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三唑类化合物具有良好的生物活性,作为农用杀菌剂已使用多年,作为杀虫杀螨剂的例子也不少,但以前作为除草剂使用的实例较少,仅有杀草强和三唑磺,且未广泛使用。然而三唑类除草剂近几年得到了迅速的发展,尤其引人注目的是美国FMC公司开发的三唑啉酮类、陶氏益农公司开发的三唑并嘧啶磺酰胺类、日本吴羽化学公司开发的苯基三唑酰胺类以及日本中外制药公司开发的以CH 900为代表的三唑酰胺类化合物。这些化合物不仅具有新型的化学结构,而且在使用剂量方面亦具有优越性,可与超高效除草剂磺酰脲类相媲美。本文将对三唑类除草剂的研究进展按化学结构分类予以简要的介绍。 相似文献
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寡聚噻吩类衍生物作为一个富电子体系通常表现出优越的电子传输性和光电性能,炔键作为一个直线型的富电子单元,引入到噻吩体系中可以增长体系的共轭度,增大体系中的刚硬核长度,同时还可以提高整个分子的平面规整度。含炔键单元的噻吩类化合物所具备的分子自组装性能和优异电子传输性已引起人们极大的关注。介绍了炔键在主链上,侧链上及含噻吩炔单元的环形、星形、X形与树枝形的寡聚噻吩类化合物的研究进展。阐述了它们的分子结构与液晶相态结构、光电性能、器件性能、自组装结构之间的关系。所有的研究表明该类化合物在有机分子器件方面有着重要的应用前景。 相似文献
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噻吩类化合物主要分为α-衍生物和β-衍生物,其应用领域广泛,其中噻吩类化合物在农药方面就有很广泛的应用,主要用于杀菌和杀虫,外国的很多研究显示噻吩类化合物对蚊蝇类卵、鳞翅目昆虫、幼虫具有显著的光活化毒杀效应,鳞翅目幼虫的生长发育起到抑制作用。概述了被文献报道的具有杀虫活性的部分噻吩类化合物,并对其发展前景进行展望。 相似文献
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Delphine Briand Eric Dubreucq Pierre Galzy 《Journal of the American Oil Chemists' Society》1995,72(11):1367-1373
This study describes the influence of various factors on the hydrolysis and alcoholysis activities of the lipase fromCandida parapsilosis (Ashford), Langeron and Talice in aqueous media. Optimal activities were obtained at 45°C and pH 6–6.5. The influence of
the nature of the substrate on the temperature activity profiles was observed. Total or partial recovery of the activities
was obtained when methanol was added to the enzyme extract after thermal denaturation. A tyrosin residue appeared to be necessary
for lipase function. Magnesium was a required metal cofactor. These activities were optimal in the presence of high amounts
of water (water activity >0.9). 相似文献
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1,3,4-噁二唑取代芳酰基硫脲的合成及杀菌活性研究 总被引:2,自引:0,他引:2
设计合成了10个1,3,4-噁二唑取代的芳酰基硫脲类化合物,所有化合物的结构经IR,^1HNMR及元素分析确证。初步生物测试结果表明,大多数化合物具有较好的杀菌活性。 相似文献
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姜黄素衍生物具有杀虫、抑菌、抗病毒、消炎抗氧化、抗癌等多种生物活性。概述了对姜黄素芳环及芳环上酚羟基、β-二酮、活泼亚甲基进行修饰,或者对去掉活泼亚甲基和一个羰基后的1,4-戊二烯-3-酮类化合物进一步修饰后,得到的化合物具有较高的生物活性,并展望了其未来的发展前景。 相似文献
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The liver microsomal Δ9 and Δ6 desaturase activities have been studied in rats with carbon tetrachloride-induced hepatitis. Immediately after poisoning,
significant decreases were observed for both types of desaturase activity. However, recovery kinetics were slower for the
Δ6 desaturase than for the Δ9 desaturase. The activities of NADH-ferricyanide and NADH-cytochrome C reductases, proteins involved in the electron transfers
associated with microsomal desaturation, were also measured. There was a fall in both activities after poisoning, but this
decrease was less than that of the desaturase activities. 相似文献
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初步研究了所合成的五个二胍基钛配合物与改性的甲基铝氧烷(MMAO)组成的摧化体系对苯乙烯聚合的催化性能。结果表明:二胍基钛二氯化物和MMAO组成的催化体系可以催化苯乙烯的立体规整聚合,得到高间同含量的聚苯乙烯。 相似文献
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酰腙类化合物由于其广泛的生物活性,在农药与医药研究领域占有重要的地位。主要用作杀虫剂、杀菌剂、除草剂、消炎剂、镇痛剂。多年来酰腙类化合物的合成和生物活性研究一直是精细化工领域研究开发的重要方向之一。本文综述了近年来该类化合物生物活性方面的研究近况。 相似文献
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The abilities of three commercially available lipases—Lipozyme IM 20, Amano PS-30, and Amano CE—to synthesize fatty acid ethyl
esters via the alcoholysis of soy triglycerides (TG) and phosphatidylcholine (PC) in grade No. 2 diesel fuel were investigated.
All three enzyme preparations were active in water-saturated diesel fuel, synthesizing fatty acid esters from both TG and
PC. Response surface methodology, based on a Modified Central Composite design, was employed to examine the coordinate effects
of lipid, water, and ethanol concentrations on enzyme activities and to identify conditions yielding maximum alcoholysis.
For all three enzymes, optimal activities toward TG occurred at added water concentrations of less than 0.3 M. With PC as
substrate, optimal enzyme activities occurred at added water concentrations as much as tenfold greater than this, and the
amount of water required for maximum activity was proportional to the substrate concentration. For both substrates the enzyme
activities were generally reduced as ethanol concentrations rose. The exceptions to this were the Lipozyme-TG combination,
where activity increased with increasing ethanol concentrations, and the PS-30-PC combination, where activity was roughly
constant across the range of water and ethanol concentrations examined. Hydrolytic activities of the enzymes in aqueous reactions
were poor predictors of transesterification activity in organic solvent: the aqueous hydrolytic activities of CE and PS-30
toward TG were roughly comparable, and 25 to 50 times greater than that of IM 20. However, in the alcoholysis of TG in diesel
fuel the order of activities was PS-30>IM 20>CE. The activities of Lipozyme and CE toward PC were similar to one another,
and PS-30 was considerably less active on this substrate. CE lipase was more active toward PC than toward TG. Lipozyme displayed
comparable activity toward the two substrates. PS-30 was considerably more active on TG than on PC. Degrees of conversion
were consistent with the transesterification of only one fatty acid of TG, and slightly greater than one fatty acid for PC.
Preliminary studies indicated that for CE and PS-30, but not for Lipozyme IM 20, the degree of conversion of TG, but not PC,
could be significantly increased by the further provision of ethanol. Expansion of this work could lead to a method for the
production of simple fatty acid esters, which are suitable as diesel fuels, from multicomponent agricultural materials containing
TG and PC. 相似文献