不同加载路径下的AZ31B镁合金的成形极限

为了分析实际成形过程中AZ31B镁合金产生破裂的原因,并为改善工艺条件提供实用可靠的判据,采用实验和有限元模拟相结合的方法研究AZ31B镁合金的成形极限.分别对沿轧制方向、垂直于轧制方向、与轧制方向成45°的3种方向的试件进行单向拉伸实验,获得AZ31B镁合金的工程应力-工程应变曲线,获得材料的真实应力-真实应变曲线和...     

镁合金表面等离子喷涂Al2O3-TiO2陶瓷涂层的耐腐蚀性研究

采用等离子喷涂技术在AZ31镁合金表面制备Al2O3-13％TiO2陶瓷复合涂层,对涂层的微观组织进行了观察分析,测试了涂层的表面硬度.通过极化曲线和浸泡腐蚀试验,对比研究了镁合金基材及喷涂陶瓷涂层的试样在5％ NaCl溶液中的耐腐蚀性能.结果表明:涂层镁合金试样的硬度和耐腐蚀性优于基体镁合金,但当腐蚀液透过涂层孔隙时...     

高精度AZ31镁合金薄壁管件等温挤压后的组织与性能

研究了不同条件下AZ3l镁合金管材的等温挤压情况,并对挤压前后材料组织与力学性能的变化进行了分析.研究结果表明,AZ31镁合金热挤压时发生了动态再结晶,材料组织比铸态时细化,力学性能大幅度提高;在(653±10)K挤压温度范围内金属流动均匀,挤出管材尺寸精度较高,力学性能良好;从综合性能看,AZ31镁合金挤压产品的合适退火工艺为573 K × 2 h;此时管材的机械拉伸强度为260 MPa,伸长率为23%.     

Ce对热轧AZ31镁合金动态再结晶及织构的影响

研究了Ce对热轧AZ31合金的动态再结晶过程及织构的影响.结果表明:加入Ce后抑制了AZ31合金中孪生动态再结晶(TDRX)的发彺,还加速了合金动态再结晶进程,同时显著弱化了基面织构.EBSD分析表明,在AZ31-1.0Ce(质量分数,%)合金中,除(0001)基面织构外,还出现了介于(0001)基面和(1010)柱面的取向强度峰值,说明Ce的加入激活了变形时的非基面滑移系.Ce的加入并没有使合金的轴比值降低,相反还略有升高,说明非基面滑移的激活并非晶格结构的变化所致.Ce的加入可能改变了Mg原子之间的结合态以及增加了合金的层错能,使得非基面滑移系被激活,从而导致基面织构弱化.     

多向锻造对变形镁合金AZ31组织和力学性能的影响

文章采用不同锻造工艺对电磁连铸变形镁合金AZ31铸锭进行了多向锻造研究。结果表明,通过大变形的多向锻造后,变形镁合金AZ31可以得到有效细化,多向锻造有利于变形镁合金发生再结晶,锻造后变形镁合金AZ31最终得到均匀细小的等轴晶组织。工艺3得到最好的综合性能,锻造后变形镁合金AZ31硬度和抗拉强度分别提高了22.5%和33.5%,延伸率也有所提高。多向锻造后,室温拉伸试样的断口形貌出现大量的韧窝,表现为剪切断裂为主的韧性断裂。     

热挤压工艺对AZ31镁合金组织与力学性能的影响

在不同挤压条件下对AZ31镁合金进行了热挤压试验,并对挤压前后材料组织与力学性能的变化进行了分析.研究结果表明,AZ31镁合金热挤压时发生了动态再结晶,材料组织比铸态时细化,力学性能大幅度提高;AZ31镁合金挤压后的组织及力学性能受挤压温度及冷却方式影响,在本试验范围内,AZ31镁合金在623 K挤压后空冷得到的组织均匀细小,力学性能良好.     

