications due to their high Curie temperature,strong corrosion resistance and thermal stability.The effect of increasing Fe content on the distribution of elements and squareness(S_r) of demagnetization curves were investigated for two kinds of magnets with different nominal compositions of Sm(Co_(bal)Fe_(0.15)-Cu_(0.07)Zr_(0.03))_(7.8) and Sm(Co_(bal)Fe_(0.28)Cu_(0.07)Zr_(0.03))_(6.6) in this work.The magnetic properties of the magnets with higher Fe content fluctuate greatly after different solution treatments,indicating that they are more sensitive to the process temperature.The increase in Fe content can obviously enhance the cellular phase size.Meanwhile,inhomogeneous Cu distribution is observed in the Sm(Co_(bal)Fe_(0.28)-Cu_(0.07)Zr_(0.03))_(6.6) magnet,resulting in the different cellular structures and corresponding magnetic domain patterns in different regions in the inner grains.Furthermore,the lower Cu content regions are responsible for the wider magnetic domain,which have weaker resistance to applied magnetic field.As a result,S_r of demagnetization curve decreases with the increase in Fe content due to the inhomogeneous Cu distribution,which was confirmed by in-situ observation of electron probe micro-analyzer(EPMA) and magneto-optical Kerr optical microscope(MOKE). 相似文献
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Cr含量对TiMn1.2-xCrxV0.25Fe0.05合金吸/放氢性能的影响 总被引:5,自引:0,他引:5
对名义成分为TiMn1.2-xCrxV0.25Fe0.05(x=0.0,0.1,0.2,0.3,0.4)合金的储氢性能进行了研究.结果表明,合金的晶格常数和晶胞体积随Cr含量的增加而增大;随着Cr含量的增加,合金的吸/放氢平台压力和滞后效应减小.随着cr含量的变化,TiMn1.2-xCrxV0.25Fe0.05合金112峰半高宽(FWHM)和晶格常数c/a比率的变化与该合金吸/放氢平台斜率的变化一致,表明合金的平台斜率与合金的品格畸变关系密切.TiMn1.0Cr0.2V0.25Fe0.05合金具有较大的储氢量、低的平台压力、小的滞后和斜率,适于作为质子交换膜燃料电池供氢源的储氢瓶应用. 相似文献
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采用光学显微镜、示差扫描热分析、交流磁化率测试和室温压缩试验等方法系统研究Ti含量对Ni53Mn23.5Ga23.5-xTix (x=0, 0.5, 2, 3.5, 8, 15)合金的显微组织、相变行为、力学行为和磁学特性的影响规律。结果表明:Ti元素在合金中的极限固溶度低于15%;随着Ti含量的增加,合金的相变温度和断裂强度及断裂应变先逐渐增加后降低,其断裂方式由沿晶断裂转变为穿晶断裂再到沿晶断裂;而合金的居里温度随Ti含量的增加逐渐降低 相似文献