AZ31和AZ91镁合金等温挤压及挤压后的微观组织变化

通过等温挤压和金相观察,研究了AZ31和AZ91镁合金不同变形条件下的挤压性能和变形后的微观组织变化。结果表明,AZ31镁合金的挤压变形性能较好,而AZ91镁合金在挤压比为4∶1、挤压温度为400℃,以及在挤压比为9∶1、挤压温度为350℃和400℃时,挤压后的试件表面均出现了裂纹;AZ31镁合金的最佳成形温度为300℃～400℃,AZ91镁合金的最佳成形温度为300℃～350℃;镁合金在热挤压过程中发生了动态再结晶,挤压之后合金的晶粒显著细化。     

基于3D CA的AZ31镁合金动态再结晶行为研究

本文建立了三维元胞自动机(3D-CA)模型,通过热压缩试验和电子背散射衍表征技术(EBSD),对AZ31镁合金在热变形过程中的微观组织演化规律进行可视化和定量预测。根据试验得出的真应力-应变曲线,确定了3D-CA模型参数在试验条件下的取值,建立了模型参数与变形条件(应变、变形温度和应变速率)之间的关系。利用所建立的3D-CA模型,对AZ31镁合金在热变形过程中的流动行为和微观组织演化进行模拟和讨论。结果表明:再结晶体积分数随着应变的增大而增加,随着变形温度的增大或应变速率降低而增大,提高应变速率或降低温度可以细化再结晶晶粒。模拟结果与实验结果吻合较好,相对误差值在4.5%-16.2%之间,所建立的3D-CA模型能够较准确地预测镁合金AZ31的微观组织演化。     

Effect of Hot Extrusion on Microstructures and Properties of TiB2/AZ31 Magnesium Based Composites

采用原位合成-半固态搅拌铸造法制备了TiB2/AZ31镁基复合材料,研究了热挤压对TiB2/AZ31镁基复合材料组织和力学性能的影响。结果表明：热挤压不仅能显著细化合金组织,而且能有效改善TiB2颗粒分布的均匀性。与铸态AZ31镁合金相比,铸态TiB2/AZ31镁基复合材料的硬度、抗拉强度都有一定程度的提高。经过热挤压后,TiB2/AZ31镁基复合材料的硬度和抗拉强度分别比基体合金提高了126.2%和98.8%,达到950 MPa和322 MPa。磨损表面形貌显示,TiB2颗粒的引入以及对TiB2/AZ31镁基复合材料进行热挤压,都可有效地提高材料的耐磨性。     

Effect of Schiff base as corrosion inhibitor on AZ31 magnesium alloy in hydrochloric acid solution

Schiff base derived from the condensation reaction of analar grade 1-amino-2-naphthol 4-sulphonic acid with cinnamaldehyde was prepared under microwave condition. The Schiff base was analysed by infrared spectroscopy. This Schiff base as a corrosion inhibitor of AZ31 magnesium alloy in 0.05 mol/L HCl solution was studied. The inhibition effect of the Schiff base compound (4Z)-4-(3-phenyl allylidene amino)-3-hydroxy naphthalene-1-sulfonic acid (AC) on AZ31 magnesium alloy corrosion was studied using mass loss, potentiodynamic polarization technique, electrochemical impedance spectroscopy methods. The potentiodynamic polarization curve shows that Schiff base AC inhibits both anodic and cathodic reactions at all concentration, which indicates it is a mixed type inhibitor. EIS results indicate that as the additive concentration is increased, the polarization resistance increases whereas double-layer capacitance decreases. The adsorption of AC on the AZ31 magnesium alloy surface in 0.05 mol/L HCl obeys the Langmuir adsorption isotherm.     

CA-P/AZ31B镁合金的生物相溶性研究

将具有磷酸钙(CA-P)表面涂层的AZ31B镁合金植入家兔的骨髂和肌肉组织间,观察了体内CA-P/AZ31B合金周围骨骼、肌肉组织的炎性反应,以及CA-P/AZ31B合金的微观结构,评价了CA-P/AZ31B合金的细胞毒性作用及溶血性.结果表明,CA-P涂层可有效地延缓AZ31B镁合金降解产物的释放速度,增加合金的表面粗糙度,减轻合金在体内诱导的组织炎性反应,显著降低合金的溶血率.CA-P/AZ31B合金具有良好的生物相容性,有望成为新一代可降解生物医学材料.     

AZ31镁合金沉积类金刚石薄膜的表面形貌和腐蚀行为

为了改善镁合金的耐蚀性,扩展其应用范围,采用等离子全方位离子镀膜技术在AZ31镁合金表面沉积了含有Si-N和Si-O的2种类金刚石(Diamond-like carbon,DLC)薄膜,研究了其表面形貌及其在3.5%NaCl溶液中的腐蚀行为,探究了DLC薄膜对AZ31镁合金腐蚀行为的影响。利用SEM和AFM观察了AZ31镁合金表面沉积DLC薄膜的表面形貌,采用电化学法测试表面沉积DLC薄膜的AZ31镁合金在3.5%NaCl溶液中的极化曲线和开路电位,通过拉伸试验测试其在空气和3.5%NaCl溶液中的应力应变。结果表明:镁合金试样表面的DLC薄膜光滑致密,在3.5%NaCl溶液中表面沉积DLC薄膜AZ31镁合金的极化行为与表面未沉积DLC薄膜AZ31镁合金相似,表面沉积DLC薄膜AZ31镁合金电位正向移动,耐蚀性提高;与表面未沉积DLC薄膜AZ31镁合金相比,在空气中,表面沉积DLC薄膜AZ31镁合金极限抗拉强度与其接近,延伸率略低;在3.5%NaCl溶液中,表面沉积DLC薄膜AZ31镁合金极限抗拉强度略有降低,延伸率略高。     

Comparison of corrosion behaviors of AZ31, AZ91, AM60 and ZK60 magnesium alloys

The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corrosion resistance of the four materials is ranked as ZK60＞AM60＞AZ31＞AZ91. The corrosion processes of the four magnesium alloys were also analyzed by SEM and energy dispersive spectroscopy(EDS). The results show that the corrosion patterns of the four alloys are localized corrosion and the galvanic couples formed by the second phase particles and the matrix are the main source of the localized corrosion of magnesium alloys. The corrosion resistance of the different magnesium alloys has direct relationship with the concentration of alloying elements and microstructure of magnesium alloys. The ratio of the β phase in AZ91 is higher than that in AZ31 and the β phase can form micro-galvanic cell with the alloy matrix, as a result, the corrosion resistance of AZ31 will be higher than AZ91. The manganese element in AM60 magnesium alloy can form the second phase particle of AlMnFe, which can reduce the Fe content in magnesium alloy matrix, purifying the microstructure of alloy, as a result, the corrosion resistance of AM60 is improved. However, due to the more noble galvanic couples of AlMnFe and matrix, the microscopic corrosion morphology of AM60 is more localized. The zirconium element in ZK60 magnesium alloy can refine grain, form stable compounds with Fe and Si, and purify the composition of alloy, which results in the good corrosion resistance of ZK60 magnesium alloy.     

AZ31镁合金的热挤压变形和力学性能分析

为了掌握高精度镁合金管材的生产工艺,通过对铸锭的均匀化处理,借助500 t挤压机、拉伸试验机、金相显微镜和透射电镜(TEM)对AZ31镁合金管材的等温挤压过程进行了研究,试制了AZ31镁合金挤压薄壁管材,获得了尺寸精度高、粗糙度小和壁厚差小的管材;分析了不同挤压条件下的AZ31镁合金管材的尺寸精度、组织、力学性能.研究结果表明:在挤压温度为623士20K挤出管材经523K×3h退火时其性能较好,抗拉强度、屈服强度和延伸率分别为270 MPa,175 MPa和23.1%.     

WCu假合金熔渗过程数值分析

利用层错能的热力学模型对AZ31,AZ61,AZ91等六方系合金的层错能进行了计算,推导出溶质元素含量及偏聚对层错能影响的理论表达式.计算结果表明:该热力学模型适用于六方系合金层错能的计算,计算的结果与实验相符.其中AZ31,AZ61,AZ91合金的基面层错能在373 K时都为45 mJ/m2.镁合金层错能随着温度的升高逐渐降低,化学自由能对层错能的影响占主导地位.Al元素有降低镁合金层错能的作用,随着固溶于镁基体中Al含量的增加,合金的层错能降低.合金元素在层错区域内的偏聚对层错能造成的影响也不容忽视,溶质元素Al的偏聚增加了镁合金的层错能.     

AZ31镁合金位错密度模型及热压缩的微观组织预测

通过热压缩实验研究AZ31镁合金挤压杆料在变形温度300、400和500℃,应变速率0.1、0.01和0.001 s^?1条件下的流变行为,基于Arrhenius方程建立流变应力的本构模型,其中激活能Q为132.45 kJ/mol,应变硬化系数n为4.67。依据AZ31镁合金高温变形中的动态再结晶(Dynamic recrystallization,DRX)机理和位错密度演化规律,建立宏观变形?微观组织多尺度耦合的位错密度模型,该模型能够反映热加工过程中的加工硬化、动态回复(Dynamic recovery,DRV)、低角晶界(Low angle grain boundaries,LAGB)和高角晶界(High angle grain boundaries,HAGB)等机制的交互作用。利用ABAQUS的VUSDFLD子程序进行热压缩过程的有限元模拟,获得DRX分数、LAGB和HAGB位错密度的数值模拟结果以及压缩载荷。结果表明:实验载荷与模拟结果基本吻合,本文提出的AZ31镁合金位错密度模型是合理的。     

镁合金钨极氩弧焊接头深冷强化机制

针对镁合金焊接接头软化问题,文中提出了AZ31镁合金TIG焊接接头深冷强化方法,进行了镁合金TIG焊接工艺试验和焊接接头的-160℃,8 h深冷处理试验;深冷处理使镁合金焊接接头抗拉强度从212.4 MPa提高到246.6 MPa;用X射线衍射仪(XRD)和透射电子显微镜(TEM)等观测了焊接接头深冷前后的微观组织与结构,分析了焊接接头深冷强化机理.结果表明,深冷处理使镁合金TIG焊接接头形成亚晶结构,第二相Mg17Al12颗粒弥散析出,提高了基体连续性,第二相颗粒数量增加,使接头组织细化并获强化,深冷处理使焊接接头的晶粒发生转动与位错转化为位错环,使接头组织产生孪晶,强化了焊接接头.     

Microstructures and properties of aluminum film and its effect on corrosion resistance of AZ31B substrate

Aluminum films with thickness of 8.78-20.82μm were deposited on the AZ31B magnesium alloys by DC magnetron sputtering.The influences of aluminum film on the micro-mechanical properties and corrosion behavior of the magnesium alloys were investigated.The morphology of aluminum film was examined by scanning electron microscopy and the microstructure of aluminum film was analyzed by X-ray diffiactometry.Nanoindentation and nanoscratch tests were conducted to investigate their micromechanical properties.More...     

Preparation of Ni-Cu-Mo-Cr film deposited on AZ31magnesium alloy by double glow sputtering with Cu interlayer

For improving the corrosion resistance of AZ31magnesium alloy, a double glow sputtering deposited Ni-Cu-Mo-Cr film with brush plating Cu interlayer is applied to deposit a metal amorphous/nanocrystal film on AZ31magnesium alloy. Using a brush plated Cu interlayer, the content of noble elements, such as Ni, Cr, and Mo, is higher than that of a Ni-based film without Cu interlayer. The microstructure of the Ni-Cu-Mo-Cr alloy film with the brush plated Cu interlayer confirms that the film is classified into two regions, i.e., an amorphous layer on the outmost surface and an underlying nanocrystalline layer with a grain size of less than 5 nm. The Ni-based alloy amorphous film formed on AZ31magnesium alloy was investigated using an electrochemical polarization measurement. Compared with the AZ31 magnesium alloy, the sputter-deposited Ni-based alloy film and the sputter-depostion Ni-based alloy film with a brush plated Cu interlayer formed on AZ31 magnesium alloy exhibit obvious passivation phenomena.